• 산업기술연구
• /
• 제20권A호
• /
• pp.39-44
• /
• 2000

Highly viscous biopolymer from alkali-tolerant Bacillus sp. was purified and its solution properties were investigated. The intrinsic viscosities for crude biopolymer and biopolymers purified by dialysis or CPC(cetylpyridinium chloride) treatment were 58.24, 73.60 and 42.18 dL/g, respectively. The intrinsic viscosity of biopolymer showed the maximum value at the neutral pH but it was decreased remarkably at the alkaline or acidic pH. Biopolymer exhibited the property of polyelectrolyte, showing the sharp decrease of intrinsic viscosity by the addition of NaCl. Intrinsic viscosity of dilute solution at the low NaCl concentration was exponentially dependent on temperature and its temperature dependency was increased with NaCl concentrations. The chain stiffness, coil overlap parameter, and critical concentration were 0.09, 5.25 and 0.07g/dL, respectively. Temperature dependency on intrinsic viscosity of biopolymer solution was different each other at $45^{\circ}C$. Flow activation energies at temperatures above $45^{\circ}C$ were constant, while those at temperatures below $45^{\circ}C$ increased with increase of added NaCl concentration.

• Membrane and Water Treatment
• /
• 제1권2호
• /
• pp.139-158
• /
• 2010

This work focuses on the application of nanofiltration (NF) to the concentration of a pharmaceutical product, Clavulanate ($CA^-$), from clarified fermentation broths, which show a complex composition with six main identified ions ($K^+$, $Cl^-$, ${NH_4}^+$, $H_2{PO_4}^-$, ${SO_4}^{2-}$ and $CA^-$), glucose and glycerol. The solutes transport through the NF membrane pores was investigated using the SEDE (Steric, Electric and Dielectric Exclusion) model. This model was applied to predict the rejection rates of the initial feed solution and the final concentrated solution (10-fold concentrated solution). The best results were achieved with a single fitted parameter, ${\varepsilon}_p$ (the dielectric constant of the solution inside pores) and considering that the membrane selectivity is governed by steric, electric (Donnan) and Born dielectric exclusion mechanisms. While the predicted intrinsic rejections of solutions comprising up to six ions and uncharged solutes were in good agreement with the experimental values, the deviations were much larger for the 10-fold concentrated solution.

• International Journal of Air-Conditioning and Refrigeration
• /
• 제14권2호
• /
• pp.41-48
• /
• 2006

Absorption performance at the vertical interface between refrigerant vapor and liquid solution of $LiBr-H_{2}O$ solution was enhanced by the waves formed due to the interfacial shear stress. The present study investigated experimentally and analytically the improvements of absorption performance in a falling film by wavy film flow. The dynamic parameter was the film Reynolds numbers ranged from 50 to 150. The energy and diffusion equations were solved simultaneously to find the temperature and concentration profiles at the interface of liquid solution and refrigerant vapor. Absorption characteristics due to heat and mass transfer were analyzed for the falling film of the LiBr aqueous solution contacted by refrigerant vapor in the absorber. Absorption performance showed a peak value at the solution flow rate of $Re_{f}>100$. Absorption performance for the wavy film flow was found to be greater by approximately 10% than that for uniform film flow. Based on numerical and experimental results, the maximum absorption rate was obtained for the wavy flow caused by spring insert. The difference between the measured and the predicted results were ranged from 5.8 to 12%.

• Journal of applied mathematics & informatics
• /
• 제40권3_4호
• /
• pp.675-694
• /
• 2022

In this article, we investigate the solution of the inverse problem for one dimensional heat equation with Neumann and Robin boundary conditions, that is, we determine the temperature and source term with given initial and boundary conditions. Three radial basis functions(RBFs) have been used for numerical solution, and Homotopy perturbation method for analytic solution. Numerical solutions which are obtained by considering each of the three RBFs are compared to the exact solution. For appropriate value of shape parameter c, numerical solutions best approximates exact solutions. Furthermore, we have shown the impact of noisy data on the numerical solution of u and f.

