• Title/Summary/Keyword: Sub-Elements

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Phase analysis of simulated nuclear fuel debris synthesized using UO2, Zr, and stainless steel and leaching behavior of the fission products and matrix elements

  • Ryutaro Tonna;Takayuki Sasaki;Yuji Kodama;Taishi Kobayashi;Daisuke Akiyama;Akira Kirishima;Nobuaki Sato;Yuta Kumagai;Ryoji Kusaka;Masayuki Watanabe
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1300-1309
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    • 2023
  • Simulated debris was synthesized using UO2, Zr, and stainless steel and a heat treatment method under inert or oxidizing conditions. The primary U solid phase of the debris synthesized at 1473 K under inert conditions was UO2, whereas a (U, Zr)O2 solid solution formed at 1873 K. Under oxidizing conditions, a mixture of U3O8 and (Fe, Cr)UO4 phases formed at 1473 K, whereas a (U, Zr)O2+x solid solution formed at 1873 K. The leaching behavior of the fission products from the simulated debris was evaluated using two methods: the irradiation method, for which fission products were produced via neutron irradiation, and the doping method, for which trace amounts of non-radioactive elements were doped into the debris. The dissolution behavior of U depended on the properties of the debris and aqueous solution for immersion. Cs, Sr, and Ba leached out regardless of the primary solid phases. The leaching of high-valence Eu and Ru ions was suppressed, possibly owing to their solid-solution reaction with or incorporation into the uranium compounds of the simulated debris.

Simulation of Rare Earth Elements Removal Behavior in TRU Product Using HSC Chemistry Code (HSC Chemistry 코드를 이용한 TRU 생성물 중의 희토류 원소 제거 거동 모사)

  • Paek, Seungwoo;Lee, Chang Hwa;Yoon, Dalsung;Lee, Sung-Jai
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.2
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    • pp.207-215
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    • 2020
  • The feasibility of rare earth (RE) removal process via oxidation reactions with UCl3 was investigated using the HSC Chemistry code to reduce the concentrations of RE in transuranic (TRU) products. The composition and thermodynamic data of TRU and RE elements contained in the reference spent fuel were examined. The reactivity was evaluated by calculating equilibrium data considering oxidation reactions with UCl3. Both RE removal rate and TRU recovery rate were evaluated for the two cases, wherein TRU products with different RE concentrations were used. When TRU products were reacted with UCl3, selective oxidation was driven by the difference in the Gibbs free energy of each element. The calculation results imply that the TRU/RE ratio of the final product can be increased by removing RE elements while maintaining the maximum recovery rate of TRU, which is accomplished by controlling the amount of UCl3 injected. Since the results of this study are based on thermodynamic equilibrium data, there are many limitations to apply to the actual process. However, it is expected to be used as an important data for the process design to supply the TRU product of pyroprocessing to SFR's fuel demanding low RE concentrations.

THE EXTENDIBILITY OF DIOPHANTINE PAIRS WITH PROPERTY D(-1)

  • Park, Jinseo
    • Korean Journal of Mathematics
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    • v.28 no.3
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    • pp.539-554
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    • 2020
  • A set {a1, a2, …, am} of m distinct positive integers is called a D(-1)-m-tuple if the product of any distinct two elements in the set decreased by one is a perfect square. In this paper, we find a solution of Pellian equations which is constructed by D(-1)-triples and using this result, we prove the extendibility of D(-1)-pair with some conditions.

