• Title/Summary/Keyword: Strontium-containing

Search Result 29, Processing Time 0.026 seconds

Sr-containing Hydroxyapatite for Bone Replacement (골 대체재로의 스트론튬(Sr)이 고용된 Hydroxyapatite)

  • Choi, Jung-Sin;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Ceramic Society
    • /
    • v.45 no.10
    • /
    • pp.589-593
    • /
    • 2008
  • The hydroxyapatite with different amounts of strontium was synthesized with wet chemical technique. The structural, morphological and chemical characterizations for the prepared hydroxyapatite with various strontium amounts were carried out with XRD, SEM, EDS, and FT-IR. Strontium is quantitatively incorporated into hydroxyapatite where its substitution for calcium provokes a well distribution in the EDS mapping and a linear shift of the infrared absorption bands of the hydroxyl and phosphate groups, coherent with the greater ionic radius of strontium.

Selective separation of Strontium in the solution containing Calcium by Supported Liquid Membrane (함침형 액막을 이용한 Calcium 함유 용액으로부터 Strontium의 선택적 분리)

  • Choi, Young-Woo;Moon, Seung-Hyeon;Lee, Chang-Woo
    • Journal of Radiation Protection and Research
    • /
    • v.24 no.1
    • /
    • pp.9-15
    • /
    • 1999
  • In order to separate $Sr^{2+}$ selectively from environmental sample solutions containing $Ca^{2+}$, supported liquid membranes(SLM) were prepared and their characteristics of separation were investigated. The contents of carriers, DC18C6 and DNNS, in SLM affected the permeabilities of metal ions and selectivities of $Sr^{2+}$. The selectivity of $Sr^{2+}$ reached to 93.3% in a SLM with 0.1 M DC18C6 and 25 mM DNNS. When the ratio of $Sr^{2+}$ to $Ca^{2+}$ concentration in the feed solution was in the range of 1/25 to 1/50, the selectivity of $Sr^{2+}$ was greater than 90 %. Therefore, it is considered that the SLM prepared in this study is capable of treating environmental sea-water samples for strontium measurement.

  • PDF

Production of SrCO3 from SrSO4 through the Black Ash Process (Black Ash법을 이용한 SrSO4로부터 SrCO3 제조)

  • Kang, Jungshin;Lee, Jin-Young
    • Resources Recycling
    • /
    • v.30 no.5
    • /
    • pp.49-56
    • /
    • 2021
  • In this study, using strontium sulfate (SrSO4) recovered from magnetite ore in Hongcheon, the Black Ash process was used to produce strontium carbonate (SrCO3). In the carbothermic reaction step, SrSO4 was reacted with carbon (C) at 1273 K under Ar gas atmosphere using a gas-tight quartz reactor to produce strontium sulfide (SrS). Afterward, water leaching of the residues produced from the carbothermic reaction at 353 K and carbonation of the leaching solution using sodium carbonate (Na2CO3) at 298 K were conducted to produce SrCO3. The results of this study demonstrate the feasibility of the production of SrCO3 via the Black Ash process using domestic magnetite ore containing strontium (Sr).

Effect of Strontium Carbonate Content on Flexural Strength of Clay-Based Membrane Supports

  • Eom, Jung-Hye;Kim, Young-Wook;Song, In-Hyuck
    • Journal of the Korean Ceramic Society
    • /
    • v.52 no.6
    • /
    • pp.467-472
    • /
    • 2015
  • The effect of $SrCO_3$ content on the microstructure, porosity, flexural strength, and pore size distribution of clay-based membrane supports was investigated. Green compacts prepared from low cost materials such as kaolin, bentonite, talc, sodium borate, and strontium carbonate were sintered at $1000^{\circ}C$ for 8 h in air. It was possible to control the porosity of the clay-based membrane supports within the range of 33% to 37% by adjusting the $SrCO_3$ content. The flexural strength of the clay-based membrane supports was found to strongly depend on their porosity. In turn, the porosity was affected by the $SrCO_3$ content. The average pore size and flexural strength of the clay-based membrane supports containing 4 wt% $SrCO_3$ were $0.62{\mu}m$ and 33 MPa at 34% porosity.

