• 제목/요약/키워드: Shape of Lattice

검색결과 172건 처리시간 0.024초

Synthesis and Photocatalytic Properties of SnO2-Mixed and Sn-Doped TiO2 Nanoparticles

  • Choi, Hong-Goo;Yong, Seok-Min;Kim, Do-Kyung
    • 한국재료학회지
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    • 제22권7호
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    • pp.352-357
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    • 2012
  • $SnO_2$-mixed and Sn-doped $TiO_2$ nanoparticles were synthesized via a hydrothermal process. $SnO_2$-mixed $TiO_2$ nanoparticles prepared in a neutral condition consisted of anatase $TiO_2$ nanoparticles(diamond shape, ~25 nm) and cassiterite $SnO_2$ nanoparticles(spherical shape, ~10 nm). On the other hand, Sn-doped $TiO_2$ nanoparticles obtained under a high acidic condition showed a crystalline phase corresponding to rutile $TiO_2$. As the Sn content increased, the particle shape changed from rod-like(d~40 nm, 1~200 nm) to spherical(18 nm) with a decrease in the particle size. The peak shift in the XRD results and a change of the c-axis lattice parameter with the Sn content demonstrate that the $TiO_2$ in the rutile phase was doped with Sn. The photocatalytic activity of the $SnO_2$-mixed $TiO_2$ nanoparticles dramatically increased and then decreased when the $SnO_2$ content exceeded 4%. The increased photocatalytic activity is mainly attributed to the improved charge separation of the $TiO_2$ nanoparticles with the $SnO_2$. In the case of Sn-doped $TiO_2$ nanoparticles, the photocatalytic activity increased slightly with the Sn content due most likely to the larger energy bandgap caused by Sn-doping and the decrease in the particle size. The $SnO_2$-mixed $TiO_2$ nanoparticles generally exhibited higher photocatalytic activity than the Sn-doped $TiO_2$ nanoparticles. This was caused by the phase difference of $TiO_2$.

Large eddy simulation of wind loads on a long-span spatial lattice roof

  • Li, Chao;Li, Q.S.;Huang, S.H.;Fu, J.Y.;Xiao, Y.Q.
    • Wind and Structures
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    • 제13권1호
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    • pp.57-82
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    • 2010
  • The 486m-long roof of Shenzhen Citizens Centre is one of the world's longest spatial lattice roof structures. A comprehensive numerical study of wind effects on the long-span structure is presented in this paper. The discretizing and synthesizing of random flow generation technique (DSRFG) recently proposed by two of the authors (Huang and Li 2008) was adopted to produce a spatially correlated turbulent inflow field for the simulation study. The distributions and characteristics of wind loads on the roof were numerically evaluated by Computational Fluid Dynamics (CFD) methods, in which Large Eddy Simulation (LES) and Reynolds Averaged Navier-Stokes Equations (RANS) Model were employed. The main objective of this study is to explore a useful approach for estimations of wind effects on complex curved roof by CFD techniques. In parallel with the numerical investigation, simultaneous pressure measurements on the entire roof were made in a boundary layer wind tunnel to determine mean, fluctuating and peak pressure coefficient distributions, and spectra, spatial correlation coefficients and probability characteristics of pressure fluctuations. Numerical results were then compared with these experimentally determined data for validating the numerical methods. The comparative study demonstrated that the LES integrated with the DSRFG technique could provide satisfactory prediction of wind effects on the long-span roof with complex shape, especially on separation zones along leading eaves where the worst negative wind-induced pressures commonly occur. The recommended LES and inflow turbulence generation technique as well as associated numerical treatments are useful for structural engineers to assess wind effects on a long-span roof at its design stage.

