Browse > Article
http://dx.doi.org/10.12989/aer.2017.6.4.301

The adsorption-desorption behavior of strontium ions with an impregnated resin containing di (2-ethylhexyl) phosphoric acid in aqueous solutions  

Kalal, Hossein Sid (Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, AEOI)
Khanchi, Ali Reza (Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, AEOI)
Nejatlabbaf, Mojtaba (Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, AEOI)
Almasian, Mohammad Reza (Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, AEOI)
Saberyan, Kamal (Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, AEOI)
Taghiof, Mohammad (Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, AEOI)
Publication Information
Advances in environmental research / v.6, no.4, 2017 , pp. 301-315 More about this Journal
Abstract
An Amberlite XAD-4 resin impregnated with di(2-ethylhexyl)phosphoric acid was prepared and its adsorption-desorption behaviors with Sr(II) ions under various conditions was examined. The resin was characterized by fourier transform infrared and thermal analysis techniques. The effects contact time, temperature, pH, interfering ions and eluants were studied. Results showed that adsorption of Sr (II) well fitted with pseudo-second-order kinetic model. The equilibrium adsorption data of Sr (II) on the impregnated resin were analyzed by Jossens, Weber-van Vliet, Redlich-Peterson and Fritz-Schlunder models to find out desirable equilibrium condition. Among them, the Fritz-Schlunder model best fitted to the experimental data. The maximum sorption capacity of impregnated resin amounted to 0.45 mg/ g at pH 8.0 and $20^{\circ}C$.
Keywords
strontium removal; Amberlite XAD-4; di (2-ethylhexyl) phosphoric acid; isotherm study;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Prohl, G., Ehlken, S., Fiedler, I., Kirchner, G., Klemt, E. and Zibold, G. (2006), "Ecological half-lives of 90Sr and 137Cs in terrestrial and aquatic ecosystems", J. Environ. Radioact., 91(1-2), 41-72   DOI
2 Puziy, A.M. (1998), "Cesium and strontium exchange by the framework potassium titanium silicate K3HTi404 (SiO4)3"4H20", J. Radiaoanal. Nucl. Chem., 237(1-2), 73-79.   DOI
3 Raut, D.R., Mohapatra, P.K. and Manchanda, V.K. (2012), "A highly efficient supported liquid membrane system for selective strontium separation leading to radioactive waste remediation", J. Membr. Sci., 390, 76-83.
4 Schulz, W.W., Mendel, J.E. and Richardson, G.L. (1963), "Solvent extraction recovery and purification of strontium-90", Ind. Eng. Chem. Proc. Des. Dev., 2(2)134-140.   DOI
5 Schutz, W.W. (1968), Effects of some Synergistic and Antagonistic Agents on HDEHP Extraction of Strontium (No. BNWL--759), Pacific Northwest Lab, Battelle-Northwest, Richland, Washington, D.C., U.S.A.
6 Singh, K.K., Pathak, S.K., Kumar, M., Mahtele, A.K., Tripathi, S.C. and Bajaj, P.N. (2013), "Study of uranium sorption using D2EHPA-impregnated polymeric beads", J. Appl. Polym. Sci., 3355-3364
7 Sivaiah, M.V., Venkatesan, K.A., Krishna, R.M., Sasidhar, P. and Murthy, G.S. (2005), "Ion exchange properties of strontium on in situ precipitated polyantimonic acid in amberlite XAD-7", Sep. Purif. Technol., 44(1), 1-9.   DOI
8 Nielsen, S.P. (2004), "The biological role of strontium", Bone, 35(2), 583-588.   DOI
9 Makrlik, E., Vanura, P., Selucky, P. and Spichal, Z.K. (2010), "Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and 2,6-(diphenylphosphino) pyridine dioxide", Acta Chimica Slovenica, 58, 860-865.
