• 제목/요약/키워드: Silicone

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A Study on the Resin Finishing of Silk Fabric -Silicone Resin Finishing- (견직물의 수지가공에 관한 연구)

  • 남중희;탁태문
    • Journal of Sericultural and Entomological Science
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    • v.27 no.2
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    • pp.28-39
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    • 1985
  • The structural and useful characteristics of silk habutae treated with silicone resin by emulsion finishing method were studied. The results were obtained through crease recovery test, water repellency test, scanning micrograph observation, amino acid analysis, X-Ray diffraction analysis, and Fourier Transform Infrared Spectroscopy. The results are summarized as follows; 1) The improvement in crease recovery of silk habutae finished with silicone resin, was observed b soaping treatment and curing conditions. 2) The higher water repellency and stiffness in silk fabrics finished with silicone resin was found by the fabric inspection and the scanning electron microscopic observation. It is suggested that silicone resin impregnated into the void of silk fibroin. 3) The polar side chains of amino acid composition were decreased, when the silicone resin was treated on silk fibroin. 4) Through Amino acid analysis of silicone resin finished fibroin, the different amounts of amino acid composition was indicated due to silk fibroin silicone polymer reaction and the structural difference of its fibroin were also proved by X-ray diffractograms. 5) The functionality of the siloxane compound may be deduced from the silicone finished silk habutae by Fourier Transform Spectroscopy. It was concluded from the above results that the useful characteristics of silk fabric can be improved by silicone resin finishing.

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Large Intraorbital Cyst after Silicone Implant Insertion: A Case Report (Silicone Implant 삽입 후에 발생한 안와내 거대 낭종)

  • Ha, Sang Wook;Lee, Hye Kyung;Yoo, Won Min;Tark, Kwan Chul
    • Archives of Plastic Surgery
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    • v.33 no.5
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    • pp.659-662
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    • 2006
  • Purpose: Alloplastic implants, such as methylmethacrylate, Teflon, silicone, Supramid are commonly used to cover the floor defect and to prevent reherniation of the displaced orbital tissue in orbital floor fracture. Silicone implant has been used for reconstruction of orbital wall defects because of pliability, advantage of carving and chemically inert nature. However, silicone implant also has complications including infection, extrusion, pain, dystopia and tissue reaction. Cyst formation around the silicone implant is a very rare complication. According to many reports, cysts around alloplastic implant in an orbital area are mostly hemorrhagic cysts consisted of blood breakdown product with fibrous capsule cell in histologic examination. Methods: The authors report atypical case and successful treatment of intraorbital hemorrhagic cyst around silicone implant of a 37-year-old male patient. Results: Preoperative symptoms of diplopia, exophthalmos, proptosis, vertical dystopia and ectropion of lower eyelid were resolved after surgical removal of implants with surrounding capsule. Conclusion: Clinical suspicion of plastic surgeon is important in diagnosis of intraorbital cyst of patients who have history of silicone implantation and computed tomography is the standard tool of diagnosis. During the operation, caution must be taken on delivering the whole capsule of intraorbital cyst along with silicone implant to prevent recurrence of the cyst.

Evaluation of 2 Part Curtainwall Structural Silicone Sealant (커튼월용 2액형 구조용 실란트 혼합비별 물성 평가 연구)

  • Kim, Sung Hyun;Jung, Jin-young;Ahn, Myung-Su;Seo, YeonWon;Bae, Keesun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.78-80
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    • 2014
  • Silicone structural glazing (SSG) is a method utilizing a silicone adhesive to attach glass, metal, or other panel material to the structure of a building. Windload and other impact loads on the facade are transferred from the glass or panel through the silicone structural sealant to the systems' framework. Silicone structural glazing systems are currently a very common method of glazing throughout the world. Locally, structural silicone glazing has become very common to achieve aesthetically pleasing and high utilization of small land for both residential and commercial building. Although structural silicone glazing has been utilized for approximately thirty years in Korea, the understanding of its technology was low and limited. Consequently, Korean projects experienced many quality issues during assembly and construction, even in very recently finished buildings. Adhesion loss and water infiltration occurred on more than one project, and the time and cost to repair these issues were substantial. In general, there are two kinds of structural silicones depending on fabrication methods. 1part structural silicone is for site glazing system and 2part structural silicone is for unitized factory glazing system. In this paper, 2part structural silicone which is very common for factory fabricating curtainwall systems was evaluated with regards to various mixing ratio. Since the structural performance of 2part sealant can be affected by mixing ratios, some extra ranges of recommended mixing ratio were evaluated to see any performance differences. Besides on cure profile, comparative evaluations for mechanical properties and adhesion develop on common building substrates were conducted.

