• Corrosion Science and Technology
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• 제19권5호
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• pp.259-264
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• 2020

Many studies have been conducted to improve the corrosion resistance and durability of various aluminum alloys through the anodizing technique. It is already used as a unique technique for enhancing the properties of aluminum alloys in various industries. This paper investigated the electrochemical corrosion and stress corrosion cracking characteristics of anodized aluminum 5083-H321 alloy in natural seawater. The corrosion characteristics were assessed by the electrochemical technique and potentiodynamic polarization test. The stress corrosion cracking characteristic was evaluated with a slow strain rate tensile test under 0.005 mm/min rate, which showed that the hard anodizing film had a thickness of about 16.8 ㎛. Although no significant characteristics of stress corrosion cracking were observed in the slow strain rate test, the anodized specimen presented excellent corrosion resistance. The corrosion current density was measured to be approximately 4.2 times lower than that of the base material, and no surface damage was observed in the anodic polarization test.

• Ocean Systems Engineering
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• 제1권2호
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• pp.121-130
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• 2011

One of the prevailing models that describe the stress corrosion is represented by an exponential dependence between rate of corrosion and stress, suggested by Gutman, Zainullin and Zuripov. This study revisits the exponential model and derives analytical expressions for the structures' durability which is postulated as the time for stress level to reach its yield value. Comparison is conducted with other possible models, namely with linear, quadratic or cubic cases.

• Corrosion Science and Technology
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• 제6권1호
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• pp.29-32
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• 2007

The final goal of this study is to develop the core technologies applicable to the design, operation and maintenance of welds in nuclear structures. This study includes predicting microstructure changes and residual stress for welded parts of nuclear power plant components. Furthermore, researches are performed on evaluating fatigue, corrosion, and hydrogen induced cracking and finally constructs systematically integrated evaluation system for structural integrity of nuclear welded structures. In this study, metallurgical and mechanical approaches have been effectively coordinated considering real welding phenomena in the fields of welds properties such as microstructure, composition and residual stress, and in the fields of damage evaluations such as fatigue, corrosion, fatigue crack propagation, and stress corrosion cracking. Evaluation techniques tried in this study can be much economical and effective in that it uses theoretical/semi-empirical but includes many additional parameters that can be introduced in real phenomena such as phase transformation, strength mismatch and residual stress. It is clear that residual stress makes great contribution to fatigue and stress corrosion cracking. Therefore the mitigation techniques have been approached by reducing the residual stress of selected parts resulting in successful conclusions.

• Journal of Welding and Joining
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• 제14권2호
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• pp.36-45
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• 1996

Fatigue strength of the spot welded lap joint is considerably influenced by corrosive environments. Particularly, the chloride and the sulfide are most injurious to strength of the spot welded lap joint. Therefore, there is a need to evaluate its effect to corrosion fatigue strength for safe life design of spot welded structures. In order to evaluate their corrosion fatigue strength, corrosion fatigue tests on the spot welded lap joints of the uncoated and the coated high strength steel sheets were conducted in air and in 10% NaCl solution. Corrosion fatigue strength of the uncoated specimens were entirely lower than the coated one in NaCl solution, but those of the coated specimens in NaCl solution were lower than in air. And stress distribution in single spon welded lap joint subjected to tension-shear load was investigated by the finite element method. Using these results, we tried to evaluate corrosion fatgue strength of the various spot welded lap joints with maximum stress $\sigma_{max}$ at edge on loading side of the spot welded lap joint. We could find that corrosion fatigue strength could be quantitatively and systematically rearranged by $\sigma_{max}$.

• 한국표면공학회지
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• 제37권6호
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• pp.350-359
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• 2004

Stress corrosion cracking(SCC) characteristics of shot-peened stainless steel containing Ti (0.09 wt%-0.92 wt%) fabricated by the vacuum furnace were investigated using SCC tester and potentiostat. The homogenization and the sensitization treatment were carried out at $1050^{\circ}C$ for 1hr and $650^{\circ}C$ for 5 hr. The samples for SCC were shot-peened using $\Phi$0.6 mm steel ball for 4 min and 10 min. Intergranular and pitting corrosion characteristics were investigated by using EPR and CPPT. SCC test was carried out at the condition of$ 288^{\circ}C$, 90 kgf pressure, water with 8 ppm dissolved oxygen, and $8.3xl0^{-7}$/s strain rate. After the corrosion and see test, the surface of the tested specimen was observed by the optical microscope, TEM and SEM. Specimen with Ti/C ratio of 6.14 showed high tensile strength at the sensitization treatment. The tensile strength decreased with the increase of the Ti/C ratio. Pitting and intergranular corrosion resistance increased with the increase of Ti/C ratio. Stress corrosion cracking strength of shot-peened specimen was higher than that of non shot- peened specimen. Stress corrosion cracking strength decreased with the increase of the Ti/C ratio.