Study on Reaction Behavior of Mg-FeB Phase for Rare Earth Elements Recovery from End-of-life Magnet

  • Sangmin Park;Dae-Kyeom Kim;Rongyu Liu;Jaeyun Jeong;Taek-Soo Kim;Myungsuk Song
    • Journal of Powder Materials
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    • v.30 no.2
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    • pp.101-106
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    • 2023
  • Liquid metal extraction (LME), a pyrometallurgical recycling method, is popular owing to its negligible environmental impact. LME mainly targets rare-earth permanent magnets having several rare-earth elements. Mg is used as a solvent metal for LME because of its selective and eminent reactivity with rare-earth elements in magnets. Several studies concerning the formation of Dy-Fe intermetallic compounds and their effects on LME using Mg exist. However, methods for reducing these compounds are unavailable. Fe reacts more strongly with B than with Dy; B addition can be a reducing method for Dy-Fe intermetallic compounds owing to the formation of Fe2B, which takes Fe from Dy-Fe intermetallic compounds. The FeB alloy is an adequate additive for the decomposition of Fe2B. To accomplish the former process, Mg must convey B to a permanent magnet during the decomposition of the FeB alloy. Here, the effect of Mg on the transfer of B from FeB to permanent magnet is observed through microstructural and phase analyses. Through microstructural and phase analysis, it is confirmed that FeB is converted to Fe2B upon B transfer, owing to Mg. Finally, the transfer effect of Mg is confirmed, and the possibility of reducing Dy-Fe intermetallic compounds during LME is suggested.

Chemical Composition of Respirable PM2.5 and Inhalable PM10 in Iksan City during Fall, 2004 (익산지역 가을철 대기 중 호흡성 및 흡입성 먼지입자의 화학조성)

  • Kang, Gong-Unn
    • Journal of Environmental Health Sciences
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    • v.36 no.1
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    • pp.61-71
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    • 2010
  • Intensive measurements of airborne respirable $PM_{2.5}$ and inhalable $PM_{2.5}$ were conducted in the downtown area of Iksan city. The $PM_{2.5}$ and $PM_{2.5}$ samples were collected twice a day in the Iksan city of Korea from October 17 to November 1, 2004. The purpose of the study was to determine the inorganic water-soluble components and trace elements of $PM_{2.5}$ and $PM_{2.5}$ in the atmospheric environment and estimate the contribution rate of major chemical components from a mass balance of all measured particulate species. The chemical analysis for PM samples was conducted for water-soluble inorganic ions using ion chromatography and trace elements using PIXE analysis. The mean concentrations of respirable $PM_{2.5}$ and inhalable $PM_{2.5}$ were $51.4{\pm}29.7$ and $79.5{\pm}39.6\;{\mu}g/m^3$, respectively, and the ratio was 0.62. The ion species of $NO_3$, $SO_4^2$, and $NH_4^+$ were abundant in both $PM_{2.5}$ and $PM_{2.5}$. These components predominated in respirable $PM_{2.5}$ fraction, while $Na^+$, $Mg^{2+}$, $Ca^{2+}$ mostly existed in coarse particle mode. Elemental components of S, Cl, K, and Si were abundant in both $PM_{2.5}$ and $PM_{2.5}$. These elements, except for Si, were considered to be emitted from anthropogenic sources, while Si, Al, Fe, Ca existed mainly in coarse particle mode and were considered to be emitted from crustal materials. The averaged mass balance analysis showed that ammonium nitrate, ammonium sulfate, crustal component, and other trace elements were composed of 18.4%, 13.2%, 4.8%, 3.5% for PM2.5 and 17.0%, 11.6%, 13.7%, 4.4% for $PM_{2.5}$, respectively.

Interpretation and application of information processing competency as mathematical competency: A case of middle school mathematics textbooks under the 2015 revised curriculum (수학과 교과역량으로서의 정보처리 능력의 해석과 적용: 2015 개정 중학교 수학 교과서를 중심으로)

  • Kim, Eun Hyun;Kim, Rae Young
    • The Mathematical Education
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    • v.59 no.4
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    • pp.389-403
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    • 2020
  • This study aims to examine how information processing competency as one of the mathematical competencies has been interpreted and applied in mathematics education by analyzing tasks in middle school mathematics textbooks under the 2015 revised national curriculum. Based on the sub-elements of information processing competency organized by Park et al.(2015), we analyzed 191 tasks in 30 different middle school mathematics textbooks using descriptive statistics and ANOVA. Also, we investigated the meaning of information processing competency embedded in the tasks by distinguishing the characteristics of several different types of tasks. The results from this study showed that the number of tasks related to information processing competency in mathematics textbooks was too small and there was a huge difference across the textbooks in terms of the sub-elements. Even though there were four sub-elements of information processing competency, 'the use of manipulative and technological tools' was extremely dominant in the tasks in general. Even many of them used technology and manipulatives superficially. Furthermore, any textbook did not provide tasks dealing with all the four sub-elements. Such an unbalanced and fragmented approach to information processing competency could produce biased knowledge and insufficient experiences for information processing competency. It calls for further investigation and discussion about how to improve information processing competency in school mathematics.

