• 제목/요약/키워드: Specific surface are

검색결과 1,400건 처리시간 0.035초

Solid-state sintering mechanism of blended elemental Ti-6Al-4V powders

  • Kim, Youngmoo;Song, Young-Beom;Lee, Sung Ho
    • 한국분말재료학회지
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    • 제25권2호
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    • pp.109-119
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    • 2018
  • The objective of this study is to reveal the sintering mechanism of mixed Ti-6Al-4V powders considering the densification and the homogenization between Ti and Al/V particles. It is found that the addition of master alloy particles into Ti enhances densification by the migration of Al into the Ti matrix prior to the self-diffusion of Ti. However, as Ti particles become coarser, sintering of the powders appears to be retarded due to slower inter-diffusion of the particles due to the reduced surface energies of Ti. Such phenomena are confirmed by a series of dilatometry tests and microstructural analyses in respect to the sintering temperature. Furthermore, the results are also consistent with the predicted activation energies for sintering. The energies are found to have decreased from 299.35 to $135.48kJ{\cdot}mol^{-1}$ by adding the Al/V particles because the activation energy for the diffusion of Al in ${\alpha}-Ti$ ($77kJ{\cdot}mol^{-1}$) is much lower than that of the self-diffusion of ${\alpha}-Ti$. The coarser Ti powders increase the energies from 135.48 to $181.16kJ{\cdot}mol^{-1}$ because the specific surface areas of Ti decrease.

Development of a reference framework to assess stylized human intrusion scenarios using GENII Version 2 considering design features of planned near-surface disposal facility in Korea

  • Kwon, Ki Nam;Cheong, Jae Hak
    • Nuclear Engineering and Technology
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    • 제51권6호
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    • pp.1561-1574
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    • 2019
  • A standard form of six stylized human intrusion scenarios for a near-surface disposal facility (e.g. the planned Korean repository, Gyeongju Phase II) is proposed through re-categorization of totally thirty-one past cases reported in public literature. A reference assessment framework for inadvertent human intrusion is newly developed using GENII Version 2 conforming to the ICRP Publication 60 and thereafter. Calculated dose from the assessment framework is verified by comparing with hand calculation results for simplified model equations independently derived. Results from GENII Version 2 and 1.485 show inevitable differences, which is mainly attributed to the difference in the external dose assessment model. If intake dose coefficients in GENII Version 1.485 are modified, the difference can be reduced but still exist to an extent. Through deterministic and probabilistic sensitivity analysis, most affecting four parameters are derived and uncertainties of the parameters are quantified. It is expected that the reference assessment framework together with representative stylized scenarios can be used to do a human intrusion impact assessment for a specific repository using site-specific information. Especially, the past practice of human intrusion impact assessment using GENII Version 1.485 with or without modification may be replaced with the new assessment framework developed in this study.

제조조건에 따른 활성탄의 특성 및 수은 흡착 효율 (Physical Property with the Manufacturing Conditions of Activated Carbon for Mercury Adsorption)

  • 민효기;아흐마드 탄비어;박민;이상섭
    • 한국대기환경학회지
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    • 제31권3호
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    • pp.302-314
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    • 2015
  • There is an adsorption method using activated carbon as a typical method for removing elemental mercury. Physical characteristics of activated carbon such as specific surface area and volume of pore (micro and meso) have positive effect for mercury adsorption. Activated carbon is carbon-based material with a high specific surface area. This activated carbon can be manufactured through carbonization and activation process. In this process, physical characteristics of specific surface area and pore distribution are changed by controlling operating parameters like temperature, time and reagent of activation. In this study, we evaluated characteristics of activated carbons manufactured from pinewood and coal with the operating parameters. We evaluated mercury adsorption capacities of the activated carbons having excellent physical characteristics and compared those to the commercial activated carbon.

탄소섬유의 KOH 활성화와 휘발성 유기화합물(VOC)의 흡착특성 (Activation of Carbon Fibers by KOH and Adsorption Characteristics for VOC)

  • 장진석;김인기;임굉;조성준
    • 한국재료학회지
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    • 제9권4호
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    • pp.362-367
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    • 1999
  • We intended to make the activated carbon fibers which could separate, remove and recover the volatile organic compounds of benzene, toluene, acetone and methanol. Changing activation temperature and time, large specific surface area and narrow pore distribution could be obtained. The activated carbon fibers have large adsorption capacity and selectivility for those organic compounds. We characterized the adsorption capability of the activated carbon fibers for benzene, toluene, acetone and methanol by BET specific surface area and pore size and micropore volume measurements. In the result of activation, the maximum value of BET specific surface area of the fibers was $1100\m^2$/g at $800^{\circ}C$ for 60 minutes and $K_2$O was reduced actively in this condition. Their average pore size was 5.8~5.9$\AA$. The activated carbon fibers prepared in this work had high adsorption rate to saturation and the selectibility for the above organic compounds. The adsorbed amount of acetone and methanol(diameter of$ 4.3\AA$ and $4.4\AA$ respectively) which are smaller than micropore diameter in size was 43~49%, which was larger value than benzene and toluene(in the same diameter as $5.9\AA$).

