• 제목/요약/키워드: Specific Film Thickness

검색결과 90건 처리시간 0.027초

Enhancement of Power Conversion Efficiency from Controlled Nanostructure in Polymer Bulk-Hetero Junction Solar Cells

  • Wang, Dong-Hwan;Park, O-Ok;Park, Jong-Hyeok
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.76-76
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    • 2011
  • Polymer-fullerene based bulk heterojunction (BHJ) solar cells can be fabricated in large area using low-cost roll-to-roll manufacturing methods. However, because of the low mobility of the BHJ materials, there is competition between the sweep-out of the photogenerated carriers by the built-in potential and recombination within the thin BHJ film [12-15]. Useful film thicknesses are limited by recombination. Thus, there is a need to increase the absorption by the BHJ film without increasing film thickness. Metal nanoparticles exhibit localized surface plasmon resonances (LSPR) which couple strongly to the incident light. In addition, relatively large metallic nanoparticles can reflect and scatter the light and thereby increase the optical path length within the BHJ film. Thus, the addition of metal nanoparticles into BHJ films offers the possibility of enhanced absorption and correspondingly enhanced photo-generation of mobile carriers. In this work, we have demonstrated several positive effects of shape controlled Au and Ag nanoparticles in organic P3HT/PC70BM, PCDTBT/PC70BM, Si-PCPDTBT/PC70BM BHJ-based PV devices. The use of an optimized concentration of Au and Ag nanomaterials in the BHJ film increases Jsc, FF, and the IPCE. These improvements result from a combination of enhanced light absorption caused by the light scattering of the nanomaterials in an active layer. Some of the metals induce the plasmon light concentration at specific wavelength. Moreover, improved charge transport results in low series resistance.

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Blistering Induced Degradation of Thermal Stability Al2O3 Passivation Layer in Crystal Si Solar Cells

  • Li, Meng;Shin, Hong-Sik;Jeong, Kwang-Seok;Oh, Sung-Kwen;Lee, Horyeong;Han, Kyumin;Lee, Ga-Won;Lee, Hi-Deok
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제14권1호
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    • pp.53-60
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    • 2014
  • Different kinds of post-deposition annealing (PDA) by a rapid thermal process (RTP) are used to enhance the field-effect passivation of $Al_2O_3$ film in crystal Si solar cells. To characterize the effects of PDA on $Al_2O_3$ and the interface, metal-insulator semiconductor (MIS) devices were fabricated. The effects of PDA were characterized as functions of RTP temperature from $400{\sim}700^{\circ}C$ and RTP time from 30~120 s. A high temperature PDA can retard the passivation of thin $Al_2O_3$ film in c-Si solar cells. PDA by RTP at $400^{\circ}C$ results in better passivation than a PDA at $400^{\circ}C$ in forming gas ($H_2$ 4% in $N_2$) for 30 minutes. A high thermal budget causes blistering on $Al_2O_3$ film, which degrades its thermal stability and effective lifetime. It is related to the film structure, deposition temperature, thickness of the film, and annealing temperature. RTP shows the possibility of being applied to the PDA of $Al_2O_3$ film. Optimal PDA conditions should be studied for specific $Al_2O_3$ films, considering blistering.

Therapeutic Proton Beam Range Measurement with EBT3 Film and Comparison with Tool for Particle Simulation

  • Lee, Nuri;Kim, Chankyu;Song, Mi Hee;Lee, Se Byeong
    • 한국의학물리학회지:의학물리
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    • 제30권4호
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    • pp.112-119
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    • 2019
  • Purpose: The advantages of ocular proton therapy are that it spares the optic nerve and delivers the minimal dose to normal surrounding tissues. In this study, it developed a solid eye phantom that enabled us to perform quality assurance (QA) to verify the dose and beam range for passive single scattering proton therapy using a single phantom. For this purpose, a new solid eye phantom with a polymethyl-methacrylate (PMMA) wedge was developed using film dosimetry and an ionization chamber. Methods: The typical beam shape used for eye treatment is approximately 3 cm in diameter and the beam range is below 5 cm. Since proton therapy has a problem with beam range uncertainty due to differences in the stopping power of normal tissue, bone, air, etc, the beam range should be confirmed before treatment. A film can be placed on the slope of the phantom to evaluate the Spread-out Bragg Peak based on the water equivalent thickness value of PMMA on the film. In addition, an ionization chamber (Pin-point, PTW 31014) can be inserted into a hole in the phantom to measure the absolute dose. Results: The eye phantom was used for independent patient-specific QA. The differences in the output and beam range between the measurement and the planned treatment were less than 1.5% and 0.1 cm, respectively. Conclusions: An eye phantom was developed and the performance was successfully validated. The phantom can be employed to verify the output and beam range for ocular proton therapy.

