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http://dx.doi.org/10.15230/SCSK.2021.47.3.227

Preparation and Characterization of Planar-type Artificial Calamine Powder with a High Aspect Ratio for the Application to Ultraviolet and Blue Band Protection Cosmetics  

Lee, Jung-Hwan (Energy Business Unit, Duckjin Co.)
Lee, Gun-Sub (Energy Business Unit, Duckjin Co.)
Jo, Dong-Hyeon (Energy Business Unit, Duckjin Co.)
Hong, Da-Hee (Department of Advanced Materials Engineering, Korea Polytechnic University)
Yu, Jae-Hoon (Department of Advanced Materials Engineering, Korea Polytechnic University)
Gwack, Ji-Yoo (Department of Advanced Materials Engineering, Korea Polytechnic University)
Lee, Hee-Chul (Department of Advanced Materials Engineering, Korea Polytechnic University)
Publication Information
Journal of the Society of Cosmetic Scientists of Korea / v.47, no.3, 2021 , pp. 227-235 More about this Journal
Abstract
In this study, we have prepared pure planar-type ZnO and calamine powder containing both ZnO and Fe2O3 components as a raw material for cosmetics with UV and blue band blocking functions. The planar-type ZnO ceramic powder having a high aspect ratio in the range of 20:1 to 50:1 was synthesized by precipitation method in a zinc acetate and sodium citrate mixed solution with the electrolyte obtained by power generation with a zinc-air battery. The content of Fe2O3 in the artificial calamine ceramic powder could be increased by increasing the amount of iron chloride solution added, and in this case, some of the blue region of visible light and ultraviolet light were remarkably absorbed. When potassium acetate was added, the decomposition of the Zn(OH)42- anion in the solution was promoted to facilitate the growth of ZnO crystal in the form of a barrier wall in the vertical direction on the (0001) plane, which could increase UV absorption by providing more opportunities. By controlling the amount of iron chloride solution and potassium acetate solution added, the composition and shape of the thin film plate-shaped artificial calamine ceramic powder can be optimized, and when applied to cosmetic formulations, the light transmittance of the blue region can be greatly reduced.
Keywords
artificial calamine powder; UV protection; blue band; planar-type ZnO; cosmetic formulation;
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  • Reference
1 A. Andersen, Annual review of cosmetic ingredient safety assessments, Int. J. Toxicol., 30(5), 73 (2011).   DOI
2 M. J. Cho, H. S. Jung, M. Y. Song, H. H. Seo, A. Kulkarni, S. S. Suh, T. K. Lee, and S. H. Moh, Effect of sun screen utilizing Porphyra-334 derived from Ocean Algae for skin protection, J. Korea Acad. Industr. Coop. Soc., 15(7), 4272 (2014).   DOI
3 W. Montagna, S. Kirchner, and K. Carlisle, Histology of sun-damaged human skin, J. Am. Acad. Dermatol., 21(5), 907 (1989).   DOI
4 I. Y. Kim and S. W. Kang, SPF measurement and cytotoxicity of sunscreen agents in cosmetic, Anal. Sci. Technol., 11(2), 79 (1998).
5 T. G. Sm ijs and S. Pavel, Titanium dioxide and zinc oxide nanoparticles in sunscreens: focus on their safety and effectiveness, Nanotechnol. Sci. Appl., 4, 95 (2011).   DOI
6 O. S. Kwon, E. J. Hwang, T. S. Lee, J. M. Park, K. H. Kim, and J. H. Chung, Effects of skin temperature on UV-induced erythema and pigmentation in human skin in vivo, Korean J. Dermatol., 41(3), 326 (2003).
7 J. Y. Seo, K. H. Cho, H. C. Eun, and J. H. Chung, Skin aging from phenotype to mechanism, Korean J. Invest. Dermatol., 8(4), 187 (2001).
8 E. H. Lim, J. Y. Hwang, and H. J. Kim, Study on the current use of sunscreen and the development of natural materials, Kor. J. Aesthet. Cosmetol., 11(3), 427 (2013).
9 J. H. Lee, G. S. Lee, E. N. Park, S. H. Hong, S. B. Kye, S. W. Kim, J. Y. Gwack, and H. C. Lee, Preparation and characterization of planar-type ZnO powder with high aspect ratio for application in ultraviolet- and heat-shield cosmetics, J. Nanosci. Nanotechnol., 21(3), 1897 (2021).   DOI
10 E. S. Jang, Recent progress in synthesis of plate-like ZnO and its applications: a review, J. Korean Ceram. Soc., 54(3), 167 (2017).   DOI
11 Z. R. Tian, J. A. Voigt, J. Liu, B. Mckenzie, and M. J. Modermott, Biomimetic arrays of oriented helical ZnO nanorods and columns, J. Am. Chem. Soc., 124(44), 12954 (2002).   DOI
12 D. R. Lee, Y. J. Hong, H. G. Kim, and C. S. Kang, Review on the harmfulness of UV irradiation, the regulations and the appropriate approaches for UV protection, JKSCC, 6(2), 223 (2016).
13 D. Q. Liu, Y. Liu, S. F. Han, Y. F. Zhang, and C. Y. Yin, Study on the calamine/sodium alginate modified viscose fiber, Advaned Materials Research, 418, 192 (2012).
14 E. S. Jang, X. Chen, J. H. Won, J. H. Chung, D. J. Jang, and J. H. Choy, Soft-solution route to ZnO nanowall array with low threshold power density, Appl. Phys. Lett., 97(4), 043109 (2010).   DOI
15 C. A. Downs, E. K. Winter, R. Segal, J. Fauth, S. Knutson, O. Bronstein, F. R. Ciner, R. Jeger, Y. Lichtenfeld, C. M. Woodley, P. Pennington, K. Cadenas, A. Kushmaro, and Y. Loya, Toxicopathological effects of the sunscreen UV filter, oxybenzone(benzophenone-), on coral planulae and cultured primary cells and its environmental contamination in Hawaii and the U. S. Virgin islands, Arch. Environ. Contam. Toxicol., 70(2), 265 (2016).   DOI
16 E. F. Mohamed, Nanotechnology: future of environmental air pollution control, Environ. Manage. Sustainable Dev., 6(2), 429 (2017).   DOI