• Journal of the Korean Chemical Society
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• v.55 no.5
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• pp.733-740
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• 2011

Multiple regression analysis was used for the calculation of pKa values of 15 substituted benzaldoximes by using various types of descriptors as parameters. These descriptors are based on quantum mechanical treatments. They were derived by employing semi-empirical calculation represented by the PM3 model and an Abinitio method expressed by Hartree-Fock(HF) model performed at the 6-311 G(d, p) level of theory. The parameters tested for their ability to represent the variations observed in the experimental pKa(s) are atomic and structural properties including Muliken charges on the atoms of hydroxyl group and C=N bond, the angle $C_6-C_1-C_7$, and length of O-H bond. Molecular properties are also used like energies of HOMO and LUMO, hardness(${\eta}$), chemical potential(${\mu}$), total energy(TE), dipole of molecule(DM), and electrophilicity index(W). The relation between pKa values and each of these parameters of the studied compounds is investigated. Depending on these relations, two sets of parameters were constructed for comparison between the PM3 and HF methods. The results obtained favor the Abinitio method for such applications although both models proved to have high predictive power and have sufficient reliability to describe the effect of substituents on pKa values of benzaldoxime compounds under consideration which is clear from the values of correlation coefficient $R^2$ obtained and the consistency between the experimental and the calculated values.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.2B
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• pp.175-185
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• 2011

This study investigates tsunami force acting on a group of onshore structures numerically by using three-dimensional one-field model for immiscible multi-phase flows, which is based on Navier-Stokes solver. In particular, we studied on the characteristics of tsunami with respect to the arrangement of onshore structures and the distance from seawall trough numerical experiments. For validation of the numerical method used in this study to calculate tsunami force, numerical results for tsunami force on the structures in coastal area are compared with available experimental data. Furthermore, a detail study on the efficiency of the numerical method is performed for the estimation of tsunami force based on the hydrostatic and hydrodynamic methods in which the numerical results are used. The obtained results are compared to the previous experimental one and design criteria. Considering both experimental results and numerical analysis results, semi-empirical formula by regression analysis is proposed. As a result, it was confirmed that the numerical analysis is effective to estimate on tsunami force acting on onshore structures.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.43 no.3
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• pp.187-194
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• 2015

Course correction munition is a smart projectile which improves its accuracy by the control mechanism equipped in the fuze section with canard. In this paper, various aerodynamic configurations of the fuze section were analysed by utilizing a semi-empirical method and a CFD method. A final canard configuration showing the least drag was then determined. During the CFD simulation, it was found that the k-${\omega}$ SST turbulence model combined with O-type grid base is suitable for the prediction of the base drag. Finally, the aerodynamic characteristics of the smart munition and the change of drag due to the canard installation were analysed.

• The KSFM Journal of Fluid Machinery
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• v.18 no.2
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• pp.14-21
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• 2015

Design lifetime of a wind turbine is required to be at least 20 years. The most important step to ensure the deign is to evaluate the loads on the wind turbine as accurately as possible. In this study, extreme design load of a offshore wind turbine using Garrad Hassan (GH) Bladed and National Renewable Energy Laboratory (NREL) FAST codes are calculated considering structural dynamic loads. These wind turbine aeroelastic analysis codes are high efficiency for the rapid numerical analysis scheme. But, these codes are mainly based on the mathematical and semi-empirical theories such as unsteady blade element momentum (UBEM) theory, generalized dynamic wake (GDW), dynamic inflow model, dynamic stall model, and tower influence model. Thus, advanced CFD-dynamic coupling method is also applied to conduct cross verification with FAST and GH Bladed codes. If the unsteady characteristics of wind condition are strong, such as extreme design wind condition, it is possible to occur the error in analysis results. The NREL 5 MW offshore wind turbine model as a benchmark case is practically considered for the comparison of calculated designed loads. Computational analyses for typical design load conditions such as normal turbulence model (NTM), normal wind profile (NWP), extreme operation gust (EOG), and extreme direction change (EDC) have been conducted and those results are quantitatively compared with each other. It is importantly shown that there are somewhat differences as maximum amount of 18% among numerical tools depending on the design load cases.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.27 no.4
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• pp.293-302
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• 1991

The anomalous sea level deviation or storm surge caused by the typhoon Thelma in 1987 are studied analysing tidal observation data at 7 stations in the south coast of Korean peninsula. The surges are calculated by subtracting the predicted tidal height from the observed tidal record. The tidal deviation at these stations along the coast are discussed in association with meteorological data. The sea level anomalies are studied by means of the empirical orthogonal function (EOF) analysis and the fast fourier transform (FFT) method. The results of analysis suggest that the peak value of surges are higher at the tidal stations in semi-enclosed bay and in long narrow channel than at the ones facing with the open sea. From the result of EOF analysis, the temporal and spatial fluctuations of storm surge can be described by the first EOF mode, which explains 63% of the total variances during the passage of typhoon Thelma. The deviation of storm surge in the studied areas indicates bi-modal peak during the passage of typhoon Thelma. From the results of FFT spectrum analysis, the peak of energy of autospectrum for surge, atmospheric pressure, and wind stress appeared at low frequency fluctuations band of 0.008-0.076 cph over the 4 stations. Auto-correlation function of surge showed periodicity, while that of atmospheric pressure and wind stress indicates no periodicity. The result of FFT analysis shows that the typhoon surges are related chiefly with the change of atmospheric pressure in an open bay (Cheju Harbor), but with the wind stress in a semi-enclosed bay (Yeosu Harbor).

