• Title/Summary/Keyword: Separation Behavior

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A reliability-based fragility assessment method for seismic pounding between nonlinear buildings

  • Liu, Pei;Zhu, Hai-Xin;Fan, Peng-Peng;Yang, Wei-Guo
    • Structural Engineering and Mechanics
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    • v.77 no.1
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    • pp.19-35
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    • 2021
  • Existing methods to estimate the probability of seismic pounding occurrence of adjacent buildings do not account for nonlinear behavior or only apply to simple lumped mass systems. The present study proposes an efficient method based on subset simulation for fragility and risk assessment of seismic pounding occurrence between nonlinear adjacent buildings neglecting pounding effects with application to finite element models. The proposed method is first applied to adjacent buildings modeled as elastoplastic systems with substantially different dynamic properties for different structural parameters. Seismic pounding fragility and risk of adjacent frame structures with different floor levels is then assessed, paying special attention to modeling the non-linear material behavior in finite element models. Difference in natural periods and impact location are identified to affect the pounding fragility simultaneously. The reliability levels of the minimum code-specified separation distances are also determined. In addition, the incremental dynamic analysis method is extended to assess seismic pounding fragility of the adjacent frame structures, resulting in higher fragility estimates for separation distances larger than the minimum code-specified ones in comparison with the proposed method.

Static and Fatigue Behavior of RC Beams Strengthened with Steel Plates

  • Oh, Byung-Hwan;Cho, Jae-Yeol;Cha, Soo-Won
    • KCI Concrete Journal
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    • v.14 no.1
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    • pp.51-60
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    • 2002
  • Strengthening of existing concrete structures is a major concern in recent years as the number of degraded structures increases. The purpose of this paper is to investigate the static and fatigue behavior of reinforced concrete (RC) beams strengthened with steel plates. To this end, a comprehensive test program has been set up and many series of strengthened beams have been tested. The major test variables include the plate thickness, adhesive thickness, and the shear-span to depth ratio. The test results indicate that the separation of plates is the dominant failure mechanism even for the full-span-length strengthened beams with steel plate. The theoretical ultimate load capacities for strengthened beams based on the full composite action of concrete beam and steel plate are found to be larger than the actual measured load capacities. The strengthened beams exhibit more dominant shear cracking as the shear-span to depth ratio decreases. The ultimate capacity of strengthened beams increases slightly with the increase of adhesive thickness, which may be caused by the late initiation of plate separation in the beams with thicker adhesive. A realistic concept of ductility for plate-strengthened beams is proposed in this study. It is seen that the strengthened beams show relatively low ductility compared with unstrengthened beams. The present study indicates that the strengthened beams exhibit much higher fatigue resistance than the unstrengthened beams. The increase of deflections of strengthened beams according to the number of load cycles is much smaller than that of unstrengthened beams. The present study provides very useful results for the realistic application of plate-strengthening method in reinforced concrete structures.

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Facile Synthesis of g-C3N4 Modified Bi2MoO6 Nanocomposite with Improved Photoelectronic Behaviors

  • Zhu, Lei;Tang, Jia-Yao;Fan, Jia-Yi;Sun, Chen;Meng, Ze-Da;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.31 no.11
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    • pp.593-600
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    • 2021
  • Herein, a series of g-C3N4 modified Bi2MoO6 nanocomposites using Bi2MoO6 and melamine as original materials are fabricated via sintering process. For presynthesis of Bi2MoO6 an ultrasonic-assisted hydrothermal technique is researched. The structure and composition of the nanocomposites are characterized by Raman spectroscopy, X-ray diffraction (XRD), and high-resolution field emission scanning electron microscopy (SEM). The improved photoelectrochemical properties are studied by photocurrent density, EIS, and amperometric i-t curve analysis. It is found that the structure of Bi2MoO6 nanoparticles remains intact, with good dispersion status. The as-prepared g-C3N4/Bi2MoO6 nanocomposites (BMC 5-9) are selected and investigated by SEM analysis, which inhibits special morphology consisting of Bi2MoO6 nanoparticles and some g-C3N4 nanosheets. The introduction of small sized g-C3N4 nanosheets in sample BMC 9 is effective to improve the charge separation and transfer efficiency, resulting in enhancing of the photoelectric behavior of Bi2MoO6. The improved photoelectronic behavior of g-C3N4/Bi2MoO6 may be attributed to enhanced charge separation efficiency, photocurrent stability, and fast electron transport pathways for some energy applications.

