• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.394-400
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• 2023

In this study, the tuning phenomena, gas storage capacity, and thermal expansion behaviors of binary (cyclopentylamine + CH₄) and (cyclopropylamine + CH₄) clathrate hydrates were investigated for the potential applications of clathrate hydrates to gas storage. To understand the tuning behaviors of binary (cyclopentylamine + CH₄) and (cyclopropylamine + CH₄) clathrate hydrates, ¹³C solid-state NMR spectroscopy was used, and the results confirmed that maximum tuning factors for the binary (cyclopentylamine + CH₄) and (cyclopropylamine + CH₄) clathrate hydrates were achieved at 0.5 mol% and 1.0 mol% of guest concentration, respectively. The gas storage capacity of binary (cyclopentylamine + CH₄) and (cyclopropylamine + CH₄) clathrate hydrates were also checked, and the results showed the CH₄ capacity of our hydrate systems was superior to that of binary (tetrahydrofuran + CH₄) and (cyclopentane + CH₄) clathrate hydrates. The synchrotron diffraction patterns of these hydrates collected at 100, 150, 200, and 250 K confirmed the formation of a cubic Fd-3m hydrate. In addition, the lattice constant of clathrate hydrates with cyclopentylamine and methane were larger than that with cyclopropylamine and methane due to the effects of molecular size and shape.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.5B
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• pp.441-452
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• 2009

This paper describes the evaluation technique for climate change effect on daily precipitation frequency using daily precipitation generator that can use outputs of the climate model offered by IPCC DDC. Seoul station of KMA was selected as a study site. This study developed daily precipitation generation model based on two-state markov chain model which have transition probability, scale parameter, and shape parameter of Gamma-2 distribution. Each parameters were estimated from regression analysis between mentioned parameters and monthly total precipitation. Then the regression equations were applied for computing 4 parameters equal to monthly total precipitation downscaled by K-NN to generate daily precipitation considering climate change. A2 scenario of the BCM2 model was projected based on 20c3m(20th Century climate) scenario and difference of daily rainfall frequency was added to the observed rainfall frequency. Gumbel distribution function was used as a probability density function and parameters were estimated using probability weighted moments method for frequency analysis. As a result, there is a small decrease in 2020s and rainfall frequencies of 2050s, 2080s are little bit increased.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.1A
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• pp.1-13
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• 2010

This paper presents an investigation on the geometric nonlinear behavior of cable-stayed bridges using geometric nonlinear finite element analysis method. The girder and mast in cable-stayed bridges show the combined axial load and bending moment interaction due to horizontal and vertical forces of inclined cable. So these members are considered as beam-column member. In this study, the nonlinear finite element analysis method is used to resolve the geometric nonlinear behavior of cable-stayed bridges in consideration of beam-column effect, large displacement effect (known as P-${\delta}$ effect) and cable sag effect. To analyze a cable-stayed bridge model, nonlinear 6-degree of freedom frame element and nonlinear 3-degree of freedom equivalent truss element is used. To resolve the geometric nonlinear behavior for various live load cases, the initial shape analysis is performed for considering dead load before live load analysis. Then the geometric nonlinear analysis for each live load case is performed. The deformed shapes of each model, load-displacement curves of each point and load-tensile force curves for each cable are presented for quantitative study of geometric nonlinear behavior of cable-stayed bridges.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.6A
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• pp.789-798
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• 2008

The stiffness method provides a framework to calculate the structural deformations directly from solving the equilibrium state. However, to use the displacement shape functions leads to approximate estimation of stiffness matrix and resisting forces, and accordingly results in a low accuracy. The conventional flexibility method uses the relation between sectional forces and nodal forces in which the equilibrium is always satisfied over all sections along the element. However, the determination of the element resisting forces is not so straightforward. In this study, a new fiber finite element mixed method has been developed for nonlinear anaysis of steel-concrete composite structures in the context of a standard finite element analysis program. The proposed method applies the Newton method based on the load control and uses the incremental secant stiffness method which is computationally efficient and stable. Also, the method is employed to analyze the steel-concrete composite structures, and the analysis results are compared with those obtained by ABAQUS. The comparison shows that the proposed method consistently well predicts the nonlinear behavior of the composite structures, and gives good efficiency.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.1A
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• pp.105-113
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• 2008

Solar radiation induces non-uniform temperature distribution in the bridge structure depending on the shape of the structure and shadows cast on it. Especially in the case of curved steel box girder bridges, non-uniform temperature distribution caused by solar radiation may lead to unusual load effects enough to damage the support or even topple the whole curved bridge structure if not designed properly. At present, it is very difficult to design bridges in relation to solar radiation because it is not known exactly how varying temperature distribution affects bridges; at least not specific enough for adoption in design. Standard regulations related to this matter are likewise not complete. In this study, the thermal behavior of curved steel box girder bridges is analyzed while taking the solar radiation effect into consideration. For the analysis, a method of predicting the 3-dimensional temperature distribution of curved bridges was developed. It uses a theoretical solar radiation energy equation together with a commercial FEM program. The behavior of the curved steel box girder bridges was examined using the developed method, while taking into consideration the diverse range of bridge azimuth angles and radii. This study also provides reference data for the thermal design of curved steel box girder bridges under solar radiation, which can be used to develop design guidelines.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.1A
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• pp.125-133
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• 2008

