• Title/Summary/Keyword: Self-purification

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Association of PAH-DNA adducts and Urinary PAH metabolites influenced by polymorphisms of xenobiotic metabolism enzymes in industrial wase incinerating workers (산업폐기물 소각장 근로자에서 요중 PAHs 대사산물과 혈중 aromatic-DNA adducts)

  • ;Masayoshi Ichiba
    • Environmental Mutagens and Carcinogens
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    • v.22 no.4
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    • pp.303-311
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    • 2002
  • This study evaluated the concentrations of urinary metabolites of polycyclic aromatic hydrocarbons (PAHs) in industrial waste incineration workers. The effect of genetic polymorphisms of xenobiotic metabolism enzymes on urinary concentration of PAH metabolites was assessed. And, aromatic DNA adduct levels were also determined in total white blood cells. Fifty employees were recruited from a company handling industrial wastes located in Ansan, Korea: non-exposed group (n=21), exposed group (n=29). Sixteen ambient PAHs were determined by GC/MSD (NIOSH method) from personal breathing zone samples of nine subjects near incinerators. Urinary 1-hydroxypyrene glucuronide (1-OHPG), a major pyrene metabolite, was assayed by synchronous fluorescence spectroscopy after immunoaffinity purification using monoclonal antibody 8E11 (SFS/IAC). Multiplex PCR was used for genotyping for GSTMI/TI and PCR-RFLP for genotyping of CYP1A1 (MspI and Ile/Val). PAH-DNA adducts in peripheral blood WBC were measured by the nuclease P1-enhanced postlabeling assay. Smoking habit, demographic and occupational information were collected by self-administered questionnaire. The range of total ambient PAH levels were 0.00-7.00 mg/㎥ (mean 3.31). Urinary 1-OHPG levels were significantly higher in workers handling industrial wastes than in those with presumed lower exposure to PAHs (p=0.006, by Kruskal-Wallis test). There was a statistically significant dose-response increase in 1-OHPG levels with the number of cigarettes consumed per day (Pearson correlation coefficient=0.686, p<0.001). Urinary 1-OHPG levels in occupationally exposed smoking workers were highest compared with non-occupationally exposed smokers (p=0.053, by Kruskal-Wallis test). Smoking and GSTMI genotype were significant predictors for log-transformed 1-OHPG by multiple regression analysis (overall model R²=0.565, p<0.001), whereas smoking was the only significant predictor for log-transformed aromatic DNA adducts (overall model R²=0.249, p=0.201). Aromatic DNA adducts was also a significantly correlation between log transferred urinary 1-OHPG levels (pearson's correlation coefficient=0.307, p=0.04). However, the partial correlation coefficient adjusting for Age, Sex, and cigarette consumption was not significant (r=0.154, p=0.169). The significant association exists only in individuals with the GSTMI null genotype (pearsons correlation coefficient=0.516, p=0.010; partial correlation coefficient adjusting for age, sex, and cigarette consumption, r=0.363, p=0.038). Our results suggest that the significant increase in urinary 1-OHPG in the exposed workers is due to higher prevalence of smokers among them, and that the association between urinary PAH metabolites and aromatic DNA adducts in workers of industrial waste handling may be modulated by GSTMI genotype. There results remain to be confirmed in future larger studies.

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Analysis on the Type of Damaged Land in DeMilitarized Zone(DMZ) Area and Restoration Direction (비무장지대(DMZ) 인근의 훼손지 유형 분석 및 복원방향)

