• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.85-85
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• 2013

Label-free, sensitive and selective detection methods with high spatial resolution are critically required for future applications in chemical sensor, biological sensor, and nanospectroscopic imaging. Here I describe the development of Plasmon Resonance Energy Transfer (PRET)-based molecular imaging in living cells as the first demonstration of intracellular imaging with PRET-based nanospectroscopy. In-vivo PRET imaging relied on the overlap between plasmon resonance frequency of gold nanoplasmonic probe (GNP) and absorption peak frequencies of conjugated molecules, which leads to create 'quantized quenching dips' in Rayleigh scattering spectrum of GNP. The position of these dips exactly matched with the absorption peaks of target molecules. As another innovative application of PRET, I present a highly selective and sensitive detection of metal ions by creating conjugated metal-ligand complexes on a single GNP. In addition to conferring high spatial resolution due to the small size of the metal ion probes (50 nm in diameter), this method is 100 to 1,000 folds more sensitive than organic reporter-based methods. Moreover, this technique achieves high selectivity due to the selective formation of Cu2+complexes and selective resonant quenching of GNP by the conjugated complexes. Since many metal ion ligand complexes generate new absorption peak due to the d-d transition in the metal ligand complex when a specific metal ion is inserted into the complex, we can match with the scattering frequency of nanoplasmonic metal ligand systems and the new absorption peak.

• Journal of electromagnetic engineering and science
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• v.9 no.1
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• pp.46-52
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• 2009

This paper conducts a study on the frequency-dependent filtering and blocking effects of a variety of periodic structures, dubbed frequency selective surface(FSS). The periodic structures of interest are 1D and 2D repeated patterns of metal patches or slots sitting on the interface between the two different regions in the layered media which will show the capacitive or inductive behaviors and incorporated with the electromagnetic bandgap(EBG) geometry as another stratified media. Besides the normal substances so called double positive(DPS)-type in the layered media, metamaterials of double negative(DNG) are considered as layering components on the purpose of investigating the unusual electromagnetic phenomena. Frequency responses of transmission(absorption in terms of scattering) and reflection will be calculated by a numerical analysis which can be validated by the comparison with the open literature and demonstrated for the periodic structures embedding metamaterials or not. Most importantly, numerous examples of FSS will present the useful guidelines to have absorption or reflection properties in the frequency domain.

• Journal of the Korean Solar Energy Society
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• v.31 no.4
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• pp.48-56
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• 2011

Black cobalt solar selective coatings were prepared by thermal oxidation of electroplated cobalt metal on copper and nickel substrates. The optical properties and structure of the black cobalt selective coating for solar energy utilizations were characterized by glow discharge spectrometry (GDS), ultraviolet-visible-near infrared (UV-VIS-NIR) spectrometer, atom force microscopy(AFM) and X-ray photoelectron spectroscopy(XPS). The optical properties of optimum black cobalt selective coating prepared on copper substrate were a solar absorptance of 0.82 and a thermal emittance of 0.01. From the GDS depth profile analysis of these coatings, the concentration of cobalt particles near the interface was higher than at the surface, but oxygen concentration at the surface was higher than at the interface. These results suggest that the selective absorption was dominated by this chemical composition variation in the coating. The surface of this film exhibited morphology with root-mean-square(rms) roughness of about 144.3nm. XPS measurements data showed that several phases of Co coexist($Co_3O_4$,CoO) in the film.

• Solar Energy
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• v.4 no.2
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• pp.29-36
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• 1984

This paper reviews the current status of R&D work on selective absorber materials. For the efficient utilization of solar energy, various types of selective absorber materials are being used for solar hot water heaters. Many selective absorbers which have been proposed and designed up to data are classified according to the absorption mechanisms. Temperature-time cycle method is often recommended for the measurement of solar absorptance. In addition, conversion efficiency of the solar collector with selective surface is compared with one with black paint surface.

• The Journal of Natural Sciences
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• v.12 no.1
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• pp.49-59
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• 2002

Exponential decrease of saturation absorption signal was reported in pump beam spacially keeping off from probe beam. Optimum angle between pump beam and probe beam in the differential-velocity-selective saturation absorption spectroscopy was computed theoretically, $1.33^{\circ}$ in cesium atoms and $1.08^{\circ}$ in Rb 87 atoms, and was good agreement with the experimental results.

• Journal of Nutrition and Health
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• v.11 no.3
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• pp.9-12
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• 1978

An effect of alginate and seaweeds on the intestinal absorption of cadmium was tested in vitro. The absorption of cadmium was remarkably suppressed by alginate though the effect was not selective toward cadmium or calcium. The suppressive effect was also observed with tangle and laver, differing in some aspects from alginate only.

• Bulletin of the Korean Chemical Society
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• v.31 no.12
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• pp.3539-3542
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• 2010

Selective mercuration at the 1,6-positions of 2-hydroxy derivative of Nile Red and its application towards $Hg^{2+}$-selective signaling was investigated. The 2-hydroxy Nile Red exhibited a selective UV-vis absorption and fluorescent signaling behavior towards $Hg^{2+}$ ions over common coexisting physiologically important metal ions in aqueous environment. $^1H$ NMR studies revealed that the mercuration was selectively effected at the 1,6-positions of 2-hydroxy Nile Red, which is quite different from that at the 6,8-positions for the parent Nile Red.

• Current Optics and Photonics
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• v.1 no.5
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• pp.514-524
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• 2017

We proposed an integrated wavelength-selective photodetector based on a grating-assisted contradirectional coupler and a graphene absorption layer for a coarse wavelength division multiplexing (CWDM) communication system. The center wavelength of the absorption spectrum of the proposed device can be tuned simply by changing the period of the grating, and the proposed device structure is suitable to forming a cascaded structure. Therefore, an array of the proposed device of different grating periods can be used for simultaneous wavelength demultiplexing and signal detection in a CWDM communication system. Our theoretical study showed that the designed device with a grating length of $500{\mu}m$ could have an absorption of 95.1%, an insertion loss of 0.2 dB, and a 3 dB bandwidth of 7.5 nm, resulting in a -14 dB crosstalk to adjacent CWDM channels. We believe that the proposed device array can provide a compact and economic solution to receiver implementation in the CWDM system by combining functions of wavelength demultiplexing and signal detection.

• Journal of the Optical Society of Korea
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• v.19 no.6
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• pp.665-672
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• 2015

We demonstrate an ultrathin metamaterial for polarization independent perfect absorption as well as a band-pass filter (BPF) which works at a higher frequency band compared to the perfect absorption band. The planar metamaterial is comprised of three layers, symmetric split ring resonators (SSRRs) at the front and structured ground plane (SGP) at the back separated by a dielectric layer. The perfect metamaterial absorber (MA) can realize near 100% absorption due to high electromagnetic losses from the electric and/or magnetic resonances within a certain frequency band. The thickness of the structure is only 1/28 of the maximum absorption wavelength.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1309-1313
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• 2010

The effects of boronic acid on the fluoride-selective chemosignaling behavior of a merocyanine dye were investigated. In the presence of phenylboronic acid (PBA), N-methylquinolinium-based merocyanine dye displayed fluoride-selective chromogenic signaling behavior over other commonly coexisting anions in the micromolar concentration range. Signaling is produced by a fluoride-induced displacement of the dye from its complex with PBA, resulting in a significant chromogenic signal for the fluoride ion. This signaling was successfully analyzed using a ratiometric analysis of the UV-vis absorption in response to changes in fluoride ion concentration. A PBA substituted with an electron withdrawing group was found to exhibit a more pronounced signal. Polymer-bound PBA also exhibited useful fluoride-selective signaling behavior.