• 한국물환경학회지
• /
• 제28권2호
• /
• pp.292-299
• /
• 2012

The objective of this study is to develop a novel method for evaluating forward osmosis (FO) membrane performances using a non-pressurized FO system. Basic membrane performance parameters including water (A) and solute (B) permeability coefficients and unique parameter for FO membrane such as the support layer structural parameter (S) were determined in two FO modes (i.e., active layer faces feed solution (AL-FS) and active layer faces draw solution (AL-DS)). Futhermore, these parameters were compared with those determined in a pressurized reverse osmosis (RO) system. Theoretical water flux was calculated by employing these parameters to a model that accounts for the effects of both internal and external concentration polarization. Water flux from FO experiment was compared to theoretical water fluxes for assessing the reliability of those parameters determined in three different operation modes (i.e., AL-FS FO, AL-DS FO, and RO modes). It is demonstrated that FO membrane performance parameters can be accurately measured in non-pressurized FO mode. Specifically, membrane performance parameters determined in AL-DS FO mode most accurately predict FO water flux. This implies that the evaluation of FO membrane performances should be performed in non-pressurized FO mode, which can prevent membrane compaction and/or defect and more precisely reflect FO operation conditions.

• Steel and Composite Structures
• /
• 제34권4호
• /
• pp.511-524
• /
• 2020

In this research, a simple four-variable trigonometric integral shear deformation model is proposed for the static behavior of advanced functionally graded (AFG) ceramic-metal plates supported by a two-parameter elastic foundation and subjected to a nonlinear hygro-thermo-mechanical load. The elastic properties, including both the thermal expansion and moisture coefficients of the plate, are also supposed to be varied within thickness direction by following a power law distribution in terms of volume fractions of the components of the material. The interest of the current theory is seen in its kinematics that use only four independent unknowns, while first-order plate theory and other higher-order plate theories require at least five unknowns. The "in-plane displacement field" of the proposed theory utilizes cosine functions in terms of thickness coordinates to calculate out-of-plane shear deformations. The vertical displacement includes flexural and shear components. The elastic foundation is introduced in mathematical modeling as a two-parameter Winkler-Pasternak foundation. The virtual displacement principle is applied to obtain the basic equations and a Navier solution technique is used to determine an analytical solution. The numerical results predicted by the proposed formulation are compared with results already published in the literature to demonstrate the accuracy and efficiency of the proposed theory. The influences of "moisture concentration", temperature, stiffness of foundation, shear deformation, geometric ratios and volume fraction variation on the mechanical behavior of AFG plates are examined and discussed in detail.

• 한국전산구조공학회:학술대회논문집
• /
• 한국전산구조공학회 1995년도 가을 학술발표회 논문집
• /
• pp.225-233
• /
• 1995

This paper presents an efficient numerical method for computation of eigenpair derivatives for the real symmetric eigenvalue problem with distinct and multiple eigenvalues. The method has very simple algorithm and gives an exact solution. Furthermore, it saves computer storage and CPU time. The algorithm preserves the symmetry and band of the matrices, allowing efficient computer storage and solution techniques. Thus, the algorithm of the proposed method will be inserted easily in the commercial FEM codes. Results of the proposed method for calculating the eigenpair derivatives are compared with those of Rudisill and Chu's method and Nelson's method which is efficient one in the case of distinct natural frequencies. As an example to demonstrate the efficiency of the proposed method in the case of distinct eigenvalues, a cantilever plate is considered. The design parameter of the cantilever plate is its thickness. For the eigenvalue problem with multiple natural frequencies, the adjacent eigenvectors are used in the algebraic equation as side conditions, they lie adjacent to the m (multiplicity of multiple natural frequency) distinct eigenvalues, which appear when design parameter varies. As an example to demonstrate the efficiency of the proposed method in the case of multiple natural frequencies, a cantilever beam is considered. Results of the proposed method fDr calculating the eigenpair derivatives are compared with those of Bailey's method (an amendation of Ojalvo's work) which finds the exact eigenvector derivatives. The design parameter of the cantilever beam is its height. Data is persented showing the amount of CPU time used to compute the first ten eigenpair derivatives by each method. It is important to note that the numerical stability of the proposed method is proved.