  • Sung, Hyun-Chan;Kim, Su-Ryeon;Kang, Da-In;Seo, Joung-Young;Lee, Sang-Mi
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.19 no.1
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    • pp.185-193
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    • 2016
  • Purpose of this study is to classify damaged lands according to the cause of the damage and their influences based on characteristic of the damaged lands in DeMilitarized Zone(DMZ) area, and utilize this study as a fundamental study for establishment of ecosystem restoration system. Literature review and field survey have been conducted to review the damage status of DMZ area. For field survey, first year and second year have been conducted, in which type of the damage has been reviewed in this study. In the result, types of damage have been classified into 6 categories: 'alteration of initial landform', 'loss of surface layer', 'land pollution', 'alteration of soil chemical property', 'decline of vegetation', and 'invasion of foreign species'. Restoration for each damage type is as following. First, for alteration of initial landform, the land is restored to the original landform prior to the damage and connection to surrounding ecosystem is considered. Second, for loss of surface layer, lost surface layer is restored or further loss is prevented with stabilization. Third, for land pollution, source of the pollution is eradicated or self-circulation with purification of polluted land is encouraged. Fourth, for alteration of soil chemical property, soil is restored of its original property with eradication of the pollution source and improvement of soil. Fifth, for decline of vegetation, current vegetation and anticipated alteration in future are considered and number of wild species is to be increased based on structure and characteristic of nearby vegetation. Sixth, for invasion of foreign species, prevention of dominance by risky species and facilitation ecological stability with ecological management are to be considered. Influence according to the cause of damage has occurred in secondary(indirect) influence or simultaneous occurrence of several damage types. Considering all these aspects, when type of the damage is complex, restoration process for each of former mentioned 6 damage types with solitary influence should be considered in unison.

Developing Evaluation Index and Item for Water Environment Improvement of Gyeongin ARA Waterway (경인 아라뱃길의 물환경 개선을 위한 오염원인 평가항목 및 지표 개발)

  • Lee, Kyung-Su;Kim, Tae-Hyeong
    • The Journal of the Korea Contents Association
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    • v.18 no.8
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    • pp.469-482
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    • 2018
  • This research has developed the criteria and index for systematically and objectively assessing the quality of river water by fixing the various factors that affect Gyeongin ARA waterway's water quality through analysis with the Delphi Technique and analytic hierarchy program (AHP) Method. Based on the results, the highest criteria are, in order of importance, physical and environmental factors 28%, administrative factors 26%, natural fixed factors 26% and finally, cultural and social factors 20%. The three dimensions of the criteria show that for the internal physical and environmental factors, the most important are the loss of self-purification capacity, and the external factors are Gulpocheon and the sludge deposit due to Gyulhweon-weir the bridge. The facility factor in management was affected by the coagulation and waste water disposal facilities. The problem for the policy and institutional factors was seen in the regulatory area. The aquatic ecology/ point pollution source for the natural fixed factors show that it is due to the polluted water of Gulpo-cheon and the living environment/ non-point pollution source is shown through the inflow water from other rivers. Cultural and social factors show that the economical causes were due to the cargo and passenger flight operations and the external factors of having a lack of sewage treatment equipment have an importance effect. In order to estimate the order of priority through logical evidence and objectivity, future research must be continued on the evaluation indexes to measure the specific methodology and technique needed to improve the Gyeongin ARA Waterway.

Economic Management of River Water Quality by Utilization of Self Purification-An Environmental Resource (환경자원의 자정능력 선용을 통한 경제적 하천 수질관리)

  • Koo, Ja Kong;Lee, Byung Kuk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.13-21
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    • 1987
  • The object of this study was to evaluate the management alternatives with respect to the attainable water quality and total cost(construction+O & M cost) in order to devise a reasonable water quality management system. Joong Ryang-cheon stream located Seoul, Korea was taken as the study area, and dissolved oxygen concentration as the water quality index. Water quality simulation model QUAL2E and linear programming optimization technique were used for scientific and rational analyses. It was assumed that the improvement of water quality could be obtained by the treatment of major point sources where imaginary treatment plants were constructed. And by this, the relationship between total cost of the treatment plants and the stepwise improvement of water quality was studied. The result showed that 3.5mg/l of DO(=dissolved oxygen) level at best could be attained in Joong Ryang-cheon stream during summer. When the DO standard was set 3.0mg/l in the severely polluted regions, more than 5.0mg/l of DO level can be achieved by the construction of 4 treatment plants. Also, the cost comparisons showed that the uniform treatment method is economically inefficient(\$24.8{\times}10^8$) in comparison with the least cost method(\$22.9{\times}10^8$), and there is little difference between the least cost method and the the zoned treatment method(\$23.0{\times}10^8$) that is regarded as more equitable, which shows the characteristics of this basin.

