• Title/Summary/Keyword: Solvent-free

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Improvement of Permeation of Solvent-free Multi-Layer Encapsulation of thin films on Ethylene Terephthalate(PET) (고분자 기판위에 유기 용매를 사용하지 않은 다층 박막 Encapsulation 기술 개발)

  • Kang, Hee-Jin;Han, Jin-Woo;Kim, Jong-Yeon;Moon, Hyun-Chan;Choi, Sung-Ho;Park, Kwang-Bum;Kim, Tae-Ha;Kim, Hwi-Woon;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.04a
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    • pp.56-57
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    • 2006
  • In this paper, the inorganic multi-layer thin film encapsulation was newly adopted to protect the organic layer from moisture and oxygen. Using the electron beam, Sputter, inorganic multi-layer thin-film encapsulation was deposited onto the Ethylene Terephthalate(PET) and their interface properties between inorganic and organic layer were investigated. In this investigation, the SiON SiO2 and parylene layer showed the most suitable properties. Under these conditions, the WVTR for PET can be reduced from a level of $0.57\;g/m^2/day$ (bare subtrate) to 1*10-5 g/$m^2$/day after application of a SiON and SiO2 layer. These results indicates that the PET/SiO2/SiON/Parylene barrier coatings have high potential for flexible organic light-emitting diode(OLED) applications.

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Mineral, Nutritional, and Phytochemical Profile, Total Phenolic Content, and Radical Scavenging Activity of Philippine Bamboo "Bolo" Gigantochloa levis (Blanco) Merr. Leaves

  • Tongco, Jovale Vincent V.;Rodriguez, Evelyn B.;Abasolo, Willie P.;Mun, Sung Phil;Razal, Ramon A.
    • Natural Product Sciences
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    • v.22 no.1
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    • pp.60-63
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    • 2016
  • The study is a pioneering effort to determine the mineral, nutritional, and phytochemical composition and phenolic content and to determine the free radical scavenging activity of Gigantochloa levis (Blanco) Merr, a native bamboo species (locally known as "bolo") in the Philippines. Proximate analysis showed that air-dried G. levis leaves contain 15.8% ash, 22.6% crude protein, 1.2% crude fat, 29.3% crude fiber, and 19.7% total sugar. Phytochemical tests indicated the presence of diterpenes, triterpenes, saponins, phenols, tannins, and flavonoids in both the ethanolic and aqueous leaf extracts, while phytosterols were only detected in the ethanolic extract. Folin-Ciocalteu assay determined the total phenolic content in gallic acid equivalents (GAE) to be $85.86{\pm}3.71$ and $32.32{\pm}1.01mg\;GAE/100g$ dried sample for the ethanolic and aqueous extracts, respectively. The total phenolic content in quercetin equivalents (QE) was $74.44{\pm}3.11$ and $29.43{\pm}0.85mg\;QE/100g$ dried sample for the ethanolic and aqueous extracts, respectively. The radical scavenging activity of the different solvent fractions containing varying concentrations of the extract was determined using the 2, 2-diphenyl-1-picrylhydrazyl (DPPH) assay. The ethyl acetate and 1-butanol fractions were found to have the highest radical scavenging activity. Mineral analysis via Energy Dispersive X-Ray Spectrometry (EDS) of the ash of G. levis leaves showed that Si is the major component, followed by K and Mg. These results point to the potential of G. levis leaves as a source of minerals and bioactive compounds with medicinal value.

Synthesis of Propylene Carbonate over Metal containing Ionic Liquid Catalysts (금속 함유 이온성 액체 촉매상에서의 프로필렌 카보네이트의 합성)

  • Moon, Ye-Ji;Ji, Dahye;Kim, Dong-Woo;Kim, Hyeon-Gook;Cho, Deug-Hee
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.153-157
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    • 2016
  • In this study, three different metal-containing ionic liquid catalysts were prepared by metal insertion and characterized by various physicochemical analytic methods. The catalytic performance of the metal containing ionic liquids in the cycloaddition of $CO_2$ with propylene oxide (PO) to produce propylene carbonate (PC) was investigated under the solvent free condition. The order of approximate rate constants ($K_{app}$) for the metal containing ionic liquid catalysts was $(MeIm)_2ZnCl_2$, > $(MeIm)_2FeCl_2$ > $(MeIm)_2CuCl_2$. These results are in accord with the experimentally obtained activity order of the different metal containing ionic liquid catalysts.

