• 제목/요약/키워드: Solid to solid interface

검색결과 618건 처리시간 0.026초

원자층 증착법을 통한 고체산화물 연료전지의 세라믹 인터페이스 제어 (Control of solid oxide fuel cell ceramic interfaces via atomic layer deposition)

  • 서종수;정우철;김정환
    • 세라미스트
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    • 제23권2호
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    • pp.132-144
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    • 2020
  • Solid oxide fuel cell (SOFC) have attracted much attention due to clean, efficient and environmental-friendly generation of electricity for next-generation energy conversion devices. Recently, many studies have been reported on improving the performance of SOFC electrodes and electrolytes by applying atomic layer deposition (ALD) process, which has advantages of excellent film quality and conformality, and precise control of film thickness by utilizing its unique self-limiting surface reaction. ALD process with these advantages has been shown to provide functional ceramic interfaces for SOFC electrodes and electrolytes. In this article, recent examples of successful functionalization and stabilization on SOFC electrodes and electrolytes by the application of ALD process for realizing high performance SOFC cells are reported.

배전용 반도체 변압기 구현을 위한 SiC MOSFET 기반 전력변환회로 단위모듈 설계에 관한 연구 (Design and Implementation of a Power Conversion Module for Solid State Transformers using SiC MOSFET Devices)

  • 임정우;조영훈
    • 전력전자학회논문지
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    • 제22권2호
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    • pp.109-117
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    • 2017
  • This paper describes the design and implementation of a unit module for a 10 kVA class 13.2 kV/220 V unidirectional solid-state transformer (SST) with silicon-carbide metal-oxide-semiconductor field-effect transistors. The proposed module consists of an active-front-end (AFE) converter to interface 1320 V AC voltage source to 2500 V DC link and an isolated resonant DC-DC converter for 500 V low-voltage DC output. The design approaches of the AFE and the isolated resonant DC-DC converters are addressed. The control structures of the converters are described as well. The experiments for the converters are performed, and results verify that the proposed unit module can be successfully adopted for the entire SST operation.

Quantitative Investigation of Grain Growth in Carbide Added(Mo$_2$C, ZrC and WC) to TiC-Ni Matrix Cermets

  • Kim, Soon-Ho
    • International Journal of Precision Engineering and Manufacturing
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    • 제5권1호
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    • pp.19-26
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    • 2004
  • The growth of solid particles in TiC-XC-2vo1.% and TiC-XC-30vo1.% Ni alloys, (where X=Zr, W or Mo) was fitted to the equation of the form $d^3$-${do}^3$=Kt during the liquid phase sintering at 1,673K. Also, the grain growth behavior decreased markedly with the addition of ${MO}_2$C or WC and increased with the addition of zrC. The contiguity was greater in the alloys with a smaller growth rate constant and especially, decreased by increasing the Ni content in the TiC-${MO}_2$C-Ni alloy. In addition, the effect of the addition of carbide on the grain growth of 2 vo1.% Ni alloys was found to be similar to that of 30vo1.% Ni alloys. Consequently, the grain growth mechanism cannot be explained by the usual solution / reprecipitation process, but can be explained in terms of a new growth velocity equation, which includes the effects of contiguous carbide grain boundaries in restricting the overall grain growth, as well as the area of the solid / liquid interface in the alloy.

탄화규소계 세라믹스에서 미끄럼시의 마모 및 마모천이에 미치는 계면강도의 영향 (Effects of Interface Boundary Strength on Wear and Wear Transition during Sliding in Silicon Carbide Ceramics)

  • 김동진;박성길;류현;엄창도;조성재;김석삼
    • Tribology and Lubricants
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    • 제11권4호
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    • pp.21-27
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    • 1995
  • The effects of interface boundary strength on wear and wear transition during sliding have been investigated in silicon carbide ceramics. Three different microstructures, i.e., solid state sintered silicon carbide, liquid phase sintered silicon carbide and liquid phase sintered silicon carbide composite reinforced with TiB$_{2}$ particulates, were designed by hot pressing. Examinations of crack patterns and fracture modes indicated that interface boundaries were relatively strong between silicon carbide grains in the solid state sintered silicon carbide, intermediate in the liquid phase sintered silicon carbide and weak between silicon carbide grains and TiB$_{2}$ particles in the composite. Wear data and examinations of worn surfaces revealed that the wear behavior of these silicon carbide ceramics could be significantly affected by the interface strength. In the solid state sintered silicon carbide, the wear occurred by a grooving process. In the liquid phase sintered silicon carbide and composite, on the other hand, an abrupt transition in wear mechanism from initial grooving to grain pull-out process occurred during the test. The transition occurred significantly earlier in the composite than in the carbide.

Level-Set 방법을 이용한 비등현상 해석 (NUMERICAL SIMULATION OF BOILING PHENOMENA USING A LEVEL-SET METHOD)

  • 손기헌
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2009년 추계학술대회논문집
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    • pp.218-222
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    • 2009
  • A level-set (LS) method is presented for computation of boiling phenomena which involve liquid-vapor interfaces that evolve, merge and break up in time, the flow and temperature fields influenced by the interfacial motion, and the microlayer that forms between the solid and the vapor phase near the wall. The LS formulation for tracking the phase interfaces is modified to include the effects of phase change on the liquid-vapor interface and contact angle on the liquid-vapor-solid interline. The LS method can calculate an interface curvature accurately by using a smooth distance function. Also, it is straightforward to implement for two-phase flows in complex geometries. The numerical method is applied for analysis of nucleate boiling on a horizontal surface and film boiling on a horizontal cylinder.