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Effect of Film Thickness on the Photocatalytic Performance of TiO2 Film Fabricated by Room Temperature Powder Spray in Vacuum Process (상온 진공 분말 분사공정에 의해 제조된 TiO2 광촉매 막의 두께변화에 따른 광촉매 특성)

  • Kim, Kun-Young;Ryu, Jung-Ho;Hahn, Byung-Dong;Choi, Jong-Jin;Yoon, Woon-Ha;Lee, Byoung-Kuk;Park, Dong-Soo;Park, Chan
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.839-844
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    • 2008
  • $TiO_2$ is an environment-friendly semiconducting material, and it has photocatalytic and hydrophilic effect. There are a lot of reports on the photocatalytic characteristics of $TiO_2$, such as organic pollutants resolving, anti-bacterial, and self-purification material. In this paper, $TiO_2$ micron-sized powders were deposited on the glass by room temperature powder spray in vacuum process, so called aerosol deposition (AD), and nano-grained $TiO_2$ photocatalytic thin films were fabricated. The thickness of the films were controlled by changing the number of deposition cycle. Morphologies and characteristics of the AD-$TiO_2$ thin films were examined by SEM, TEM, XRD, and UV-Visible Spectrophotometer. As the thickness of $TiO_2$ films increased, surface roughness increased. By this increment, the reaction area between film and pollutant was enlarged, resulting in better photocatalytic property.

Influence on the Land Use Factors Affecting the Water Quality of Iwonchon Basin (토지이용이 이원천 유역의 하천수질에 미치는 영향)

  • 이호준;방제용;김용옥
    • The Korean Journal of Ecology
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    • v.22 no.5
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    • pp.235-240
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    • 1999
  • Characterization of water quality was performed from March 1993 to March 1998, on the purpose of clarifying the relationships between water quality and land use types. The study sites were two reservoir basins; Kaesim and Jangchan in Iwon-myon, Okchon-gun, Chungcho'ngbukdo Province. The two basins were characterized by cultivated area (Kaesim reservoir) and mountain area (Jangchan reservoir), and divided into eleven small basins, where dynamics of pollutants, and the relationship between water quality and land use types were investigated. BOD, SS and TKN became lower and lower from up-stream to down-stream, except for the small basin G where self-purification limit was exceeded. And water quality of Jangchan reservoir basin was worse because of fish nursery. Area below altitude 200m occupied 56% in Kaesim and 44% in Jangchan reservoir basins. Especially total phosphorous (Y/sub T-P/=0.2023X+0.0991, r=0.54) and total nitrogen increased in small basins where the proportion of cultivated and residential area was higher. The analysis of influences of pollutant discharge on water quality showed that pollution charge was very high in cultivated areas. The concentrations of pollutants were attenuated flowing into watersheds through physical, chemical, biochemical, and biological processes. The pollution level of mountain area was lower than that of cultivated areas.

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Physicochemical Properties and Distribution of Heavy Metals in Stream Sediments of the Daejeon Area (대전지역 주요하천 하상퇴적물의 물리화학적 특성 및 중금속 분포)

  • Jeong, Chan-Ho;Lee, Sang-Gu
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.259-264
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    • 2006
  • This work carried out to analyze the physicochemical properties and investigate the assessment of heavy metal contamination of stream sediments of the Yudeung and the Gab streams in the Daejeon area. The pH of stream sediments of the Yudeung stream shows the range of weak acid and weak alkaline. Most of stream sediments contain about 80% sand grain and have low water and cation retention capacity. Hence the stream sediments are not suitable fur various plans to grow up. The analysis of heavy metals in the stream sediments shows that the concentration of Pb, Cr and Cd increases from upstream to down stream. It is likely that the trend has a relationship with the water. Contamination of stream water. The authors recommend that clay materials be replenished in the stream sediments to increase the self-purification capacity and to make the suitable condition for growing up of various plants, and that water quality of the stream which can Influence into the contamination of stream sediments be monitored.