According to longer and longer span, dynamic instability of stay cable should be prevented. Dynamic instability occurs mainly symmetric 1st mode and antisymmetric 1st mode in stay cable. Especially symmetric 1st mode has a lot of influence on sag. Therefore fundamental frequency of stay cable is different from that of taut sting. Irvine, Triantafyllou, Ahn etc. analyzed dynamic behavior of taut cable with sag through analytical technical and their researches give important results for large bounds of Irvine parameter. But each research shows mutually different values out of characteristic (cross-over or mode-coupled) point and each solution of frequency equations of all researchers can be very difficultly found because of their very high non-linearity. Presented study focuses on fundamental frequency of stay cable. Generalized mechanical energy with symmetric 1st mode vibration shape satisfied boundary conditions is evolved by Rayleigh-Ritz method. It is possible to give linear analytic solution within characteristic point. Error by this approach shows only below 3% at characteristic point against existing researches. And taut cable don't exceed characteristic point. I.e. high accuracy, easy solving techniques, and a little bit limitations. Therefore presented study can be announced that it is good study ergonomically.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.1B
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• pp.11-20
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• 2008

The spillway type of small and midsize dams in Korea is almost overflow weir. To examine flood control capacity of overflow spillway, FLOW-3D was applied to Daesuho dam and analysis was focused on the discharge of dam spillway by changing weir shape. Overflow phases and discharges of linear labyrinth weir and curved labyrinth weir were compared with those of existing linear ogee weir. Hydraulic model experiment was performed to verify numerical result. Verification results showed that overflow behaviors and flow characteristics in the side channel by hydraulic model experiment and numerical simulation are well matched, and water surface elevation at side wall coincides with each other. When the reservoir elevation was increased up to design flood level, in case of the linear ogee weir the flow over the crest ran through smoothly in the side channel, whereas in cases of linear labyrinth weir and curved labyrinth weirs, the flow discharge was increased by 40 cms, and the flow over the weir crest, rotating counter-clockwise, was submerged in the side channel. The results of the water level-discharge curve revealed that labyrinth weir can increase discharge by 71% compared to the discharge of linear ogee weir at low reservoir elevation since it can have longer effective length. But as water surface elevation rises, the slope of water level-discharge curve of labyrinth weir becomes milder by submergence and nappe interference in the side channel.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.5A
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• pp.861-872
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• 2006

The element free Galerkin method is extended by the local partition of unity method to model the cohesive cracks in two dimensional continuum. The shape function of a particle whose domain of influence is completely cut by a crack is enriched by the step enrichment function. If the domain of influence contains a crack tip inside, it is enriched by a branch enrichment function which does not have the LEFM stress singularity. The discrete equations are obtained directly from the standard Galerkin method since the enrichment is only for the displacement field, which satisfies the local partition of unity. Because only particles whose domains of influence are influenced by a crack are enriched, the system matrix is still sparse so that the increase of the computational cost is minimized. The condition for crack growth in dynamic problems is obtained from the material instability; when the acoustic tensor loses the positive definiteness, a cohesive crack is inserted to the point so as to change the continuum to a discontiuum. The crack speed is naturally obtained from the criterion. It is found that this method is more accurate and converges faster than the classical meshless methods which are based on the visibility concept. In this paper, several well-known static and dynamic problems were solved to verify the method.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.1A
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• pp.191-203
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• 2006

The vibration characteristics of composite stiffened laminated plates with stiffener is presented using the assumed natural strain 9-node shell element. To compare with previous research, the stiffened plates are composed of carbon-epoxy composite laminate with a symmetric stacking sequence. Also, the result of the present shell model for the stiffener made of composite material is compared with that of the beam model. In the case of torsionally weak stiffener, a local buckling occurs in the stiffener. In this case, the stiffener should be idealized by using the shell elements. The current investigation concentrates upon the vibration analysis of rectangular stiffened and unstiffened composite plates when subjected to the in-plane compression and shear loads. The in-plane compression affect the natural frequencies and mode shapes of the stiffened laminated composite plates and the increase in magnitude of the in-plane compressive load reduces the natural frequencies, which will become zero when the in-plane load is equal to the critical buckling load of the plate. The natural frequencies of composite stiffened plates with shear loads exhibit the higher values than the case of without shear loads. Also, the intersection, between the curves of frequencies against in-plane loads, interchanges the sequence of some of the mode shapes as a result of the increase in the inplane compressive load. The results are compared with those available in the literature and this result shows that the present shell model for the stiffened plate gives more accurate results. Therefore, the magnitude, direction type of the in-plane shear and compressive loads in laminated composite stiffened plates should be selected properly to control the specific frequency and mode shape. The Lanczos method is employed to solve the eigenvalue problems.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.6C
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• pp.321-329
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• 2008

In this study, a series of column test as a way in order to make up for the weakness point of the conventional acceleration method were conducted to both propose the suction board drain method and grapes the specific improvement character of this method as a result of a sort of plastic drain board and a phase of vacuum pressure conditions. On this occasion, the study focused on computing the effective factors of the fittest Suction board drain method affected by each condition through confirming the settlement generated during the test, the water content reduction and stress increase effect occurred arising from the test, and the ratio of consolidation related to the improvement period. In accordance with the shape of core and that whether the core is attached to the filter(pocket or adhesion), the castle type of adhesion and the column type of pocket are more efficient than the others as a consequence of the test to find out the improvement effect depending on each drainage such as a castle type, coil type, harmonica type, column type of pocket and a castle of the adhesion. In case of the step suction pressure, the shorter the period of $-0.8\;kg/cm^2$ as a final step of the suction pressure is, the better the improvement is. In addition, the correlation between degree of consolidation per each suction pressure level and duration of application was drawn as a curve and the point of inflection on this curve was provided to determine the duration period to maximize the consolidation.