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Storage Effectiveness of Deep-Fried Potato Chip Prepared with Canola Oil Fortified with TBHQ and Silicone (Potato Chip 제조시 TBHQ 와 Silicone 첨가유에 의한 저장 연장 효과)

  • Jung, Byoung-Doo;Rhee, Soon-Jae
    • Korean Journal of Food Science and Technology
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    • v.29 no.4
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    • pp.635-640
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    • 1997
  • The oxidative stability of the potato chip prepared with canola oil fortified with antioxidnats was studied to explore the possibility of substituting it for imported frying fats and oils. BHT, BHA, TBHQ and silicone were added to the oil at a level of 0.02% and 10 ppm, respectively. Potato chip samples were prepared in a commercial scale and stored at $25.0{\pm}0.5^{\circ}C$ for 5 months. The oxidative stability of the extracted oils from potato chips during storage was estimated on the basis of some their physico-chemical changes, such as acid values, peroxide values, iodine values, ansidine values, fatty acid composition of the oils. An organoleptic test for the flavor of the samples was also performed. The oxidative stability of the samlpes was estimated on the basis of the changes of the parameter values. The effectiveness of the antioxidants was in the order of canola oil+TBHQ (0.02%)+silicone (10 ppm) > canola oil+TBHQ (0.02%) > canola oil+BHA (0.02%)+silicone (10 ppm) > canola oil+BHT (0.02%)+silicone (10 ppm) > canola oil+BHA (0.02%) > canola oil+BHT (0.02%) > canola oil. The antioxidant effect of canola oil+TBHQ (0.02%)+silicone (10 ppm) was more salient than any other antioxidant used in the potato chip.

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The Effect of Anionic Surfactants in Synthesizing Silicone Dioxide/Acrylate Core-Shell Polymer (이산화규소/아크릴계 유기물의 코어-셀 합성에서 음이온 계면활성제의 영향)

  • Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.2
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    • pp.199-204
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    • 2009
  • Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S133D) surfactant was prepared. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 2.0 wt% EU-S133D, silicone dioxide/Acrylate core-shell polymerization was carried out on the surface of silicone dioxide particle without forming the new silicone dioxide particle during acrylate shell polymerization in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by scanning electron microscope(SEM).

Effects of Added Silicone Oils on the Surface Hydrophobicity of Silicone Rubber (실리콘 고무의 소수성에 미치는 첨가된 실리콘 오일의 영향)

  • Han Dong-Hee;Cho Han-Goo;Kang Dong-Pll;Min Kyung-Eun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.1
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    • pp.46-51
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    • 2006
  • This paper reports on the effects of silicone oils, used as processing agents, on the recovery of hydrophobicity of silicone rubber. The recovery of hydrophobicity was evaluated by the measuring the contact angle, the surface electrical resistance and SEM. Here, we formed artificial contamination on the surface of samples, which scratched by sand papers and alumina powders. There was small recovery of hydrophobicity on the surface of SIR-A that silicone oil was not added. In both oil-added samples, SIR-B and SIR-C, recovery of hydrophobicity was achieved greatly. The surface of SIR-C showed that a lot of silicone oil was observed due to migration of oil, relatively in comparison with SIR-B. The tendency of recovery of hydrophobicity expressed by contact angle was in a good agreement with electrical property as determined by surface resistivity.

