• 제목/요약/키워드: Self diffusion

검색결과 386건 처리시간 0.021초

Cation Self-Diffusin and Impurity Diffusion of Mn and Zn in CoO: (I) A comparison of the Residual Activity and the Tracer Sectioning Method

  • Lee, Jong-Ho;Martin, Manfred
    • The Korean Journal of Ceramics
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    • 제4권2호
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    • pp.90-94
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    • 1998
  • Self diffusion coefficients of $^{67}$Co and impurity diffusion coefficients of $^{51}$Mn and $^{65}$Zn in single crystalline CoO have been measured by applying different radioactive isotopes simultaneously. To compare the residual activity method and the tracer sectioning method we analyzed our tracer diffusion experiments by using both methods simultaneously. According to our experimental results, the diffusion coefficients obtained from both methods are identical within experimental error, demonstrating the relibility of our experimental procedures. The diffusion coefficients of all the isotopes obtained during these test experiments for the methodology are similar in magnitude and show similar dependences on oxygen partial pressure. These first observations indicate that impurity diffusion of Mn and Zn occur via a vacancy mechanism as known for self diffusion of cobalt.

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INSTABILITY IN A PREDATOR-PREY MODEL WITH DIFFUSION

  • Aly, Shaban
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제13권1호
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    • pp.21-29
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    • 2009
  • This paper treats the conditions for the existence and stability properties of stationary solutions of a predator-prey interaction with self and cross-diffusion. We show that at a certain critical value a diffusion driven instability occurs, i.e. the stationary solution stays stable with respect to the kinetic system (the system without diffusion) but becomes unstable with respect to the system with diffusion and that Turing instability takes place. We note that the cross-diffusion increase or decrease a Turing space (the space which the emergence of spatial patterns is holding) compared to the Turing space with self-diffusion, i.e. the cross-diffusion response is an important factor that should not be ignored when pattern emerges.

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초기재령 콘크리트의 수분확산과 자체건조에 관한 연구 (Moisture Diffusion and Self-desiccation of Concrete at Early Ages)

  • 김진근;이칠성
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1998년도 봄 학술발표회 논문집(I)
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    • pp.303-308
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    • 1998
  • In the concrete structures exposed to environmental conditions at early ages, water movement occurs by moisture diffusion in the concrete, and self-desiccation of concrete is also occurred. Thus the internal relative humidity is changed from moisture diffusion and self-desiccation. Thus the internal relative humidity at each location in concrete includes the decrease by self-desiccation. Especially, for high-strength concrete the much unit cement content is used, so that the non-uniform relative humidity distribution is affected form self-desiccation at early ages. In this study, the internal relative humidity in concrete was measured at early ages, and the moisture diffusion component and self-desiccation component of total relative humidity were discussed.

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TURING INSTABILITY IN A PREDATOR-PREY MODEL IN PATCHY SPACE WITH SELF AND CROSS DIFFUSION

  • Aly, Shaban
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제17권2호
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    • pp.129-138
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    • 2013
  • A spatio-temporal models as systems of ODE which describe two-species Beddington - DeAngelis type predator-prey system living in a habitat of two identical patches linked by migration is investigated. It is assumed in the model that the per capita migration rate of each species is influenced not only by its own but also by the other one's density, i.e. there is cross diffusion present. We show that a standard (self-diffusion) system may be either stable or unstable, a cross-diffusion response can stabilize an unstable standard system and destabilize a stable standard system. For the diffusively stable model, numerical studies show that at a critical value of the bifurcation parameter the system undergoes a Turing bifurcation and the cross migration response is an important factor that should not be ignored when pattern emerges.