10 Mazhar, M. (2009), "Potassium iron (III) hexacyanoferrate (II) supported on polymethylmethacrylate ionexchanger for removal of strontium (II)", J. Radiaoanal. Nucl. Chem., 281(3), 393-403.   DOI
11 Peppard, D.F., Ferraro, J.R. and Mason, G.W. (1985), "Hydrogen bonding in organophosphoric acids", J. Inorg. Nucl. Chem., 7(3), 231-244.   DOI
12 Bilgin, B., Atun, G. and Keceli, G. (2001), "Adsorption of strontium on illite", J. Radiaoanal. Nucl. Chem., 250(2), 323-328.   DOI
13 Zhang, L., Zhou, J., Zhou, D. and Tang, Y. (1999), "Adsorption of cadmium and strontium on cellulose/alginic acid ion-exchange membrane", J. Membr. Sci., 162(1-2), 103-109.   DOI
14 Solecki, J. and Michalik, S. (2006), "Studies of 85Sr adsorption on grain fractions of soil", J. Radiaoanal. Nucl. Chem., 267(2), 271-278.   DOI
15 Tripathi, A., Medvedev, D.G., Nyman, M. and Clearfield, A. (2003), "Clearfield Selectivity for Cs and Sr in Nb-substituted titanosilicate with sitinakite topology", J. Solid State Chem., 175(1), 72-83.   DOI
16 Ye, X., Liu, T., Li, Q., Liu, H. and Wu, Z. (2008), "Comparison of strontium and calcium adsorption onto composite magnetic particles derived from Fe3O4 and bis(trimethoxysilylpropyl)amine", Colloid. Surface. A Physicochem. Eng. Asp., 330(1), 21-27.   DOI
17 Cakir, P., Inan, S. and Altas, Y. (2014), "Investigation of strontium and uranium sorption onto zirconiumantimony oxide/polyacrylonitrile (Zr-Sb oxide/PAN) composite using experimental design", J. Hazard. Mater., 271, 108-119.   DOI
18 Chaudry, M.A. and Ahmad, I. (1994), "Extraction and stripping study strontium ions across D2EHPA-TBP-Kerosene oil based supported liquid membrane", J. Radiaoanal. Nucl. Chem., 185(2), 369-385.   DOI
19 Chen, P.Y. (2007), "The assessment of removing strontium and cesium cations from aqueous solutions based on the combined methods of ionic liquid extraction and electrodeposition", Electrochimica Acta, 52(17), 5484-5492.   DOI
20 Chen, J.H., Chen, W.R., Gau, Y.Y. and Lin, C.H. (2003), "The preparation of di(2-ethylhexyl) phosphoric acid modified Amberlite 200 and its application in the separation of metal ions from sulfuric acid solution", React. Funct. Polym., 56(3), 175-188.   DOI
21 Hafizi, M., Abolghasemi, H., Moradi, M. and Milani, S.A. (2011), "Strontium adsorption from sulfuric acid solution by Dowex 50W-X resins", Chin. J. Chem. Eng., 19(2), 267-272.   DOI
22 Ding, S.D., Yang, T., Liu, N. and Zhang, L. (2010), "Extraction behavior of strontium from nitric acid solution with N,N, N',N'-tetraisobutyl diglycolamide", J. Iran. Chem. Soc., 7, 545-553   DOI
23 Greve, K., Nielsen, E. and Ladefoged, O. (2007), "Evaluation of health hazards by exposure to strontium in drinking water", Toxicol. Lett., 172(S210).
24 Grynpas, M.D., Hamilton, E., Cheung, R., Tsouderos, Y., Deloffre, P., Hott, M. and Marie, P.J. (1996), "Strontium increases vertebral bone volume in rats at a low dose that does not induce detectable mineralization defect", Bone, 18(3), 253-259.   DOI
25 Heilgeist, M. (2000), "Use of extraction chromatography, ion chromatography and liquid scintillation spectrometry for rapid determination of strontium-89 and strontium-90 in food in cases of increased release of radionuclides", J. Radiaoanal. Nucl. Chem., 245(2), 249-254.   DOI
26 Jeong, S.K. and Ju, C.S. (2002), "Extraction of strontium ion from sea water by contained liquid membrane permeator", Kor. J. Chem. Eng., 19(1), 93-98.   DOI
27 Kocherginsky, N.M., Zhang, Y.K. and Stucki, J.W. (2002), "D2EHPA based strontium removal from strongly alkaline nuclear waste", Desalination, 144(1-3), 267-272.   DOI