Fabrication and magnetic properties of hexagonal BaFe12O19 ferrite obtained by magnetic-field-assisted hydrothermal process

  • Zhang, Min;Dai, Jianming;Liu, Qiangchun;Li, Qiang;Zi, Zhenfa
    • Current Applied Physics
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    • 제18권11호
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    • pp.1426-1430
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    • 2018
  • High magnetic field effects on the microstructure and magnetic properties of $BaFe_{12}O_{19}$ hexaferrites synthesized hydrothermal method have been investigated. The obtained results indicate that the lattice constant decreases gradually as the magnetic field strength increases, which may be attributed to the lattice distortion resulted from the high magnetic field. Polycrystalline $BaFe_{12}O_{19}$ samples prepared under magnetic field strength at zero and 5 T are single phase. It is found that application of external magnetic field during synthesis can induce orientated growth of the hexaferrite crystals along the easy magnetic axis. The magnetic properties can be effectively regulated by an application of high magnetic fields. It is observed that the $BaFe_{12}O_{19}$ prepared under a 5 T magnetic field exhibits a higher room-temperature saturation magnetization (66.3 emu/g) than that of the sample (43.6 emu/g) obtained without magnetic field. The results can be explained as the enhanced crystalline, improvement of $Fe^{3+}$ ions occupancy and the oriented growth induced by the external magnetic field. The growing orientation of particles gives rise to increased coercivity due to the enhancement in shape anisotropy. It is expected that an application of magnetic field during the formation of magnetic nanoparticles could be a promising technique to modify magnetic properties with excellent performance.

사각 및 원형 팁의 횡운동에 의한 물 메니스커스 형상변화에 관한 연구 (Study on a Shape Deformation of Water Meniscus for the Rectangular and Circular Tips Moving Horizontally)

  • 김상선;손성완;하만영;윤현식;김형락
    • 설비공학논문집
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    • 제23권12호
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    • pp.843-851
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    • 2011
  • A two-dimensional immiscible water meniscus deformation phenomena on a moving tip in a channel has been investigated by using lattice Boltzmann method involving two-phase model. We studied the behavior of a water meniscus between the tip and a solid surface. The contact angles of the tip and a solid surface considered are in the range from $10^{\circ}$ to $170^{\circ}$. The velocity of the tip used in the study are 0.01, 0.001, and 0.0001. The shapes of tip considered are rectangular and circular. The behavior of water confined between the tip and a solid surface depends on the contact angles of the tip and a solid surface, and the tip velocity. When the tip is moving, we can observe the various behaviors of shear deformation of a water meniscus. As time goes on, the behavior of a water meniscus can be classified into three different patterns which are separated from the tip or adhered to the tip or sticked to a solid surface according to the contact angles and the tip velocity.

딥러닝을 이용한 나노소재 투과전자 현미경의 초해상 이미지 획득 (Super-Resolution Transmission Electron Microscope Image of Nanomaterials Using Deep Learning)

  • 남충희
    • 한국재료학회지
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    • 제32권8호
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    • pp.345-353
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    • 2022
  • In this study, using deep learning, super-resolution images of transmission electron microscope (TEM) images were generated for nanomaterial analysis. 1169 paired images with 256 × 256 pixels (high resolution: HR) from TEM measurements and 32 × 32 pixels (low resolution: LR) produced using the python module openCV were trained with deep learning models. The TEM images were related to DyVO4 nanomaterials synthesized by hydrothermal methods. Mean-absolute-error (MAE), peak-signal-to-noise-ratio (PSNR), and structural similarity (SSIM) were used as metrics to evaluate the performance of the models. First, a super-resolution image (SR) was obtained using the traditional interpolation method used in computer vision. In the SR image at low magnification, the shape of the nanomaterial improved. However, the SR images at medium and high magnification failed to show the characteristics of the lattice of the nanomaterials. Second, to obtain a SR image, the deep learning model includes a residual network which reduces the loss of spatial information in the convolutional process of obtaining a feature map. In the process of optimizing the deep learning model, it was confirmed that the performance of the model improved as the number of data increased. In addition, by optimizing the deep learning model using the loss function, including MAE and SSIM at the same time, improved results of the nanomaterial lattice in SR images were achieved at medium and high magnifications. The final proposed deep learning model used four residual blocks to obtain the characteristic map of the low-resolution image, and the super-resolution image was completed using Upsampling2D and the residual block three times.