Zeolite Membranes: Functionalizing of Properties by Tailored Compositions (제올라이트 분리막: 조성 변경을 통한 분리막 성질의 조절)

  • Richter, Hannes;Weyd, Marcus;Simon, Adrian;Kuhnert, Jan-Thomas;Gunther, Christiane;Voigt, Ingolf;Michaelis, Alexander
    • Membrane Journal
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    • v.27 no.6
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    • pp.469-476
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    • 2017
  • Membrane separation is a technology of low energy consumption. Membranes made of zeolites are of great interest because their fixed and open pores in the size of small molecules inside crystalline structures allow separation processes under harsh conditions. While zeolite NaA (LTA-type) is industrially used for dewatering of organic solvents, its pore size and thermal and hydrothermal stability can be tuned by exchange of framework and extra-framework elements. SOD with pores of only 0.28 nm is of great interest for $H_2$- und $H_2O$-separation and also can be tuned by ion exchange. Zeolites open the opportunity to create membranes of adapted separation behavior for small molecules in conditions of surrounding technical processes.

Effect of Concentration Polarization on The Pervaporation of Aqueous Chlorinated-Organic Solution (유기염화물 수용액의 투과증발에 미치는 농도분극의 영향)

  • Cho, Min-Suk;Kim, Seung-Jai;Kim, Jin-Hwan
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.698-703
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    • 1998
  • The pervaporation experiments of aqueous solutions of trichloroethylene (TCE) and chlorobenzene (CB) through the silicone rubber (polydimethylsiloxane, PDMS) membrane were carried out and the effect of concentration polarization on the separation characteristics was investigated. The resistance-in-series model was used to explain the boundary layer resistance. It was clear that the concentration polarization phenomenon had a significant effect on the permeation behavior in the pervaporation separation of the trace organic chlorides from aqueous solutions. With the same membrane thickness, the permeation of TCE, which has a stronger affinity for the PDMS, appeared to be more influenced by the boundary layer resistance than that of CB. The effect of boundary layer resistance was reduced and the membrane resistance became dominant with increasing membrane thickness at a given hydrodynamic condition. The separation factor was increased to approach the intrinsic separation factor of the membrane with its thickness.

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A Transient Separation Behavior of PDMS/PSF Hollow Fiber Membrane Modules for Ethanol-Water Mixtures (PDMS/PSF 중공사 분리막의 시간 의존적 에탄올-물 분리 거동 연구)

  • Muhammad Junaid, Ammar;Arepalli, Devipriyanka;Kim, Min-Zy;Ha, Seong Yong;Cho, Churl Hee
    • Membrane Journal
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    • v.32 no.2
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    • pp.163-171
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    • 2022
  • Many studies on pervaporation (PV) for the separation of dilute alcohols as an alternative to conventional energy-intensive technique of distillation have been conducted earlier. The pervaporation transition behavior of ethanol-water mixtures through the PDMS/PSF membrane is important, in order to understand the mechanism of diffusion process. Therefore, in the present work, transient PV behavior for 50 wt% EtOH/H2O mixture at 50℃ was investigated by using 1194 cm2 PDMS/PSF hollow fiber membrane modules. The overall total flux and the separation factor of all the membrane modules increased initially and then gradually decreased with respect to PV time. The initial increase can be attributed to fact that membrane fibers were dry and it took time to dissolve into the membrane surface, but the subsequent decrease is due to the depletion of ethanol concentration in the feed. Therefore, it was confirmed that the ethanol permeation through a PDMS membrane is governed by the solution-diffusion mechanism.

Characteristics of the Electrochemical Ion Exchanger for the Treatment of Cations in Nuclear Wastewater (원자력 폐수의 양이온 처리를 위한 전기화학적 이온교환체의 특성)

  • Hwang, Young-Gi
    • Journal of the Korean Society of Industry Convergence
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    • v.19 no.4
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    • pp.176-184
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    • 2016
  • Electrochemical ion exchange method is expected to be one of the most acceptable techniques for the separation of radioactive cations from nuclear wastewater. In this study a thin film of hexacyanoferrate on nickel surface was derivatized chemically in an aqueous potassium-ferricyanide solution. Electrochemical redox behavior of the nickel hexacyanoferrate(NiHCNFe) film electrode was investigated with the use of cyclic voltammetry potentiostated from -100 to 800 mV versus SCE. The electro-reduction characteristics of the NiHCNFe film were examined in the cobalt solutions. The NiHCNFe ion exchanger was more useful at lower concentration, lower temperature, and pH7 of the cobalt solution. The capacity loss of NiHCNFe was 0.018%/cycle that was less than the average loss of 2~3%/cycle of the convective organic exchanger. The 45~55% of the initial cobalt ions was electro-deposited on the NiHCNFe by using continuous recirculating reactor system. As a result, it was found that the electroactive NiHCNFe films showed better performance than the organic resins for the separation of cobalt ion from the aqueous solutions.

