Evaluation of Forward Osmosis (FO) Membrane Performances in a Non-Pressurized Membrane System

비가압식 막 공정을 통한 정삼투막 성능 평가

  • Kim, Bongchul (School of Civil, Environmental & Architectural Engineering, Korea University) ;
  • Boo, Chanhee (School of Civil, Environmental & Architectural Engineering, Korea University) ;
  • Lee, Sangyoup (School of Civil, Environmental & Architectural Engineering, Korea University) ;
  • Hong, Seungkwan (School of Civil, Environmental & Architectural Engineering, Korea University)
  • 김봉철 (고려대학교 건축사회환경공학부) ;
  • 부찬희 (고려대학교 건축사회환경공학부) ;
  • 이상엽 (고려대학교 건축사회환경공학부) ;
  • 홍승관 (고려대학교 건축사회환경공학부)
  • Published : 2012.03.30

Abstract

The objective of this study is to develop a novel method for evaluating forward osmosis (FO) membrane performances using a non-pressurized FO system. Basic membrane performance parameters including water (A) and solute (B) permeability coefficients and unique parameter for FO membrane such as the support layer structural parameter (S) were determined in two FO modes (i.e., active layer faces feed solution (AL-FS) and active layer faces draw solution (AL-DS)). Futhermore, these parameters were compared with those determined in a pressurized reverse osmosis (RO) system. Theoretical water flux was calculated by employing these parameters to a model that accounts for the effects of both internal and external concentration polarization. Water flux from FO experiment was compared to theoretical water fluxes for assessing the reliability of those parameters determined in three different operation modes (i.e., AL-FS FO, AL-DS FO, and RO modes). It is demonstrated that FO membrane performance parameters can be accurately measured in non-pressurized FO mode. Specifically, membrane performance parameters determined in AL-DS FO mode most accurately predict FO water flux. This implies that the evaluation of FO membrane performances should be performed in non-pressurized FO mode, which can prevent membrane compaction and/or defect and more precisely reflect FO operation conditions.

Keywords

References

  1. 김충환, 정혜원(1999). 역삼투공정을 이용한 먹는물 생산하는 붕소제거에 관한연구, 수질보전 한국물환경학회지, 15(1), pp. 13-22.
  2. 차기철, 황명구, 이명규, 태민호(2002). 역삼투막을 이용한 음식폐기물 액비의 농축, 수질보전 한국물환경학회지, 18(2), pp. 159-168.
  3. Baker, R. W. (2004). Membrane Technology and Applications, 2nd ed.; J. Wiley: Chichester, New York, pp. 210-278.
  4. Cath, T. Y., Childress, A. E., and Elimelech, M. (2006). Forward Osmosis: Principles, Applications, and Recent Developments, Journal of Membrane Science, 281, pp. 70-87. https://doi.org/10.1016/j.memsci.2006.05.048
  5. Gray, G. T., McCutcheon, J. R., and Elimelech, M. (2006). Internal Concentration Polarization in Forward Osmosis: Role of Membrane Orientation, Desalination, 197, pp. 1-8. https://doi.org/10.1016/j.desal.2006.02.003
  6. Lee, S., Boo, C., Elimelech, M., and Hong, S. (2010). Comparison of Fouling Behavior in Forward Osmosis (FO) and Reverse Osmosis (RO), Journal of Membrane Science, 365, pp. 34-39. https://doi.org/10.1016/j.memsci.2010.08.036
  7. McCutcheon, J. R. and Elimelech, M. (2006). Influence of Concentrative and Dilutive Internal Concentration Polarization on Flux Behavior in Forward Osmosis, Journal of Membrane Science, 284, pp. 237-247. https://doi.org/10.1016/j.memsci.2006.07.049
  8. McGinnis, R. L. and Elimelech, M. (2007). Energy Requirements of Ammonia-Carbon Dioxide Forward Osmosis Desalination, Desalination, 207, pp. 370-382. https://doi.org/10.1016/j.desal.2006.08.012
  9. Mulder, M. (1996). Basic Principles of Membrane Technology, 2nd ed.; Kluwer Academic: Dordrecht, Boston, pp. 191-232.
  10. Phillip, W. A., Yong, J. S., and Elimelech, M. (2010). Reverse Draw Solute Permeation in Forward Osmosis: Modeling and Experiments, Environmental Science & Technology, 44, pp. 5170-5176. https://doi.org/10.1021/es100901n
  11. Sairam, M., Sereewatthanawut, E., Li, K., Bismarck, A., and Livingston, A. G. (2011). Method for the Preparation of Cellulose Acetate Flat Sheet Composite Membranes for Forward Osmosis-Desalination Using $MgSO_4$ Draw Solution, Desalination, 273, pp. 299-307. https://doi.org/10.1016/j.desal.2011.01.050
  12. Wang, R., Shi, L., Tang, C. Y., Chou, S., Qiu, C., and Fane, A. G. (2010). Characterization of Novel Forward Osmosis Hollow Fiber Membranes, Journal of Membrane Science, 355, pp. 158-167. https://doi.org/10.1016/j.memsci.2010.03.017
  13. Yip, N. Y., Tiraferri, A., Phillip, W. A., Schiffman, J. D., and Elimelech, M. (2010). High Performance Thin-Film Composite Forward Osmosis Membrane, Environmental Science & Technology, 44, pp. 3812-3818. https://doi.org/10.1021/es1002555