Purification and Physicochemical Properties of Superoxide Anion Radical Scavenger from Capsella bursa-pastoris (냉이(Capsella bursa-pastoris)로부터 Superoxide Anion Radical 소거물질의 정제 및 이화학적 성질)

  • Kwak, Jae-Hyock;Kweon, Mee-Hyang;Ra, Kyung-Soo;Sung, Ha-Chin;Yang, Han-Chul
    • Korean Journal of Food Science and Technology
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    • v.28 no.1
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    • pp.184-189
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    • 1996
  • A scavenger of superoxide anion radical which causes oxygen toxicity was isolated from Capsella bursa-pastoris, and its physicochemical properties were investigated. The scavenger was isolated and purified by solvent fractionation and liquid column chromatographies (Amberlite XAD-2, Sephadex LH-20, Bio gel P-2, ODS (silica gel with 100% octadecyl silanization)). An active compound of 0.25 g was finally isolated by Fast Protein Liquid chromatography (FPLC) from 100 g ethanol extract of Capsella bursa-pastoris. A 50% decrease of superoxide anion radical was obtained with the scavenger compound of 0.58 g. The compound was assumed to be a phenolic glycoside from its physicochemical properties.

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Mechanical Properties on Vegetable Oil based eco-friendly Stainless Steel Coatings (식물성오일 기반의 친환경 스테인레스 스틸 코팅에 대한 기계적 특성)

  • Kim, Ki-Jun;Sung, Wan-Mo;Kim, Joo-Han;Jung, Hyung-Hak
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.851-856
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    • 2017
  • The mechanical properties of coating resin on stainless steel were measured by SEM, FT-IR spectra, tensile properties, mole % of [NCO/OH], and particle size analyzer. Growing concerns in the environment-friendly coating resin, we have synthesized the solvent-free coating resin to be coating on metals such as stainless steel. The properties of the synthesized coating resin to be contained polyols, MDI, silicone surfactant, fillers and vegetable oil(castor oil), that they have highly stronger in intensity and longer durability than general coating resin of polyurethane resin on stainless steel. The rigid segments of polyurethane in mechanical properties of coatings were due to unsaturated vegetable oil and the increase mole % of [NCO/OH]. In conclusion, the coating microstructure with castor oil can be good material for coatings of anticorrosion of metal substrates such as stainless steel.

Synthesis of Polymers in Supercritical Carbon Dioxide (초임계 유체를 이용한 고분자 합성 연구)

  • Lee, Hyun-Suk;Kim, Jin-Woong
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.36 no.1
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    • pp.17-32
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    • 2010
  • This review shows the design and the development of new $CO_2$-soluble hydrocarbon copolymers which can be used as effective stabilizers for successful dispersion polymerizations of bio-compatible materials in supercritical carbon dioxide ($scCO_2$). The basic concepts of supercritical fluid including its solvent properties and applications in polymer synthesis are described. We report the facile synthesis of highly soluble hydrocarbon based copolymers, prepared with good control via controlled free radical polymerization from readily accessible and commercially available monomers. The phase behaviour of these materials was monitored in pure $CO_2$ to investigate how the molecular weights and the composition of the copolymers affect their solubility in $CO_2$. Their activity as a stabilizer was then tested in dispersion polymerization of N-vinyl pyrrolidone in $CO_2$ at various reaction conditions to identify the key parameters required for a successful dispersion stabilization of growing PVP particles. Some prospective potentials of this research which can be applied in developing new polymer materials in an environmentally-friendly fashion for use in cosmetics are also discussed.

Convergence Study on FTO Film Etchant (FTO 필름 식각액에 관한 융합연구)

  • Han, Doo-Hee;Yang, Ui-Dong
    • Journal of Convergence for Information Technology
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    • v.8 no.6
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    • pp.43-48
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    • 2018
  • An etchant capable of forming a circuit in an FTO film that can replace ITO, which depends on full imports, was prepared. The etching solution is composed of 1 to 30% by weight of fluoride, 1 to 20% by weight of acid, 0.5 to 5% by weight of surfactant, 5 to 20% by weight of solvent, 0.5 to 10% by weight of corrosion inhibitor and the balance of water. This etchant can be etched using a dry film, thereby reducing the cost, and is free from bubbles and residue of the etchant. The characteristics of the etchant were etched in a time of 2 minute with a 100 nm thick FTO, and the etchant temperature was maintained at $50^{\circ}C$. An undercut of -0.00364% was obtained when put into a 2 minute etching solution. No harmful substances such as Cd, Pb, Hg and Cr components were measured. The use of FTO in Korea where rare earths do not exist can achieve localization and import substitution effect.