• Journal of the Korean Association of Geographic Information Studies
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• v.18 no.1
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• pp.48-63
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• 2015

In this study, we introduce various hyperspectral data processing techniques for the monitoring of shallow and coastal waters to enlarge the application range and to improve the accuracy of the end results in Korea. Unlike land, more accurate atmospheric correction is needed in coastal region showing relatively low reflectance in visible wavelengths. Sun-glint which occurs due to a geometry of sun-sea surface-sensor is another issue for the data processing in the ocean application of hyperspectal imagery. After the preprocessing of the hyperspectral data, a semi-analytical algorithm based on a radiative transfer model and a spectral library can be used for bathymetry mapping in coastal area, type classification and status monitoring of benthos or substrate classification. In general, semi-analytical algorithms using spectral information obtained from hyperspectral imagey shows higher accuracy than an empirical method using multispectral data. The water depth and quality are constraint factors in the ocean application of optical data. Although a radiative transfer model suggests the theoretical limit of about 25m in depth for bathymetry and bottom classification, hyperspectral data have been used practically at depths of up to 10 m in shallow and coastal waters. It means we have to focus on the maximum depth of water and water quality conditions that affect the coastal applicability of hyperspectral data, and to define the spectral library of coastal waters to classify the types of benthos and substrates.

• JSTS:Journal of Semiconductor Technology and Science
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• v.10 no.4
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• pp.265-275
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• 2010

In this work, reliable methodology for device design is presented. Based on this method, the underlap length has been optimized for minimizing the gateinduced drain leakage (GIDL) in a 22-nm node 4-terminal (4-T) silicon-on-insulator (SOI) fin-shaped field effect transistor (FinFET) by TCAD simulation. In order to examine the effects of underlap length on GIDL more realistically, doping profile of the source and drain (S/D) junctions, carrier lifetimes, and the parameters for a band-to-band tunneling (BTBT) model have been experimentally extracted from the devices of 90-nm channel length as well as pnjunction test element groups (TEGs). It was confirmed that the underlap length should be near 15 nm to suppress GIDL effectively for reliable low standby power (LSTP) operation.

• BMB Reports
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• v.31 no.5
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• pp.459-467
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• 1998

A new set of functional group interaction energy descriptors relevant to the ACE (Angiotensin-Converting Enzyme) inhibitory peptide, QSAR (Quantitative Structure Activity Relationships), is presented. The functional group interaction energies approximate the charged interactions and distances between functional groups in molecules. The effective energies of the computationally derived geometries are useful parameters for deriving 3D-QSAR models, especially in the absence of experimentally known active site conformation. ACE is a regulatory zinc protease in the renin-angiotensin system. Therapeutic inhibition of this enzyme has proven to be a very effective treatment for the management of hypertension. The non bond interaction energy values among functional groups of six-feature of ACE inhibitory peptides were used as descriptor terms and analyzed for multivariate correlation with ACE inhibition activity. The functional group interaction energy descriptors used in the regression analysis were obtained by a series of inhibitor structures derived from molecular mechanics and semi-empirical calculations. The descriptors calculated using electrostatic and steric fields from the precisely defined functional group were sufficient to explain the biological activity of inhibitor. Application of the descriptors to the inhibition of ACE indicates that the derived QSAR has good predicting ability and provides insight into the mechanism of enzyme inhibition. The method, functional group interaction energy analysis, is expected to be applicable to predict enzyme inhibitory activity of the rationally designed inhibitors.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.465-465
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• 2009

Wind power is one of the most reliable renewable energy sources and the installed wind turbine capacities are increasing radically every year. Although wind power has been favored by the public in general, the problem with the impact of wind turbine noise on people living in the vicinity of the turbines has been increased. Low noise wind turbine design is becoming more important as noise is spreading more adverse effect of wind turbine to public. This paper demonstrates the design of 10 kW class wind turbines, each of three blades, a rotor diameter 6.4m, a rated rotating speed 200 rpm and a rated wind speed 10 m/s. The optimized airfoil is dedicated for the 75% spanwise position because the dominant source of a wind turbine blade has been known as trailing edge noise from the outer 25% of the blade. Numerical computations are performed for incompressible flow and for Mach number at 0.145 and for Reynolds numbers at $1.02{\times}10^6$ with a lift performance, which is resistant to surface contamination and turbulence intensity. The objective in the low design process is to reduce noise emission, while sustaining high aerodynamic efficiency. Dominant broadband noise sources are predicted by semi-empirical formulas composed of the groundwork by Brooks et al. and Lowson associated with typical wind turbine operation conditions. During the airfoil redesign process, the aerodynamic performance is analyzed to minimize the wind turbine power loss. The results obtained from the design process show that the design method is capable of designing airfoils with reduced noise using a commercial 10 kW class wind turbine blade airfoil as a basis. The new optimized airfoil clearly indicates reduction of total SPL about 3 dB and higher aerodynamic performance.

• Nuclear Engineering and Technology
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• v.23 no.2
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• pp.200-209
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• 1991

A new semi-empirical average heat transfer correlation applicable for both laminar and turbulent film-wise condensation on a vertical surface has been presented. Re functional form of the present correlation is based on the representative existing correlations for laminar and turbulent film flows, whereas the numerical coefficients of the present correlation have been determined by the least squares method using experimental data obtained from the open literatures. In addition, the performance of the present as well as the seven existing correlations (four for laminar and three for turbulent film flow regimes) were evaluated for their accuracy and the range of application. The result shows that for laminar film filow regimes Zazuli's and the present correlations give the samllest values of mean error, whereas for turbulent film How regimes Kirkbride and Badger's and the present correlations produce the smallest values of mean error.