• Title/Summary/Keyword: Sn-stabilized

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Characterization of electromechanical properties of Sn-Cu double layer stabilized GdBCO coated conductor tapes at 77 K

  • Shin, Hyung-Seop;Diaz, Mark Aangelo;Lee, Jae-Hun
    • Progress in Superconductivity and Cryogenics
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    • v.19 no.4
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    • pp.26-30
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    • 2017
  • The promising characteristics of 2G high-temperature superconductor (HTS) coated conductor (CC) tapes have made it possible to apply to various electrical device applications. In this study, the mechanical and electromechanical properties of Sn-Cu double layer stabilized GdBCO CC tapes have been characterized. The stress and strain tolerances of $I_c$ in GdBCO CC tapes adopting stainless steel substrate were evaluated using $I_c$-strain measurement at 77 K under both uniaxial tension and monotonic bending conditions. The results were compared to the conventional single Cu layer stabilized CC tape. As a result, the Sn-Cu double layer stabilized GdBCO CC tapes showed somehow lower or comparable electromechanical properties as compared to the Cu stabilized CC tape ones.

Measurement reliability of irreversible stress/strain limits in Sn-Cu double layer stabilized IBAD/RCE-DR processed GdBCO coated conductor tapes under uniaxial tension at 77 K

  • Bautista, Zhierwinjay;Diaz, Mark Angelo;Shin, Hyung-Seop;Lee, Jae-Hun
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.4
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    • pp.36-40
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    • 2018
  • In this study, the electromechanical properties in Sn-Cu double layer stabilized GdBCO coated conductor (CC) tapes with and without external lamination under uniaxial tension were examined at 77 K and self-field. Their irreversible stress and strain limits were determined using a loading-unloading scheme based on different critical current ($I_c$) recovery criteria. The repeated tests were performed and statistical estimation was done to check the reproducibility depending on the criterion adopted in evaluating the electromechanical properties. From the results, it showed that the Sn-Cu double-layer stabilized CC tapes have the higher irreversible stress limit, but lower irreversible strain limit as compared to brass laminated ones. Through the repeated tests, it can be found that a small scattering of irreversible limits existed in both CC tape samples. Finally, similar strain sensitivity of $I_c$ in both CC tapes was obtained.

Performance evaluation of differently structured RCE-DR GdBCO coated conductor tapes under uniaxial tension at 77 K

  • Diaz, Mark Angelo E.;Shin, Hyung-Seop;Jung, Ho-Sang;Lee, Jaehun
    • Progress in Superconductivity and Cryogenics
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    • v.24 no.1
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    • pp.13-17
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    • 2022
  • The mechanical properties of REBCO coated conductor (CC) tapes under uniaxial tension are mainly determined by the thick layer Components like the substrate and the stabilizer. Depending on the applications of the CC tapes, it is also needed to externally reinforce thin metallic foils to one side or both sides of the CC tapes. This study investigated the effect of additional stabilizer layers or lamination on the electrical resistivity and electromechanical properties in RCE-DR processed GdBCO CC tapes with different structures. The strain/stress tolerance of Ic in differently processed 12 mm-wide REBCO CC tapes under uniaxial tension at 77 K and self-field could be determined by the loading-unloading scheme. As a result, Sn-Cu stabilized CC tape showed a significant decrease in mechanical properties due to its soft but thick stabilizing layer. However, similar electromechanical properties have been observed on both Sn-Cu and Sn-stabilized CC tapes, the Ic degradation behavior was independent of whether the CC tape has an external reinforcement or different stabilizing layers.

Properties of Sintered Body of the $Ba(Ti_{1-x}Sn_x)_4O_9$ Ceramics Synthesized by Oxalate Method (II) (수산염법으로 합성한 $Ba(Ti_{1-x}Sn_x)_4O_9$ 분말의 소결체 특성(II))

  • 허혜경;지미정;안주삼;최병현
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.895-900
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    • 1996
  • Ba(Ti1-xSnx)4O9 powder was synthesized by oxalate method. With the substitution of Sn into Ti site the sintered BaTiO4 crystal phase was stabilized due to the formation of solid solution. The optimal amounts of Sn solutbility for formation of BaTi4O9 crystalline phase was 0.16mole and of Sn was substituted and sintering was done at 135$0^{\circ}C$ for 30 minutes long rod type crystal was well developed and the highest Q value was obtained. But dielectric constant wasnearly constant without regarding to the Sn addition and the sintering time.

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Stabilizing Li2O-based Cathode/Electrolyte Interfaces through Succinonitrile Addition

  • Myeong Jun Joo;Yong Joon Park
    • Journal of Electrochemical Science and Technology
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    • v.14 no.3
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    • pp.231-242
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    • 2023
  • Li2O-based cathodes utilizing oxide-peroxide conversion are innovative next-generation cathodes that have the potential to surpass the capacity of current commercial cathodes. However, these cathodes are exposed to severe cathode-electrolyte side reactions owing to the formation of highly reactive superoxides (Ox-, 1 ≤ x < 2) from O2- ions in the Li2O structure during charging. Succinonitrile (SN) has been used as a stabilizer at the cathode/electrolyte interface to mitigate cathode-electrolyte side reactions. SN forms a protective layer through decomposition during cycling, potentially reducing unwanted side reactions at the interface. In this study, a composite of Li2O and Ni-embedded reduced graphene oxide (LNGO) was used as the Li2O-based cathode. The addition of SN effectively thinned the interfacial layer formed during cycling. The presence of a N-derived layer resulting from the decomposition of SN was observed after cycling, potentially suppressing the formation of undesirable reaction products and the growth of the interfacial layer. The cell with the SN additive exhibited an enhanced electrochemical performance, including increased usable capacity and improved cyclic performance. The results confirm that incorporating the SN additive effectively stabilizes the cathode-electrolyte interface in Li2O-based cathodes.