The adsorption-desorption behavior of strontium ions with an impregnated resin containing di (2-ethylhexyl) phosphoric acid in aqueous solutions

  • Kalal, Hossein Sid;Khanchi, Ali Reza;Nejatlabbaf, Mojtaba;Almasian, Mohammad Reza;Saberyan, Kamal;Taghiof, Mohammad
    • Advances in environmental research
    • /
    • v.6 no.4
    • /
    • pp.301-315
    • /
    • 2017
  • An Amberlite XAD-4 resin impregnated with di(2-ethylhexyl)phosphoric acid was prepared and its adsorption-desorption behaviors with Sr(II) ions under various conditions was examined. The resin was characterized by fourier transform infrared and thermal analysis techniques. The effects contact time, temperature, pH, interfering ions and eluants were studied. Results showed that adsorption of Sr (II) well fitted with pseudo-second-order kinetic model. The equilibrium adsorption data of Sr (II) on the impregnated resin were analyzed by Jossens, Weber-van Vliet, Redlich-Peterson and Fritz-Schlunder models to find out desirable equilibrium condition. Among them, the Fritz-Schlunder model best fitted to the experimental data. The maximum sorption capacity of impregnated resin amounted to 0.45 mg/ g at pH 8.0 and $20^{\circ}C$.

Structural and Thermal Analysis and Membrane Characteristics of Phosphoric Acid-doped Polybenzimidazole/Strontium Titanate Composite Membranes for HT-PEMFC Applications

  • Selvakumar, Kanakaraj;Kim, Ae Rhan;Prabhu, Manimuthu Ramesh;Yoo, Dong Jin
    • Composites Research
    • /
    • v.34 no.6
    • /
    • pp.373-379
    • /
    • 2021
  • A series of novel PBI/SrTiO3 nanocomposite membranes composed of polybenzimidazole (PBI) and strontium titanate (SrTiO3) with a perovskite structure were fabricated with various concentrations of SrTiO3 through a solution casting method. Various characterization techniques such as proton nuclear magnetic resonance, thermogravimetric analysis, atomic force microscopy (AFM) and AC impedance spectroscopy were used to investigate the chemical structure, thermal, phosphate absorption and morphological properties, and proton conductivity of the fabricated nanocomposite membranes. The optimized PBI/SrTiO3-8 polymer nanocomposite membrane containing 8wt% of SrTiO3 showed a higher proton conductivity of 7.95 × 10-2 S/cm at 160℃ compared to other nanocomposite membranes. The PBI/SrTiO3-8 composite membrane also showed higher thermal stability compared to pristine PBI. In addition, the roughness change of the polymer composite membrane was also investigated by AFM. Based on these results, nanocomposite membranes based on perovskite structures are expected to be considered as potential candidates for high-temperature PEM fuel cell applications.

Recent Advances in the Removal of Radioactive Wastes Containing 58Co and 90Sr from Aqueous Solutions Using Adsorption Technology

  • Alagumalai, Krishnapandi;Ha, Jeong Hyub;Choi, Suk Soon
    • Applied Chemistry for Engineering
    • /
    • v.33 no.4
    • /
    • pp.352-366
    • /
    • 2022
  • Nuclear power plant operations for electricity generation, rare-earth mining, nuclear medical research, and nuclear weapons reprocessing considerably increase radioactive waste, necessitating massive efforts to eradicate radioactive waste from aquatic environments. Cobalt (58Co) and strontium (90Sr) radioactive elements have been extensively employed in energy generation, nuclear weapon testing, and the manufacture of healthcare products. The erroneous discharge of these elements as pollutants into the aquatic system, radiation emissions, and long-term disposal is extremely detrimental to humans and aquatic biota. Numerous methods for treating radioactive waste-contaminated water have emerged, among which the adsorption process has been promoted for its efficacy in eliminating radioactive waste from aquatic habitats. The current review discusses the adsorptive removal of radioactive waste from aqueous solutions using low-cost adsorbents, such as graphene oxide, metal-organic frameworks, and inorganic metal oxides, as well as their composites. The chemical modification of adsorbents to increase their removal efficiency is also discussed. Finally, the current state of 58Co and 90Sr removal performances is summarized and the efficiencies of various adsorbents are compared.