Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Selective Mercuration of 2-Hydroxy Nile Red and Its Application towards Chemodosimetric Hg2+-selective Signaling

  • Received : 2010.09.14
  • Accepted : 2010.09.17
  • Published : 2010.12.20
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Abstract

Selective mercuration at the 1,6-positions of 2-hydroxy derivative of Nile Red and its application towards $Hg^{2+}$-selective signaling was investigated. The 2-hydroxy Nile Red exhibited a selective UV-vis absorption and fluorescent signaling behavior towards $Hg^{2+}$ ions over common coexisting physiologically important metal ions in aqueous environment. $^1H$ NMR studies revealed that the mercuration was selectively effected at the 1,6-positions of 2-hydroxy Nile Red, which is quite different from that at the 6,8-positions for the parent Nile Red.

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References

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