• 한국표면공학회지
• /
• 제49권2호
• /
• pp.159-165
• /
• 2016

The hydrogen has been recognized as a clean, nonpolluting and unlimited energy source that can solve fossil fuel depletion and environmental pollution problems at the same time. Water electrolysis has been the most attractive technology in a way to produce hydrogen because it does not emit any pollutants compared to other method such as natural gas steam reforming and coal gasification etc. In order to improve efficiency and durability of the water electrolysis, comprehensive studies for highly active and stable electrocatalysts have been performed. The platinum group metal (PGM; Pt, Ru, Pd, Rh, etc.) electrocatalysts indicated a higher activity and stability compared with other transition metals in harsh condition such as acid solution. It is necessary to develop inexpensive non-noble metal catalysts such as transition metal oxides because the PGM catalysts is expensive materials with insufficient it's reserves. The optimization of operating parameter and the components is also important factor to develop an efficient water electrolysis cell. In this study, we optimized the operating parameter and components such as the type of AEM and density of gas diffusion layer (GDL) and the temperature/concentration of the electrolyte solution for the anion exchange membrane water electrolysis cell (AEMWEC) with the transition metal oxide alloy anode and cathode electrocatalysts. The maximum current density was $345.8mA/cm^2$ with parameter and component optimization.

• Steel and Composite Structures
• /
• 제18권2호
• /
• pp.425-442
• /
• 2015

This paper addresses theoretically the bending and buckling behaviors of size-dependent nanobeams made of functionally graded materials (FGMs) including the thickness stretching effect. The size-dependent FGM nanobeam is investigated on the basis of the nonlocal continuum model. The nonlocal elastic behavior is described by the differential constitutive model of Eringen, which enables the present model to become effective in the analysis and design of nanostructures. The present model incorporates the length scale parameter (nonlocal parameter) which can capture the small scale effect, and furthermore accounts for both shear deformation and thickness stretching effects by virtue of a sinusoidal variation of all displacements through the thickness without using shear correction factor. The material properties of FGM nanobeams are assumed to vary through the thickness according to a power law. The governing equations and the related boundary conditions are derived using the principal of minimum total potential energy. A Navier-type solution is developed for simply-supported boundary conditions, and exact expressions are proposed for the deflections and the buckling load. The effects of nonlocal parameter, aspect ratio and various material compositions on the static and stability responses of the FGM nanobeam are discussed in detail. The study is relevant to nanotechnology deployment in for example aircraft structures.

• 한국통신학회논문지
• /
• 제41권8호
• /
• pp.917-920
• /
• 2016

전통적 도래각 추정기법[1]과 별개로 2004년 이후 입사신호의 입사방향은 공간 영역에서 희소도(sparsity)를 가짐을 이용한 도래각 추정 기법이 제안되었다. 압축센싱 기반 도래각 추정 알고리즘인 SpSF 알고리즘에 이용되는 비용함수는 비선형 다변수 최적화문제이다. 적절한 변환을 통하여 해당 비용함수는 볼록 최적화 (convex optimization) 문제로 표현할 수 있다. 볼록 최적화 문제는 제한조건이 있는 최적화 문제이며 제한조건에 포함되는 상수를 지정해야 한다. 본 연구에서는 제한조건에 포함되는 사용자지정 상수값 결정법을 제안한다. 잡음의 실수부와 허수부가 서로 독립인 평균 0인 정규분포를 따름을 이용하여 제한조건에 포함되는 행렬의 Frobenius norm의 평균을 유도할 수 있으며, 이를 이용하여 제한조건에 포함되는 상수를 결정할 수 있다. 제안된 방법에 의해 결정된 상수를 이용한 SpSF 알고리즘이 실제로 동작함을 보였다.