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미세액적의 분사를 이용한 박막 패터닝 공정에 대한 수치적 연구 (Numerical Study on a Thin Film Patterning Process Using Microdroplet Ejection)

  • 서영호;손기헌
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 춘계학술대회논문집
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    • pp.658-659
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    • 2008
  • Numerical simulation is performed for a microdroplet deposition on the pre-patterned micro-structure. The liquid-air interface is tracked by level set method improved by incorporating the ghost fluid approach based on a sharp-interface representation. The method is further extended to treat the contact angle condition at an immersed solid surface. The present computation of a patterning process using microdroplet ejection demonstrates that the multiphase characteristics between the liquid-gas-solid phases can be used to overcome the patterning error.

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Solid-Electrolyte Interphase in the Spinel Cathode Exposed to Carbonate Electrolyte in Li-Ion Battery Application: An ab-initio Study

  • 최대현;강준희;한병찬
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.169-169
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    • 2017
  • Due to key roles for the electrochemical stability and charge capacity the solid-electrolyte interphase (SEI) has been extensively studied in anodes of a Li-ion battery cell. There is, however, few of investigation for cathodes. Using first-principles based calculations we describe atomic-level process of the SEI layer formation at the interface of a carbonate electrolyte and $LiMn_2O_4$ spinel cathode. Furthermore, using beyond the conventional density functional theory (DFT+U) calculations we examine the work function of the cathode and frontier orbitals of the electrolyte. Based on the results we propose that proton transfer at the interface is an essential mechanism initiating the SEI layer formation in the $LiMn_2O_4$. Our results can guide a design concept for stable and high capacity Li-ion battery cell through screening an optimum electrolyte fine-tuned energy band alignment for a given cathode.

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Theory and technology of growing striation-free crystals

  • Scheel, Hans J.
    • 한국결정성장학회지
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    • 제14권4호
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    • pp.174-186
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    • 2004
  • Striations are growth-induced inhomogeneities which hamper the applications of solid-solution crystals and of doped crystals in numerous technologies. Thus the optimized performance of solid solutions often can not be exploited. The inhomogeneity problem can be solved in specific cases by achieving a distribution coefficient one in growth from melts and from solutions. Macrostep-induced striations can be suppressed by controlling the growth mode, by achieving growth on facets thereby preventing step bunching. Thermal striations are commonly assumed to be caused by convective instabilities so that reduced convection by microgravity or by damping magnetic fields was and is widely attempted to reduce such inhomogeneities. Here it will be shown that temperature fluctuations at the growth interface cause striations, and that hydrodynamic fluctuations in a quasi-isothermal growth system do not cause striations. The theoretically derived conditions were experimentally established and allowed the growth of striation-free crystals of $KTa_{1-x}Nb_xO_3$"KTN" solid solutions. Hydrodynamic variations from the accelerated crucible rotation technique ACRT did not cause striations as long as the temperature was controlled within $0.03^{\circ}$ at $1200^{\circ}C$ growth temperature. Alternative approaches to solve or reduce the segregation and striation problems in growth from melts and from solutions are discussed as well.

VisualLISP을 이용한 스퍼기어의 3차원 모델링에 관한 연구 (A Study on the 3-Dimensional Modeling of Spur Gear Using VisualLISP)

  • 이승수;김민주;김래호;전언찬
    • 한국공작기계학회논문집
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    • 제13권1호
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    • pp.48-54
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    • 2004
  • This paper describes the development of automatic shape design program for spur gear. It produces automatically third-dimensional surface and solid model used in CAD/CAM system with inputting simple measurements. This program can maximize user's convenience and get surface and solid model quickly as accepting GUI(graphic user interface). Automatic shape design program for spur gear was developed by Visual LISP, a developer program. Besides, a geometrical method and a mathematical algerian are used in this program. Use frequency of a fine spur gear is on the increase recently and manufacture process of this gear is heat treatment after press processing with molding. In this press processing, the upper punch portion of a fine spur gear shape is drafted by CAM. Therefore, estimated that surface and solid model of spur gear used to CAM are needed in this research. In this research, after 2 ㎜ gear was modeled by auto shape design program, the upper punch portion of a fine spur gear was manufactured as giving third-dimensional model to CAM software and then, displayed the result as applying to press process.

Numerical analysis of segmental tunnel linings - Use of the beam-spring and solid-interface methods

  • Rashiddel, Alireza;Hajihassani, Mohsen;Kharghani, Mehdi;Valizadeh, Hadi;Rahmannejad, Reza;Dias, Daniel
    • Geomechanics and Engineering
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    • 제29권4호
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    • pp.471-486
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    • 2022
  • The effect of segmental joints is one of main importance for the segmental lining design when tunnels are excavated by a mechanized process. In this paper, segmental tunnel linings are analyzed by two numerical methods, namely the Beam-Spring Method (BSM) and the Solid-Interface Method (SIM). For this purpose, the Tehran Subway Line 6 Tunnel is considered to be the reference case. Comprehensive 2D numerical simulations are performed considering the soil's calibrated plastic hardening model (PH). Also, an advanced 3D numerical model was used to obtain the stress relaxation value. The SIM numerical model is conducted to calculate the average rotational stiffness of the longitudinal joints considering the joints bending moment distribution and joints openings. Then, based on the BSM, a sensitivity analysis was performed to investigate the influence of the ground rigidity, depth to diameter ratios, slippage between the segment and ground, segment thickness, number of segments and pattern of joints. The findings indicate that when the longitudinal joints are flexible, the soil-segment interaction effect is significant. The joint rotational stiffness effect becomes remarkable with increasing the segment thickness, segment number, and tunnel depth. The pattern of longitudinal joints, in addition to the joint stiffness ratio and number of segments, also depends on the placement of longitudinal joints of the key segment in the tunnel crown (similar to patterns B and B').