Carbon Nanotube Film을 이용한 액체 전기화학 센서 (Liquid electrochemical sensors using carbon nanotube film)

  • 노재하;안상수;이창한;이상태;이문진;서동민;장지호
    • 센서학회지
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    • 제30권4호
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    • pp.255-260
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    • 2021
  • We studied electrochemical sensors using printed carbon nanotube (CNT) film on a polyethylene terephthalate (PET) substrate. Multiwalled CNT films were printed on a PET substrate to study its feasibility as hazardous and noxious substances (HNS) detection sensor. The printed CNT film (PCF) with a 50 ㎛ thickness exhibited a specific resistance of 230 ohm. To determine the optimum sensor structure, a resistance-type PCF sensor (R-type PCF sensor) and a conductive-type PCF sensor (C-type PCF sensor) were fabricated and compared using diluted NH3 droplets with various concentrations. The response magnitude, response time, sensitivity, linearity, and limit of detection (LOD) were compared, and it was concluded that the C-type PCF sensor exhibited superior performance. By applying a C-Type PCF sensor, we confirmed the detection performance of 12 types of floating HNS and the response of the sensor with selectivity according to the degree of polarity.

전착법을 이용한 슈퍼커패시터용 다공성 Co(OH)2 나노플레이크 박막의 제조 및 전기화학적 특성 (Electrochemical Properties of Porous Co(OH)2 Nano-flake Thin Film Prepared by Electro-deposition for Supercapacitor)

  • 이현정;김은미;정상문
    • Korean Chemical Engineering Research
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    • 제54권2호
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    • pp.157-162
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    • 2016
  • 다공성 $Co(OH)_2$ 나노플레이크 박막은 전위제어 전착법을 이용하여 티타늄 메쉬에 여러 전착전위(-0.75, -1.0, -1.2 및 -1.4 V)에서 전착하여 슈퍼커패시터에 이용하였다. 티타늄 메쉬에 전착된 $Co(OH)_2$ 나노플레이크 박막의 두께 및 전착량은 전착전위의 제어에 의해 결정되었고 -1.4 V에서 전착한 $Co(OH)_2$ 나노플레이크 박막의 두께는 약 $34{\mu}m$로 가장 두껍게 전착되었으며 전착량은 17.2 g이다. 전착전위 -0.75, -1.0, -1.2 및 -1.4 V에서 전착한 경우 초기 방전용량은 각각 226, 370, 720 그리고 $1,008mF\;cm^{-2}$으로 나타났고 1,000 사이클 후 각각 206, 349, 586 그리고 $866mF\;cm^{-2}$으로 나타났다. 또한 이들의 용량유지율은 각각 91, 94, 81 및 86%로 나타났다.

전자선치료 시 3D 프린터로 제작한 환자 맞춤형 차폐체의 유용성 평가 (Evaluation of the Usefulness of Patient Customized Shielding Block Made with 3D Printer in the Skin Cancer Electron Beam Therapy)

  • 안기송;정우찬;김대현;김무섭;윤도군;심재구;서태석
    • 대한방사선기술학회지:방사선기술과학
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    • 제42권6호
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    • pp.447-454
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    • 2019
  • In order to improve and supplement the shielding method for electron beam treatment, we designed a patient-specific shielding method using a 3D printer, and evaluated the usefulness by comparing and analyzing the distribution of electron beam doses to adjacent organs. In order to treat 5 cm sized superficial tumors around the lens, a CT Simulator was used to scan the Alderson Rando phantom and the DICOM file was converted into an STL file. The converted STL file was used to design a patient-specific shield and mold that matched the body surface contour of the treatment site. The thickness of the shield was 1 cm and 1.5 cm, and the mold was printed using a 3D printer, and the patient customized shielding block (PCSB) was fabricated with a cerrobend alloy with a thickness of 1 cm and 1.5 cm. The dosimetry was performed by attaching an EBT3 film on the surface of the Alderson Rando phantom eyelid and measuring the dose of 6, 9, and 12 MeV electron beams on the film using four shielding methods. Shielding rates were 83.89%, 87.14%, 87.39% at 6, 9, and 12 MeV without shielding, 1 cm (92.04%, 87.48%, 86.49%), 1.5 cm (91.13%, 91.88% with PSCB), 92.66%) The shielding rate was measured as 1 cm (90.7%, 92.23%, 88.08%) and 1.5 cm (88.31%, 90.66%, 91.81%) when the shielding block and the patient-specific shield were used together. PCSB fabrication improves shielding efficiency over conventional shielding methods. Therefore, PSCB may be useful for clinical application.