A Study on Properties of Partial Discharge in Silicone Rubber (실리콘 고무의 부분방전 특성에 관한 연구)

  • Lee, Sung-Ill;Kwon, Young-Cheon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.11
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    • pp.890-894
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    • 2011
  • In this thesis, the silicone filler with a sample size of 0~75 phr and void size of 2~4.5 mm is prepared in order to diagnose the defect of void which exists in widely used insulation material, silicone rubber. In this silicone rubber sample, electrodes are connected and whilst the voltage changes, applied voltage 7 kV~9 kV is increased constantly over time and discharge quantity, discharge frequency and applied voltage (T-QNV) were measured. The discharge quantity of the applied voltage (VQ) is measured to estimate inception voltage and extinction voltage. In addition, under the condition of maintaining constant applied voltage, discharge quantity and discharge frequency (QN) are measured, and its characteristics are analyzed.

Comparison of Wound Healing Between Conventional Tie-over Dressing and Silicone Sheeting after Skin Grafting (피부이식술 후 고식적 봉합붕대법과 실리콘판법의 임상적 고찰)

  • Park, Hyun-Chul;Park, Hyun-Sik;Ahn, Sang-Cheon;Cho, Sang-Hyun;Kim, Sang-Soo;Chang, Jin
    • Archives of Reconstructive Microsurgery
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    • v.20 no.1
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    • pp.26-31
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    • 2011
  • Purpose: We compared wound healing between the conventional tie-over dressing and silicone sheeting after skin grafting in patients with skin defects. Materials and Methods: Of a total of 30 cases of skin defects, 15 underwent conventional tie-over dressing and the remaining 15 underwent silicone sheeting skin grafting, we compared hematoma formation and infection status between the 2 techniques 1 and 2 weeks after operation Results: Hematoma was not observed in all cases. The wound infection rate decreased in silicone group. Conclusions: Silicone sheeting skin graft may be helpful in reducing wound infection.

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Mechanical Properties of Cotton Fabric Treated with BTCA and Polyalkkyleneoxide modified aminofunctional silicone (BTCA와 실리론 처리 면직물의 역학적 성질)

  • 조성교;남승현
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.7
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    • pp.987-994
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    • 2000
  • Cotton fabrics were finished with mixture of BTCA and silicone by pad-dry-cure process to achieve better mechanical properties than those of finished with BTCA alone. The changes of mechanical properties o( finished cotton fabrics were measured with by the KES-FB System and the hand values were calculated from the data of mechanical properties. With the durable press finish with BTCA tensile, bending, shear and compression properties increased. In hand values, Stiffness Crispness and Anti-Drape Stiffness increased, and Fullness & Softness decreased. Whereas silicone treatment reduced bending and shear properties and improved tensile and compressional resilience. Thus, Stiffness Crispness and Anti-Drape Stiffness decreased, and Fullness & Softness increased. These results indicated that BTCA treatment restricts fiber/yarn mobility in the fabric structure due to crosslinking, but silicone treatment reduces inter-fiber and inter-yarn frictional forces. Therefore, finish with mixture of BTCA and silicone provided cotton fabrics with a lower Stiffness, Crispness and Anti-Drape Stiffness and a higher Fullness & Softnesss than finish with BTCA alone.

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Preparation and Characteristics of High Voltage Liquid Silicone Rubber by Modified Cross-linking Agent

  • Jung, Se-Young;Kim, Byung-Kyu
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.1
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    • pp.9-15
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    • 2009
  • There is a growing demand for a high voltage silicone rubber composite with high mechanical property and high electrical property. The effect of modified cross-linking agent on the mechanical, electrical properties, and short-circuit test performance of silicone rubber insulators have been investigated. To use base polymer, the various silicone polymers were prepared by the equilibrium polymerization. Aluminum trihydrate surface was treated by vinyl silane. Liquid silicone rubber nanocomposite was prepared from the compounding of VPMPS, HPDMS, catalyst, and alumina trihydrate modified with 1,3,5-trivinyl-l,3,5-trimethylcyclotrisiloxane. The mechanical property and electrical property for insulation materials were measured, indicating the high tensile strength and the good short-circuit property.