Studies on the Manufacturing of Red Ginseng Extract for Alcoholic Beverages (알콜음료용(飮料用) 인삼(人蔘) Ext. 제조(製造)에 관(關)한 연구(硏究))

  • Sung, Hyun-Soon;Yang, Jai-Won;Park, Myung-Han;Kim, Man-Wook
    • Applied Biological Chemistry
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    • v.24 no.1
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    • pp.40-49
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    • 1981
  • A study was designed to produce a self-stable and clear Red Ginseng wine using ethanol solution for Red Ginseng extraction and low temperature treatment on the extract before packaging. Extraction of Red Ginseng at high temperature using low ethanol concentration caused an increase in the amount of crude Red Ginseng extract and a decrease of purified Red Ginseng extract. Extraction with 75% ethanol at $50{\sim}70^{\circ}C$, followed by dilution of the extract to the ethanol concentration of final product, resulted minimum precipitation in the Red Ginseng wine. Low temperature treatment at $4^{\circ}C$ retained all of the saponin content in crude extract while $-20^{\circ}C$ treatment caused a significant loss of saponin along with precipitation during purification.

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Numerical Simulations of Water Quality in ManKyong River (QUAL-II E 모델에 의(依)한 만경강(萬頃江)의 수질예측(水質豫測))

  • Shim, Jae-Hwan;Choi, Moon-Sul
    • Korean Journal of Environmental Agriculture
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    • v.10 no.1
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    • pp.67-75
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    • 1991
  • The QUAL-II E Model was applied to predict the water quality of the Mankyong drainage System, and lead to following conclusion. 1. The difference between computed and measured BOD at the M-3 (Bakgugeong) station was within 10%, indicating that the application of the QUAL-IIE Model for the prediction of water quality was satisfactory thus far. 2. The application of the model states that the discharge of concentrated pollutants at the M-1 station on the Jeonju stream, located 41Km upstream from the estuary, causes the worst problems. The sluice which extends residence time and enlarges watery surface improves water quality by a Self-purification process at the M-3 station, 28km upstream from the estuary. 3. The accuracy of the model diminished when this model was applied on the estuary downstream of the sluice. Hence, the application of the model on the estuary needs to be used with caution. 4. Among the conputed water quality parameters, BOD is the worst problem. At the M-3 station, BOD is computed to be 26.6 mg/1 in 1996, 30.7 mg/1 in 2,001, 33.0 mg/l in 2006, and 37.5 mg/1 in 2011. When preventive measures against water pollution are not properly exercised, severe problems in irrigation and water resources are expected. This study will be of used in the selection of irrigation water intake points, the criteria of effluent treatment, the management of water resources, and the establishment of water quality managemont policy.

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Influence of Spa Sewage on the Water and Soil Pollution and Restoration I. Influence of Spa Sewage on the Pollution of Stream Water and Agricultural Land (온배수 유입 소형하천의 수질 및 토양오염과 회복에 관한 연구: I. 온배수가 인근 소하천과 농업 환경에 미치는 영향)

  • 정연태;이덕배;이경보;김미연;김백호;최민규;박승택
    • Korean Journal of Environmental Biology
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    • v.17 no.3
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    • pp.337-344
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    • 1999
  • This study was carried out to investigate the influence of spa sewage on water quality and chemical contents in the paddy soil along stream from 1997 to 1998. Concentration of $PO_4, SO_4, Cl, NH_{4}, Ca, Na$ and COD in the spa sewage were lower than standard for agricultural usage, and were lowered as the sewage flew to the into stream. The concentration of $SO_4$in spa sewage was over the criteria for agricultural usage in the inlet, but was lower than criteria for agricultural usage by inlet of non polluted stream water. Concentration of pollutants in the sediment of water channel were the highest in the inlet site. There were no pollutants accumulation in the paddy soil where spa sewage was irrigated. It may be resulted from nutrients uptake of rice plant and self purification of paddy soil. On the while, considering electric conductivity and nitrate in spa sewage, this results suggest that long-term irrigation of the spa sewage may be required general management with some decreasing fertilization.

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