홀로그래픽 디지털 정보 저장장치에서의 이차원 인터리빙 구조 (Two-Dimensional Interleaving Structure of Holographic Digital Data Storage)

  • 김민승;한승훈;양병춘;이병호
    • 대한전자공학회논문지SD
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    • 제38권10호
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    • pp.721-727
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    • 2001
  • 본 논문에서 우리는 홀로그래픽 디지털 정보 저장 장치를 위한 2차원 인터리빙 구조를 제안한다. 이 저장장치에서는 다량의 디지털이진 정보를 2차원 정보 영상(1000×1000 bits) 안에 실어서 기록 및 재생, 처리하게 된다. 따라서, 저장 장치에서 발생하는 연집 오류(burst error) 또한 2차원의 형태를 띄게 되며, 이를 극복하기 위해 정보 영상 안에서 효율적인 2차원 인터리빙을 해야 할 필요가 있다. 연집 오류의 형태와 위치가 불규칙적임을 감안하여 각 부호어의 bit들을 2차원 상으로 흩뜨리면, 각 부호어의 bit들은 정삼각 격자 구조를 이루며 분포해야 한다. 이러한 정삼각 격자 형태의 인터리빙을 구현하기 위한 요소와 알고리즘을 제안한다.

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THE FORMATION MECHANISM OF GROWN-IN DEFECTS IN CZ SILICON CRYSTALS BASED ON THERMAL GRADIENTS MEASURED BY THERMOCOUPLES NEAR GROWTH INTERFACES

  • Abe, Takao
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1999년도 PROCEEDINGS OF 99 INTERNATIONAL CONFERENCE OF THE KACG AND 6TH KOREA·JAPAN EMG SYMPOSIUM (ELECTRONIC MATERIALS GROWTH SYMPOSIUM), HANYANG UNIVERSITY, SEOUL, 06월 09일 JUNE 1999
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    • pp.187-207
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    • 1999
  • The thermal distributions near the growth interface of 150mm CZ crystals were measured by three thermocouples installed at the center, middle (half radius) and edge (10m from surface) of the crystals. The results show that larger growth rates produced smaller thermal gradients. This contradicts the widely used heat flux balance equation. Using this fact, it si confirmed in CZ crystals that the type of point defects created is determined by the value of the thermal gradient (G) near the interface during growth, as already reported for FZ crystals. Although depending on the growth systems the effective lengths of the thermal gradient for defect generation are varied, were defined the effective length as 10mm from the interface in this experiment. If the G is roughly smaller than 20C/cm, vacancy rich CZ crystals are produced. If G is larger than 25C/cm, the species of point defects changes dramatically from vacancies to interstitial. The experimental results which FZ and CZ crystals are detached from the melt show that growth interfaces are filled with vacancy. We propose that large G produces shrunk lattice spacing and in order to relax such lattice excess interstitial are necessary. Such interstitial recombine with vacancies which were generated at the growth interface, next occupy interstitial sites and residuals aggregate themselves to make stacking faults and dislocation loops during cooling. The shape of the growth interface is also determined by the distributions of G across the interface. That is, the small G and the large G in the center induce concave and convex interfaces to the melt, respectively.

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HB-DECK와 현장타설 콘크리트 슬래브의 구조성능에 관한 연구 (A Study on Structural Performance of HB-DECK and Cast in Place Concrete Slab)

  • 이왕수;노병철;조현철
    • 한국구조물진단유지관리공학회 논문집
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    • 제22권2호
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    • pp.59-67
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    • 2018
  • 기존의 LB-DECK는 레티스바와 현장에서 배근되는 철근과의 간섭이 시공성 등을 저하시키는 문제점이 지적되고 있었다. HB-DECK는 레티스바의 형태를 단순화하고, 방향을 주철근 방향에서 배력근 방향으로 전환하였으며 강성을 증가시키기 위해 하면에 리브를 설치하였다. 본 연구에서는 HB-DECK가 프리캐스트 콘크리트 슬래브로써 성능을 발휘할 수 있는지를 검증하고자 하였다. 이를 위해 도로교설계기준(2015)에 의한 구조검증과 HB-DECK와 현장타설 콘크리트와의 합성거동 분석을 위해 정적재하시험을 수행하였다. 범용구조해석 프로그램인 MIDAS FEA를 이용하여 3차원 유한요소해석을 수행하였으며, 해석결과와 실험결과를 비교분석하였다. 그 결과, HB-DECK는 현장타설 콘크리트와 완전한 합성거동을 하는 것으로 나타났으며, 도로교설계기준(2015)에서 요구하는 구조성능을 만족하는 것으로 나타났다.