• 수산해양기술연구
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• 제33권3호
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• pp.194-201
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• 1997

Recently with the rapid development in the industries such as an iron mill and chemical plants, these are enlarged by the use of the piping. This piping was encountered the stress corrosion cracking(SCC) because of stress by water pressure and residual stress of welding etc. under industrial water. In this paper, the behaviour of stress corrosion cracking on the weld zone of steel pipe piping water(SPPW) were investigated according to pre-heat before welding in natural seawater(specific resistance : 25$\Omega$-cm). The main results obtained are as follows :1) The stress corrosion cracking for SPPW and SB 41 is most ready to propagate in heat affected zone of weldment. 2) The SCC sensitivity of SPPW on weldment is more susceptible than that of SB 41. 3) The stress corrosion cracking growth of heat affected zone is delayed by the preheat and dry of base metal and electrode before welding.

• 수산해양기술연구
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• 제39권4호
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• pp.291-297
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• 2003

Al-brass is usually used as the tube material of vessel's heat exchanger for seawater cooling system because it has high thermal conductivity and good mechanical properties and high corrosion resistance due to cuprous oxide (Cu20) layer against seawater. However, Al-brass tubes of heat exchanger for vessel at the actual environment is reported that local corrosion such as stress corrosion cracking occurred by synergism effect between mechanical factor and corrosion environment In this paper, the effect of corrosion environment on the stress corrosion cracking of Al-brass in various NH4OH of 3.5% NaCl solution, under flow by constant displacement tester. Based on the test results, the behavior of polarization, stress corrosion crack propagation and dezincification phenomenon of Al-brass are investigated. The main results are as follows：(1) Increasing range of potential from open circuit potential to repassivation gets lower, as the contain rate of NH4OH gets higher. (2) As contain rate of NH4OH gets higher, SCC of Al-brass is become activation but the protection film(Cu20) of Al-brass is created in 3.5% NaCl solution. (3) According as content of NH4OH increases in 3.5% NaCl solution, the dezincifiction area is spread. It is concluded that dezincification occurred by localized preferential anodic dissolution at stress focusing region.

• 한국표면공학회지
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• 제57권3호
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• pp.192-200
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• 2024

Cu as a heat exchanger tube is an important component in thermal fluid transfer. However, Cu tubes are exposed to stress in certain environments, leading to stress corrosion cracking (SCC). In this study, the effect of Sn addition on microstructure and corrosion characteristics was examined. The microstructural examination revealed the presence of columnar crystal and a grain refinement due to the addition of Sn. Electrochemical measurements showed that the 5 wt.% NH₃ environment was the most vulnerable environment to Cu corrosion, and the corrosion current density increased as stress increased. The immersion test exhibited the formation of Cu2O and Cu(OH)₂ corrosion product in 3.5 wt.% NaCl and 5 wt.% NH₃ environments, respectively. Results indicated that Sn addition to Cu was an important factor in improving the mechanical strength.

• Steel and Composite Structures
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• 제48권1호
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• pp.27-41
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• 2023

Under the long-term effect of corrosive environment, many cold-formed steel (CFS) structures have serious corrosion problems. Corrosion leads to the change of surface morphology and the loss of section thickness, which results in the change of instability mode and failure mechanism of CFS structure. This paper mainly investigates the elastic local buckling behavior of corroded CFS columns. The surface morphology scanning test was carried out for eight CFS columns accelerated corrosion by the outdoor periodic spray test. The thin shell finite element (FE) eigen-buckling analysis was also carried out to reveal the influence of corrosion surface characteristics, corrosion depth, corrosion location and corrosion area on the elastic local buckling behaviour of the plates with four simply supported edges. The accuracy of the proposed formulas for calculating the elastic local buckling stress of the corroded plates and columns was assessed through extensive parameter studies. The results indicated that for the plates considering corrosion surface characteristics, the maximum deformation area of local buckling was located at the plates with the minimum average section area. For the plates with localized corrosion, the main buckling shape of the plates changed from one half-wave to two half-wave with the increase in corrosion area length. The elastic local buckling stress decreased gradually with the increase in corrosion area width and length. In addition, the elastic local buckling stress decreased slowly when corrosion area thickness was relatively large, and then tends to accelerate with the reduction in corrosion area thickness. The distance from the corrosion area to the transverse and longitudinal centerline of the plate had little effect on the elastic local buckling stress. Finally, the calculation formula of the elastic local buckling stress of the corroded plates and CFS columns was proposed.

• 한국해양공학회지
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• 제1권2호
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• pp.93-100
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• 1987

Corrosion fatigue cracking of the austenitic stainless steel(bese metal & heat affected zone by TIG weld) was studied experimentally under the environments of various specific resistance and air. The characteristics of corrosion fatigue crack growth rate and the environmental constants of paris' rule were investigated for SUS 304 weldments in the various specific resistance. The influences of stress intensity factor range and corrosion on the crack growth rate were compared. The characteristics of corrosion fatigue cracking for the weldments were inspected from mechanical, electrochemical and microstructural point of view. Main results obtained are as follows: 1) As the specific resistance decreases, the environmental constant C of paris'rule increases(hence the corrosion fatigue crack growth rate is rapid), but the environmental constant m decreases, so the effect of corrosion to the crack growth rate is more susceptible than thet of stress intensity factor range. 2) As the stress intensity factor range decreases, the corrosion fatigue crack growth rate of heat affected zone is more susceptible than that of the base metal. 3) The corrosion fatigue crack growth rate of the heat affected zone is more rapid than that of the base metal, because of the phenomenon of softening and the less noble potential coused by wedlding heat cycle. 4) The corrosion fatigue cracking of SUS 304 weldment appears transgranular fracture.