Dynamics of Transverse Magnetic Domain Walls in Rectangular-shape Thin-film Nanowires Studied by Micromagnetic Simulations

  • Lee, Jun-Young;Choi, Sang-Kook;Kim, Sang-Koog
    • Journal of Magnetics
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    • 제11권2호
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    • pp.74-76
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    • 2006
  • Dynamic behaviors of transverse domain walls (TDWs) in rectangular shaped thin-film magnetic nanowires with different widths under applied magnetic fields less than the Walker field were studied by micromagnetic simulations. It was found that the velocity of stable TDWs in the viscous region increases from 147 to 419 m/s and their mass decreases from $6.24{\times}10^{-23}\;to\;2.70{\times}10^{-23}kg$ with increasing strength of the applied magnetic field ranging from 5 to 20 Oe for the nanowire with a dimension of 10 nm in thickness and $5{\mu}m$ in length, and 50 nm in width. With increasing the width of nanowires from 50 to 125 nm at a specific field strength of 5 Oe, the TDW's velocity also increases from 147 to 246 m/s and its mass decreases from $6.24{\times}10^{-23}\;to\;5.91{\times}10^{-23}kg$.

Thin Film Encapsulation with Organic-Inorganic Nano Laminate using Molecular Layer Deposition and Atomic Layer Deposition

  • 윤관혁;조보람;방지홍;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.270-270
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    • 2016
  • We fabricated an organic-inorganic nano laminated encapsulation layer using molecular layer deposition (MLD) combined with atomic layer deposition (ALD). The $Al_2O_3$ inorganic layers as an effective single encapsulation layer were deposited at 80 degree C using ALD with alternating surface-saturation reactions of TMA and $H_2O$. A self-assembled organic layers (SAOLs) were fabricated at the same temperature using MLD. MLD and ALD deposition process were performed in the same reaction chamber. The prepared SAOL-$Al_2O_3$ organic-inorganic nano laminate films exhibited good mechanical stability and excellent encapsulation property. The measurement of water vapor transmission rate (WVTR) was performed with Ca test. We controlled thickness-ratio of organic and inorganic layer, and specific ratio showed a lowest WVTR value. Also this encapsulation layer contained very few pin-holes or defects which were linked in whole area by defect test. To apply into real OLEDs panels, we controlled a film stress from tensile to compressive and flexibility defined as an elastic modulus with organic-inorganic ratio. It has shown that OLEDs panel encapsulated with nano laminate layer exhibits better properties than single layer encapsulated in acceleration conditions. These results indicate that the organic-inorganic nano laminate thin films have high potential for flexible display applications.

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Improvement of Mchanical Property of Indium-tin-oxide Films on Polymer Substrates by using Organic Buffer Layer

  • Park, Sung-Kyu;Han, Jeong-In;Moon, Dae-Gyu;Kim, Won-Keun
    • Transactions on Electrical and Electronic Materials
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    • 제3권2호
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    • pp.32-37
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    • 2002
  • This paper gives the basic mechanical properties of indium-tin-oxide (ITO) films on polymer substrates which are exposed to externally and thermally induced bending force. By using modified Storney formula including triple layer structure and bulge test measuring the conductive changes of patterned ITO islands as a function of bending curvature, the mechanical stability of ITO films on polymer substrates was intensively investigated. The numerical analyses and experimental results show thermally and externally induced mechanical stresses in the films are responsible for the difference of thermal expansion between the ITO film and the substrate, and leer substrate material and its thickness, respectively. Therefore, a gradually ramped heating process and an organic buffer layer were employed to improve the mechanical stability, and then, the effects of the buffer layer were also quantified in terms of conductivity-strain variations. As a result, it is uncovered that a buffer layer is also a critical factor determining the magnitude of mechanical stress and the layer with the Young's modulus lower than a specific value can contribute to relieving the mechanical stress of the films.

The Material Analysis and Conservation of Porcelain Enamel - Focus of Porcelain Enamel Excavated at Former President Yoon Bosun's Birthplace -

  • Lee, Jung-Min
    • 보존과학회지
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    • 제35권1호
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    • pp.33-40
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    • 2019
  • During the conservation and maintenance of the birthplace center yard of President Asan Yoon Bosun, four porcelain enamel dishware were excavated from the central yard well. The glaze layer of excavated enamel was severely damaged; hence, the conservation process was done rapidly. In addition, scientific investigation and analysis were conducted to confirm the material properties of the glaze layer. It was confirmed that the outer surface was inverted and dried, while the inner surface was upright and fired during the glazing and drying process by measuring the film thickness. By examining the breakup phenomenon, the breaking up of the white enamel on the colored enamel was confirmed. This indicates that the colored glaze rose to the surface depending on the density of the colored glaze and white glaze. The investigation of the cross-section of the film confirmed that the lower layer formed according to the bonding properties with metal during the glazing process. Analysis of the constituents of the identified lower layer confirmed that there are differences between the specific components of the metal oxide of the lower layer and the surface color development of the upper layer.