Long-term Characteristics of PM2.5 and Its Metallic Components in Chuncheon, Korea (춘천시 대기 중 PM2.5 및 금속성분의 장기간 농도 특성)

  • Byun, Jin-Yeo;Cho, Sung-Hwan;Kim, Hyun-Woong;Han, Young-Ji
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.3
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    • pp.406-417
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    • 2018
  • In this study, $PM_{2.5}$ samples were collected during approximately 3 years in Chuncheon, a small residential and tourist city, in Korea. The average $PM_{2.5}$ concentration was $26.9{\mu}g/m^3$, exceeding the annual national air quality standard. $PM_{2.5}$ showed typical seasonal variation, having higher concentration in winter and lower concentration in summer. Sixteen metallic elements in $PM_{2.5}$ were also analyzed, and K was the highest contributor especially in late fall and winter. In addition, K considerably increased for the top 10% of $PM_{2.5}$ samples and showed the highest correlation coefficient with $PM_{2.5}$ among all other metallic elements. These results suggest that the combustion of agricultural residue and other biomass, the major source of K was likely to be important to high $PM_{2.5}$ concentration events in this city. Crustal elements including Al, Fe, Si, Ti, Mg showed high concentration in spring while Cr, Cu and Ni were relatively consistent throughout a year. Principal component analysis was used to trace the sources, and soil re-suspension, combustion of biomass and fossil fuels, and asphalt concrete production were identified as the main sources of $PM_{2.5}$.

International Comparative Analysis on East Asian Top Level Countries' Mathematics Achievements in PISA 2012 Results (동아시아 상위 성취국의 PISA 2012 수학 결과 비교 분석)

  • Rim, Haemee
    • Journal of the Korean School Mathematics Society
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    • v.19 no.4
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    • pp.441-457
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    • 2016
  • The purpose of this study is to analyze Korean students' mathematics achievement characteristics and draw implications for better math education in schools through comparing the results of three east Asian top level countries, Korea, Singapore, and Japan in PISA 2012 results. As a results, the rate of correct answers of Korea students was relatively low compared with those of Singapore, but relatively higher than Japan. From the results of effect size, similar results from t-test was discovered. As shown in analysis according to sub-elements in math assessment framework, the Korean students had low effect size in every sub-elements than Singapore. and they had high effect size at most of sub-elements than Japan, except "personal" context. In top performing level(above level 5), the Korean students had high effect size at "quantities" in mathematical contents, and "employ" in mathematical processes compared with Singapore. And they had row effect size at 6 sub-elements compared with Japan.

A Basic Study on the Selection of Educational Contents for Cultivating Global Business Communication Competence (글로벌 비즈니스 커뮤니케이션 역량 배양을 위한 교육내용 개발에 대한 기초연구)

  • Kim, Bu-Ja
    • Journal of Digital Convergence
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    • v.17 no.2
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    • pp.91-100
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    • 2019
  • The purpose of this study was to provide basic data for the selection of educational contents when developing a course for cultivating global business communication competence. Reviewing previous studies on sub-elements of global competence, the researcher selected the sub-elements of global business communication competence. A survey was conducted on 148 employees of 20 companies regarding the importance of the sub-elements of global business communication competence. As a result, it was concluded that the sub-elements of relatively high importance-English email writing, reading and understanding of English materials and documents, telephone English, business English conversation, understanding of other cultures, communication skills, business knowledge-should be included in the educational contents of a course for cultivating global business communication competence.