용융 폴리우레탄의 완화 스펙트럼에 의한 자체확산분포 결정 (Determination of Self Diffusion Distributions of Molten Polyurethanes by Relaxation Spectra)

  • 김남정
    • 대한화학회지
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    • 제50권3호
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    • pp.196-202
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    • 2006
  • 점탄성 용융 폴리우레탄의 자체확산분포가 완화스펙트럼과 자체확산분포 관계식으로부터 얻어졌다. ester, PCL PCL dyed 형의 용융 폴리우레탄의 완화스펙트럼은 실험적인 응력완화 곡선을 Ree-Eyring and Maxwell non-Newtonian model(REM 모델)이론식에 적용시켜서 얻는다. 용융폴리우레탄의 응력완화 실험은 온도조절 장치가 있는 physica 레오메타를 이용하여 여러 온도에서 수행되었다. 이론적인 완화스펙트럼은 REM model로부터 유도한 이론적인 완화스펙트럼식을 프로그램화한 컴퓨터 계산에서 구하였다. 폴리우레탄 시료의 자체확산과 비결정 영역의 홀거리가 응력완화 실험에 의해서 연구 조사되었다. 비결정 영역에서의 유동단위의 확산을 연구하기 위해서 확산계수와 홀부피가 유변학적인 파라메타와 결정크기로부터 계산되었다. 폴리우레탄 시료의 완화스펙트럼과 자체확산은 유동 단위의 분자량분포, 점도, 홀부피, 활성화에너지와 밀접한 관계가 있는 것을 알 수 있다.

자기치유 콘크리트의 균열치유 성능평가를 위한 개선된 산소확산 시험방법 제안 (Development of Oxygen Diffusion Test Method for Crack Width Evaluation of Self-Healing Concrete)

  • 이도근;신경준
    • 한국건설순환자원학회논문집
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    • 제9권3호
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    • pp.375-382
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    • 2021
  • 자기치유 콘크리트는 직접적인 보수보강 없이도 스스로 구조물의 균열을 치유하여 효율적으로 콘크리트 구조물의 수명연장이 가능하다는 측면에서 각광받고 있다. 현재 자기치유 콘크리트는 전 세계적으로 활발히 연구가 진행되고 있는 분야이지만 대부분의 연구는 치유 성능의 향상에 초점을 맞추고 있기 때문에 객관적으로 치유성능을 평가하는 방법은 부족한 실정이다. 자기치유 콘크리트의 성능평가에 활용하기 위해 기체확산실험 방법이 개발된 바가 있지만, 시편의 포화도 및 실험시의 온습도 등과 같은 환경조건의 통제가 필요하다는 단점이 있다. 따라서 본 연구에서는 기체 확산 실험시에 필요한 환경조건을 대폭 완화하여 적용성을 향상시키고자 하였다. 아울러 실험시간을 단축시키고자 사전 안정화 과정을 도입하였고, 약 20분이내의 실험시간에서 3%이내의 오차 수준으로 균열폭의 추정이 가능하였다.

A Modified Enskog-Like Equation of Self-Diffusion Coefficients for Penetrable-Sphere Model Fluids

  • Suh, Soong-Hyuck;Liu, Hong-Lai
    • Bulletin of the Korean Chemical Society
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    • 제32권4호
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    • pp.1336-1340
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    • 2011
  • Molecular dynamics simulations have been performed to investigate the transport properties of self-diffusion coefficients in the penetrable-sphere model system. The resulting simulation data for the product of the packing fraction and the self-diffusion coefficient exhibit a transition from an increasing function of density in lower repulsive systems, where the soft-type collisions are dominant, to a decreasing function in higher repulsive systems, where most particle collisions are the hard-type reflections due to the low-penetrability effects. A modified Enskog-like equation implemented by the effective packing fraction with the mean-field energy correction is also proposed, and this heuristic approximation yields a reasonably good result even in systems of high densities and high repulsive energy barriers.

THE LOCAL TIME OF THE LINEAR SELF-ATTRACTING DIFFUSION DRIVEN BY WEIGHTED FRACTIONAL BROWNIAN MOTION

  • Chen, Qin;Shen, Guangjun;Wang, Qingbo
    • 대한수학회보
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    • 제57권3호
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    • pp.547-568
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    • 2020
  • In this paper, we introduce the linear self-attracting diffusion driven by a weighted fractional Brownian motion with weighting exponent a > -1 and Hurst index |b| < a + 1, 0 < b < 1, which is analogous to the linear fractional self-attracting diffusion. For the 1-dimensional process we study its convergence and the corresponding weighted local time. As a related problem, we also obtain the renormalized intersection local time exists in L2 if max{a1 + b1, a2 + b2} < 0.