Browse > Article
http://dx.doi.org/10.12925/jkocs.2009.26.2.13

The Effect of Anionic Surfactants in Synthesizing Silicone Dioxide/Acrylate Core-Shell Polymer  

Kim, Duck-Sool (Dept. of Biomedical Engineering, Tongmyong University)
Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.26, no.2, 2009 , pp. 199-204 More about this Journal
Abstract
Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S133D) surfactant was prepared. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 2.0 wt% EU-S133D, silicone dioxide/Acrylate core-shell polymerization was carried out on the surface of silicone dioxide particle without forming the new silicone dioxide particle during acrylate shell polymerization in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by scanning electron microscope(SEM).
Keywords
Silicone dioxide; acrylate; core-shell; polyoxyethylene alkylether sulfate; scanning electron microscope(SEM);
Citations & Related Records
연도 인용수 순위
  • Reference
1 N. S. Kim, D. S. Kim, and K. H. Park, A Study on the Synthesis and Characteristics of Acrylic Composite Particles, J. Kar. Chern. Soc., 20(3), 259 (2003)
2 K. H. Park, The Effect of Anionic Surfactants m Synthesizing Calcium Surfactants m Synthesizing Silicone Dioxide/Styrene Core-Shell Polymer, J. Kor. Oil Chem Soc., 25(3), 404 (2008)
3 J. B. Kwon, N. W. Lee, and S. D. Seul, A Consideration on Thermal Stability of the PV Ac Latex Adhesive, J. Kar. Soc. of Sqfety, 18(3), 81 (2003)
4 S. D. Seul, S. R. Lee, and N. W. Lee, A Development of Nontoxic Composite Latex Using $CaCO_3$/ PEMA, J. Kar. Soc. of Sqfety, 17(4), 133 (2002)
5 K. H. Park, Effect of Anionic Polymer/Metal Composite Nanoparticles and Their Applications, J. Kor. Ind. Eng. Chem., 14(2), 131 (2003)
6 V, I Eliseeva, Morphology and phase structure of latex particles: Their influence on the properties of latices and films, Prog. Org. Coatings, 13, 195 (1985)   DOI   ScienceOn
7 Y. S. Choi, Y. K. Kim, and I. J. Chung, Poly (methyl methacrylate-co-styrene)/ Silicate Nanocomposites Synthesized by Multistep Emulsion Polymerization, Macromalecular Research Formerly Korea Polymer J., 11(6), 418 (2003)
8 I. H. Ju and J. P. Wu, Effect of Latex Particle Morphology on the Film Formation and Film Properties of Acrylic Coatings (2), Film Forming Behavior of Model Composite Latex, J. Kor. Oil Chern. Soc., 21(2), 132 (2004)
9 R. Blankenship and A. Kowalski, Production of core-sheath polymer particles contammg voids, resulting product and use, U. S. Patent, 4, 594, 363 (1986)
10 L. E. Nielsen, Mechanical Properties of Polymers and Composite, 2, Marcel Dekker Inc. New York (1974)
11 M Hasegawa, K. Arari, and S. Saito, Uniform encapsulation of fine inorganic powder with soapless emulsion polymerization, J. Polyrn. Sci, Palyrn. Chern. Ed., 25, 3117 (1987)
12 N. S. Kim, D. S. Kim, and K. H. Park, Synthesis of Inorganic/Organic Core-Shell Polymer, J. Kor. Oil Chern. Soc., 19(4), 265 (2002)
13 T. Yamaguchi, T. Ono, M. Sekine, T. Iwai, and T. Okaea, 無機化合物粉存在下の メタクリル酸メチルの 重合みにおけるヵプセル化機構, Kobunshi Ranbunshu, 40, 259 (1983)   DOI
14 S. E. Shim and S. J. Choe, Synthesis of Core-Shell Type Polymer/Metal Composite Nanoparticles Carbonate/Acrylate Core-Shell Polymer, J. Kor. Oil Chern. Soc., 25(1), 83 (2008)
15 K. G. Lee and K. H. Park, Preparation and Physical Properties of Poly(Styrene/ Acrylate) Core-Shell Latex Particles, J. Kar. Oil Chern. Soc., 20(2), 27 (2003)
16 J. S. Yoon and H. J. Jin, Emlsion Polymerization, Polymer Sci. and Tech 7, 412 (1996)
17 M. Devon. J Garden, G. Roberts, and A. Rudin, Effects of core-shell latex morphology on film forming behavior, J. Appl. Polym: Sci., 39, 2119 (1990)   DOI