Antioxidant and Anti-inflammatory Activities of Different Parts of Ixeris dentata According to Extract Methods (씀바귀 부위별 용매추출 방법에 따른 항산화 활성 및 항염증 효과 비교)

  • Oh, Hee-Kyung
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.6
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    • pp.1567-1574
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    • 2020
  • This study was to investigate the antioxidant and anti-inflammatory activity of leaf and stem of Ixeris dentate extract by hot water and 70% ethanol. The total flavonoid and polyphenol in 70% ethanol extract of leaf and stem of Ixeris dentate were significantly higher than those of hot water extracts. DPPH and ABTS free radical scavenging activity of 70% ethanol extract of leaf was higher than that of hot water extract of leaf. 70% ethanol extract of leaf was the highest on the DPPH and ABTS activity. Nitric oxide(NO) production of 70% ethanol extract was higher than that of hot water extract. According to this study, it was found that there was difference in physiological activity due to extraction solvents of each part of Ixeris dentate and it is believed that it can be used as an ingredient of functional foods using Ixeris dentate.

Development of Humidity Sensor Based on Ceramic/Metal Halide Composite Films for Non-Contact Biological Signal Monitoring Applications (비접촉 생체신호 모니터링 응용을 위한 세라믹/메탈 할라이드 복합막 기반 습도센서 개발)

  • Park, Tae-Ung;Kim, Ik-Soo;Kim, Min-Ji;Park, Chulhwan;Seo, Eui-kyoung;Oh, Jong-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.4
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    • pp.412-417
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    • 2022
  • Capacitive-type humidity sensors with a high sensitivity and fast response/recovery times have attracted a great attention in non-contact respiration biological signal monitoring applications. However, complicated fabrication processes involving high-temperature heat treatment for the hygroscopic film is essential in the conventional ceramic-based humidity sensors. In this study, a non-toxic ceramic/metal halide (BaTiO3(BT)/NaCl) humidity sensor was prepared at room temperature using a solvent-free aerosol deposition process (AD) without any additional process. Currently prepared BT/NaCl humidity sensor shows an excellent sensitivity (245 pF/RH%) and superior response/recovery times (3s/4s) due to the NaCl ionization effect resulting in an immense interfacial polarization. Furthermore, the non-contact respiration signal variation using the BT/NaCl sensor was determined to be over 700% by maintaining the distance of 20 cm between the individual and the sensor. Through the AD-fabricated sensor in this study, we expect to develop a non-contact biological signal monitoring system that can be applied to various fields such as respiratory disease detection and management, infant respiratory signal observation, and touchless skin moisture sensing button.

Preparation and Characterization of Hydrophobic Coatings from Carnauba Wax/Lignin Blends

  • BANG, Junsik;KIM, Jungkyu;KIM, YunJin;OH, Jung-Kwon;YEO, wanmyeong;KWAK, Hyo Won
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.3
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    • pp.149-158
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    • 2022
  • To realize the infinite possibilities of materials derived from wood, it is necessary to overcome the weak moisture stability of wood. Thus, the development of an eco-friendly hydrophobic coating agent is essential, and of these, woody biomass-based materials are strongly attractive as coatings. In this study, eco-friendly hydrophobic wood coatings were prepared using carnauba wax purified from palm leaves and sprouts, and kraft lignin. The physicochemical properties of the carnauba wax/lignin blends according to the ratio of carnauba wax and lignin were observed by morphology and functional group change. In addition, the coating performance of carnauba wax/lignin blend coatings was confirmed by measuring the contact angle change. It was found that the addition of lignin could accelerate the atomization of wax particles, and that micro-roughness can be realized when applied to the actual wood surface, to ensure that the coating effect over time lasts longer. In addition, it was confirmed that the addition of lignin increases the hydrogen-bond-based interaction with the wood of the coating, thereby providing better coating stability and increasing the durability of the coating solvent under friction. The carnauba wax/lignin paint developed in this way is eco-friendly because all components are made of wood-based raw materials and have an excellent affinity with wood surfaces. Therefore, it is expected to be applicable to the coating process of wood-plastic composites and timber composites.