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Protein G를 포함하는 수정미소저울 센서 칩과 정제되지 않은 항혈청을 이용한 헵토글로빈과 트랜스페린의 면역분석 (Immunoassay of haptoglobin and transferrin with proteinG-containing QCM sensor chip and unpurified antiserum)

  • 하인영;최석정
    • 센서학회지
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    • 제17권5호
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    • pp.380-386
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    • 2008
  • Quartz crystal microbalance immunosensor has a capacity to perform a label-free and real time detection of a trace amount of analyte through the specific interaction between antibody and antigen. However, immobilization of antibody molecules on the sensor surface is a troublesome procedure for researchers who are not experienced in chemistry. Protein G has a specific affinity to antibody and would serve as a capturing agent for antibody when immobilized on the sensor surface. In this work, we prepared a protein G sensor chip by immobilizing protein G on the surface of quartz crystal microbalance and examined its capability to detect human haptoglobin or human transferrin with unpurified corresponding antiserum. Specific and dose dependent response was observed when the protein G chip was used for detection of antigens after saturated with antiserum. We also verified several advantageous aspects of the protein G chip such as improved flexibility and sensitivity.

선체 곡면의 자동 요소화 (Automatic mesh generation on ship hull surface)

  • 윤태경;김동준
    • 한국해양공학회지
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    • 제11권2호
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    • pp.138-144
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    • 1997
  • This is describes the automatic mesh generation on the ship hull surface. At first ship hull is defined as a cillocation of composite surface patches which satisfy the geometic continuity between adjoining patches by using Gregory surface method. Node points that would be mesh points are ganerated by considering the surface curvature. The triangulation of the node points is by the combination of Ohtsubo's method and Choi's one. After triangulation, shape improvement and quadrilateralization is done with specific criterin. An application to the actual ship and the results are shown.

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근접장 주사 광학 현미경을 이용한 표면 플라즈몬의 측정 (Measurement of surface plasmon using near-field scanning optical microscope)

  • 고선아;이관수;박승룡;윤재웅;송석호;김필수;오차환
    • 한국광학회지
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    • 제15권1호
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    • pp.51-55
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    • 2004
  • 표면 플라즈몬은 금속 표면에 존재하는 자유전자의 밀도파이며, 광자와 결합하여 존재한다. 본 논문에서는 근접장 주사 광학 현미경을 구성하고 이를 이용하여 표면에서 지수함수적으로 감소하는 표면 플라즈몬과 두 표면 플라즈몬에 의한 간섭무늬를 측정하였다. 표면 플라즈몬은 표면의 작은 광학적 분포에도 민감하게 변화하여, 광학 탐침이 금속 표면에 접근함에 따라서 표면 플라즈몬의 공명 조건에 영향을 준다. 이로 인해 광학 탐침이 금속 표면으로부터 약 250nm 떨어진 곳에서 광의 세기가 최대가 됨을 확인하였다.

RP 공정의 정밀도 비교 평가 (Comparison of Accuracy of RP Processes)

  • 변홍석;신행재;이관행
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2000년도 추계학술대회 논문집
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    • pp.330-333
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    • 2000
  • Dimensional accuracy and surface quality are very important in rapid prototyping especially when the models are used for the production of tools. This paper presents the development of benchmarking part to investigate dimensional accuracy and surface finish. A new test part is designed to perform benchmarking of major rapid prototyping processes such as selective laser sintering, laminated object manufacturing, stereolithography apparatus, and fused deposition modeling. The test part design includes basic manufacturing features such as holes, walls, squares, cylinder and etc. In addition, the small features are included in order to evaluate the fine details that can be manufactured by a specific RP process. The CMM program that automatically measures different features in the test part is also developed. The evaluation of accuracy as well as surface roughness are discussed for major rapid prototyping processes.

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Convenient Preparation of Tumor-specific Immunoliposomes Containing Doxorubicin

  • Nam, Sang-Min;Cho, Jang-Eun;Son, Byoung-Soo;Park, Yong-Serk
    • BMB Reports
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    • 제31권1호
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    • pp.95-100
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    • 1998
  • Two innovative methods to prepare target-sensitive immunoliposomes containing doxorubicin by coupling monoclonal antibodies (mAb DH2, SH1) specific to cancer cell surface antigens ($G_{M3}$, $Le^X$) have been developed and are described here. Firstly, liposomes containing N-glutaryl phosphatidylethanolamine (NGPE) were prepared, followed by the encapsulation of doxorubicin, DH2 or SH1 antibodies were conjugated to NGPE in the liposomes (direct coupling). Secondly, liposomes were prepared with NGPE/mAb conjugates by the detergent dialysis method (conjugate insertion), and then doxorubicin was encapsulated by proton gradient. The immunoliposomes prepared by both methods were able to specifically bind to the surface of the tumor cells - B16BL6 mouse melanoma cells. The efficiencies of doxorubicin-entrapping into liposomes prepared by direct coupling and conjugate insertion was about 98% and 25%, respectively. These types of liposomal formulation are sensitive to target cells, which can be useful for various clinical applications.

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탄소섬유 에폭시 복합재료의 정밀드릴가공 특성에 관한 연구 (A Study on Precise Drilling Characteristics of Carbon Fiber Epoxy Composite Materials)

  • 김홍배
    • 한국정밀공학회지
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    • 제15권10호
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    • pp.203-208
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    • 1998
  • Carbon fiber epoxy composite materials are widely used in the structures of aircrafts, robots and other machines because of their high specific strength, high specific stiffness and high damping. In order for the composite materials to be used in the aircraft structures or machine elements, accurate surfaces for bearing mounting or joints must be provided, which require precise machining. In this paper, the machinability characterisitcs of the drilling operation of the carbon fiber epoxy composite materials was experimentally investigated. The experimental results are as follows 1.The entrance of hole is very good manufacturing existing, but exit come to occur sever surface exfoliation. 2. The cutting force in drilling of the carbon fiber epoxy composite materials is decreased as the drilling speed increased. 3.The hole of the carbon fiber epoxy composite materials is not good manufacturing by use of the standard twist, therefore, the new drill designed in order to accurate hole.

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