Mobility Support Architecture in Locator-ID Separation based Future Internet using Proxy Mobile IPv6

  • Seok, Seung-Joon
    • Journal of the Korean Institute of Intelligent Systems
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    • v.24 no.2
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    • pp.209-217
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    • 2014
  • Of several approaches for future Internet, separating two properties of IP address into locator and identifier, is being considered as a highly likely solution. IETF's LISP (Locator ID Separation Protocol) is proposed for this architecture. In particular, the LISP model easily allows for device mobility through simple update of information at MS (Mapping Server) without a separate protocol. In recent years, some of the models supporting device mobility using such LISP attributes have emerged; however, most of them have the limitation for seamless mobility support due to the frequent MS information updates and the time required for the updates. In this paper, PMIPv6 (Proxy Mobile IPv6) model is applied for mobility support in LISP model. PMIPv6 is a method that can support mobility based on network without the help of device; thus, this we define anew the behavior of functional modules (LMA, MAG and MS) to fit this model to the LISP environment and present specifically procedures of device registration, data transfer, route optimization and handover. In addition, our approach improves the communication performance using three tunnels identified with locators between mobile node and corresponding node and using a route optimized tunnel between MN's MAG and CN's MAG. Finally, it allows for seamless mobility by designing a sophisticated handover procedure.

Capillary Electrophoresis of Single-stranded DNA

  • Choi, Hyun-Ju;Kim, Yong-Seong
    • Bulletin of the Korean Chemical Society
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    • v.24 no.7
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    • pp.943-947
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    • 2003
  • We have studied the migration behavior of single-stranded DNA using capillary gel electrophoresis under various conditions. It was found that optimum electric fields should be less than 150 V/cm for the good tradeoff between the separation time and the resolution. It seems that the gel matrix with the combination of different polymer average molecular weights is important to extend the maximum readable DNA bases. The total gel concentration less than 3.1% in the mixed gel system showed good separation efficiency up to 600 bases. The best result was obtained with the poy(ethylene)oxide (PEO) gel concentration of 1.2% of Mr 8,000,000 and 1.8% of Mr 600,000. We observed that the capillary length between 50 cm to 100 cm (effective length) should be employed for the optimization between the total DNA migration time and the maximum readable length. A trizma base-boric acid-ethlyenediaminetetraacetic acid (EDTA) (TBE) buffer was commonly used for DNA sequencing, but we found that 3-[tris(hydroxymethyl)methyl amino]-1-propane sulfonic acid (TAPS) buffer worked as well for the single-stranded DNA separation. Especially, TAPS buffer showed a good resolution for very short DNA bases (1 to 30 bases).

Prediction on the Chiral Behaviors of Drugs with Amine Moiety on the Chiral Cellobiohydrolase Stationary Phase Using a Partial Least Square Method

  • Choi, Sun-Ok;Lee, Seok-Ho;Park Choo , Hea-Young
    • Archives of Pharmacal Research
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    • v.27 no.10
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    • pp.1009-1015
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    • 2004
  • Quantitative Structure-Resolution Relationship (QSRR) using the Comparative Molecular Field Analysis (CoMFA) software was applied to predict the chromatographic behaviors of chiral drugs with an amine moiety on the chiral cellobiohydrolase (CBH) columns. As a result of the Quantitative CoMFA-Resolution Relationship study, using the partial least square method, prediction of the behavior of drugs with amine moiety upon chiral separation became possible from their three dimensional molecular structures. When a mixed mobile phase of 10 mM aqueous phosphate buffer (pH 7.0) - isopropanol (95 : 5) was employed, the best Quantitative CoMFA-Resolution Relationship, derived from the study, provided a cross-validated $q^2$ = 0.933, a normal $r^2$ = 0.995, while the best Quantitative CoMFA-Separation Factor Relationship, also derived from the study, yielded a cross-validated $q^2$ = 0.939, a normal $r^2$ = 0.991. When all of these results are considered, this QSRR-CoMFA analysis appears to be a very useful tool for the preliminary prediction on the chromatographic behaviors of drugs with an amine moiety inside chiral CBH columns.