해저지층 탐사를 위한 Schur 알고리즘 (Schur Algorithm for Sub-bottom Profiling)

  • 배진호;이종현;김회용;조정홍
    • 전자공학회논문지
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    • 제50권9호
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    • pp.156-163
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    • 2013
  • 본 논문은 송신신호와 다층의 해수층 및 해저지층으로 구성된 매질의 퇴적물의 배치 및 형태에 의해 반사된 수신 신호를 이용하여 매질 각층의 특성을 계산 할 수 있는 알고리즘을 제안한다. 제안된 알고리즘은 이종의 다층 매질로 구성되어 있는 해수층 및 해저지층의 구조 특성을 추정하는 것으로, 일반적으로 Schur 알고리즘이라 부른다. 제안된 알고리즘은 주어진 역산란(inverse scattering) 문제를 matrix factorization을 수행하여 효율적으로 매질의 반사계수(reflection coefficient)를 추정한다. 본 논문에서는 제안된 알고리즘의 성능을 분석하기 위하여 해수층 및 해저지층의 이종 다층 매질 구조를 고려한 lattice 필터모델을 구성하였고, 이 필터 모델로부터 얻어진 송신 및 반사 신호를 이용하여 다양한 컴퓨터 모의실험을 수행한 결과, 제안된 알고리즘이 효율적으로 매질을 추정함을 확인하였다.

단일 비트 전자-광학 시그마-델타 변조기의 성능 및 지터 효과 분석 (Performance and Jitter Effects Analysis of Single Bit Electro-Optical Sigma-Delta Modulators)

  • 남창호;나성웅
    • 한국전자파학회논문지
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    • 제23권6호
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    • pp.706-715
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    • 2012
  • 전자-광학 시그마-델타 변조기는 안테나로부터 수신된 광대역 초고주파 신호를 직접 디지털 신호로 변환하는 디지털 수신기의 핵심 구성품이다. 전자-광학 시그마-델타 변조기는 펄스 레이저와 두 개의 마하-젠더 간섭계(Mach-Zehnder Interferometer: MZI)를 통하여 입력 신호를 초과 샘플링하고, 격자 섬유 누적기(Fiber-Lattice Accumulator: FLA)를 통하여 잡음을 감소시킨다. 고해상도의 출력 신호를 얻기 위해 양자화기 출력에는 데시메이션 필터링 과정이 추가된다. 변조기 설계시 지터는 변조기 입력 신호를 원 신호로 복원하는데 큰 영향을 미치는 요소이다. 본 논문에서는 전자-광학 1차 단일 비트 시그마-델타 변조기의 구현 과정 및 성능을 시뮬레이션을 통하여 분석한다. 전자-광학 시그마-델타 변조기 입력 신호와 출력 신호를 시간 영역에서 분석하고, 복원된 신호에 대하여 비동기 스펙트럼 평균화 방식을 사용하여 주파수 영역의 성능을 분석한다. 지터(Jitter)가 있는 레이저 신호와 지터가 없는 레이저 신호에 대하여 시그마-델타 변조기의 성능을 비교 및 분석하여, 시간 지터가 변조기 성능에 영향을 미치는 지터값을 참고치(펄스 반복 주파수가 100 GHz인 경우, 시간 지터는 100 fs 이하)로서 제시한다. 이러한 지터값은 레이저 생성기 제작시나 변조기 설계시 참고 규격치로 이용된다.