A Study on Microscopic Deformation Behaviors of $Nb_3Sn$ Superconducting Composite Tape using Acoustic Emission Technique ($Nb_3Sn$ 복합초전도 테이프의 미시적 변형거동 특성평가를 위한 음향방출기법 적용에 관한 연구)

  • 이민래;이준현
    • Composites Research
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    • v.12 no.6
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    • pp.22-30
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    • 1999
  • Since the surface diffusion processed $Nb_3Sn$ superconducting tape has the advantage of having large overall critical current density. it is used for the construction of open type MRI superconducting magnets. However one of the disadvantages of this tape is that $Nb_3Sn$ compound often exhibited multiple cracking due to its intrinsic brittleness when subjected to mechanical loading such as bending and winding during the fabrication process for superconducting coil. This will eventually cause the severe degradation of critical current density. Therefore it is important to understand the microscopic deformation behavior of this kind of superconducting tape under the mechanical loading.In this study, acoustic emission(AE) was used to clarify microscopic deformation behavior at room temperature for $Nb_3Sn$ superconducting tape which was strengthened and stabilized with copper. For this purpose, special attention was paid to AE characteristics including AE event, energy, and amplitude distribution which were associated with microscopic mechanism of deformation of $Nb_3Sn$ superconducting tape under tensile load.

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Magnetostriction of B2-structured FeX (X = Al, Si, Ni, Ga, Ge, and Sn) Alloys: A First-principles Study (B2 구조 FeX(X = Al, Si, Ni, Ga, Ge, Sn) 합금의 자기변형에 대한 제일원리계산)

  • Lee, Sunchul;Odkhuu, Dorj;Kwon, Oryong;Hong, Soon Cheol
    • Journal of the Korean Magnetics Society
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    • v.23 no.4
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    • pp.117-121
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    • 2013
  • In this study we investigated magnetism and magnetostriction of B2-structured FeX (X = Al, Si, Ni, Ga, Ge, and Sn) using a first-principles method, in order to survey the possibility of developing a transition metal based magnetostriction material. The Full-potential Linearized Augmented Plane Wave method was employed for solving the Kohn-Sham equation within the generalized gradient approximation for exchange-correlation interaction between electrons. FeX alloys are stabilized in ferromagnetic states except for the FeSi and FeGe alloys. Magnetostrcition coefficients of FeX (X = Al, Ni, Ga, and Sn) were calculated to be -5, +6, -84, -522ppm, respectively. It is noteworthy that the magnetostriction coefficient (-522ppm) of FeSn is larger than that (+400ppm) of Gafenol.

Effects of Microstructure on the Creep Properties of the Lead-free Sn-based Solders (미세조직이 Sn계 무연솔더의 크리프 특성에 미치는 영향)

  • Yoo, Jin;Lee, Kyu-O;Joo, Dae-Kwon
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.3
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    • pp.29-35
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    • 2003
  • The Sn-based lead-free solders with varying microstructure were prepared by changing the cooling rate from the melt. Bulky as-cast SnAg, SnAgCu, and SnCu, alloys were cold rolled and thermally stabilized before the creep tests so that there would be very small amount of microstructural change during creep (TS), and thin specimens were water quenched from the melt (WQ) to simulate microstructures of the as-reflowed solders in flip chips. Cooling rates of the WQ specimens were 140∼150 K/sec, and the resultant $\beta-Sn$ globule size was 5∼10 times smaller than that of the TS specimens. Subsequent creep tests showed that the minimum strain rate of TS specimens was about $10_2$ times higher than that of the WQ specimens. Fractographic analyses showed that creep rupture of the TS-SnAgCu specimens occurred by the nucleation of voids on the $Ag_3Sn$ Sn or $Cu_6Sn_5$ particles in the matrix, their subsequent growth by the power-law creep, and inter-linkage of microcracks to form macrocracks which led to the fast failure. On the other hand, no creep voids were found in the WQ specimens due to the mode III shear rupture coming from the thin specimens geometry.

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A Study on the Efficient Stabilization of Dropper Clamp for Messenger and Trolley Wire (전차선 및 조가선 접속지지용 드롭바크램프의 성능 안정화 연구)

  • Jung, Hyun-Soo;Lee, Seung-Hyuk;Ree, Cheol-Jick;Lee, Hyung-Kwon
    • Proceedings of the KIEE Conference
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    • 2004.05b
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    • pp.156-158
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    • 2004
  • In the ATs(Auto-Transformers)-fed AC electric railroad system, the trolley wire with high power is supported with a messenger by the dropper. As the dropper maintains the height of the trolley wire and plays a role in distributing the supply power, it should be stabilized in that an electric and mechanical character accord ins the change of the open air circumstance and constructed easily. Consequently, this paper propose C5111 Sn(3.5$\sim$4.5%) and hexagonal round bolt for the way of the efficient stabilization as a result of the test that the correlation of the Sn content and the change of temperature affect a character of product.

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