• Title/Summary/Keyword: Second order parameter

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Impact of Lambertian Cloud Top Pressure Error on Ozone Profile Retrieval Using OMI (램버시안 구름 모델의 운정기압 오차가 OMI 오존 프로파일 산출에 미치는 영향)

  • Nam, Hyeonshik;Kim, Jae Hawn;Shin, Daegeun;Baek, Kanghyun
    • Korean Journal of Remote Sensing
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    • v.35 no.3
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    • pp.347-358
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    • 2019
  • Lambertian cloud model (Lambertian Cloud Model) is the simplified cloud model which is used to effectively retrieve the vertical ozone distribution of the atmosphere where the clouds exist. By using the Lambertian cloud model, the optical characteristics of clouds required for radiative transfer simulation are parametrized by Optical Centroid Cloud Pressure (OCCP) and Effective Cloud Fraction (ECF), and the accuracy of each parameter greatly affects the radiation simulation accuracy. However, it is very difficult to generalize the vertical ozone error due to the OCCP error because it varies depending on the radiation environment and algorithm setting. In addition, it is also difficult to analyze the effect of OCCP error because it is mixed with other errors that occur in the vertical ozone calculation process. This study analyzed the ozone retrieval error due to OCCP error using two methods. First, we simulated the impact of OCCP error on ozone retrieval based on Optimal Estimation. Using LIDORT radiation model, the radiation error due to the OCCP error is calculated. In order to convert the radiation error to the ozone calculation error, the radiation error is assigned to the conversion equation of the optimal estimation method. The results show that when the OCCP error occurs by 100 hPa, the total ozone is overestimated by 2.7%. Second, a case analysis is carried out to find the ozone retrieval error due to OCCP error. For the case analysis, the ozone retrieval error is simulated assuming OCCP error and compared with the ozone error in the case of PROFOZ 2005-2006, an OMI ozone profile product. In order to define the ozone error in the case, we assumed an ideal assumption. Considering albedo, and the horizontal change of ozone for satisfying the assumption, the 49 cases are selected. As a result, 27 out of 49 cases(about 55%)showed a correlation of 0.5 or more. This result show that the error of OCCP has a significant influence on the accuracy of ozone profile calculation.

Statistical Optimization for Biodegradation of 2,4-Dichlorophenoxyacetic Acid by Soil Isolated Bacterium (토양 분리 박테리아에 의한 2,4-Dichlorophenoxyacetic산의 분해 최적화)

  • Kim, Byunghoon;Myunghee Han;Sungyong Cho;Sungjin Ahn;Lim, Sung-Paal;Sunkyun Yoo
    • Microbiology and Biotechnology Letters
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    • v.31 no.1
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    • pp.83-89
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    • 2003
  • 2,4-Dichlorophenoxyacetic acid (2,4-D) as a widely used herbicide has caused serious environmental problems because of its difficult decomposition in nature. We isolated the strain capable of metabolizing 2,4-D as sole carbon and energy source by an enrichment culture technique from the 2,4-D contaminated soil collected at orchard in Gwangju, Korea. This strain was identified tentatively as Aeromonas sp. NOH2. With this strain, we established the response surface methodology (Box-Behnken Design) to optimize the principle parameters for maximizing biodegradation of 2,4-D such as culture pH, temperature, and nutrient concentration in liquid batch culture. The ranges of parameters were obtained from preliminary works done at our laboratory and chosen as 5.5, 6.5, and 7.5 for pH, 25, 30, and $35^{\circ}C$ for temperature, and 5, 20, and 35 g/1 nutrient concentration. Initial concentration of 2,4-D was 500 ppm and nutrient source was tryptic soy broth. The experimental data were significantly fitted to a second order polynomial equation using multiple regression. The most important parameter influencing 2,4-D degradation and biomass production was nutrient concentration. For 2,4-D degradation, the optimum values of pH and temperature, and nutrient concentration were obtained at pH (6.5), temperature (31.8 to $32.1^{\circ}C$), and nutrient concentration (29.6 to 30.1.0 g/1).

A Point Rainfal1 Model and Rainfall Intensity-Duration-Frequency Analysis (점 강우모형과 강우강도-지속기간-생기빈도 해석)

  • Yu, Cheol-Sang;Kim, Nam-Won;Jeong, Gwang-Sik
    • Journal of Korea Water Resources Association
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    • v.34 no.6
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    • pp.577-586
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    • 2001
  • This study proposes a theoretical methodology for deriving a rainfall intensity-duration- frequency (I-D-F) curve using a simple rectangular pulses Poisson process model. As the I-D-F curve derived by considering the model structure is dependent on the rainfall model parameters estimated using the observed first and second order statistics, it becomes less sensitive to the unusual rainfall events than that derided using the annual maxima rainfall series. This study has been applied to the rainfall data at Seoul and Inchon stations to check its applicability by comparing the two I-D-F carves from the model and the data. The results obtained are as followed. (1) As the duration becomes longer, the overlap probability increases significantly. However, its contribution to the rainfall intensity decreases a little. (2) When considering the overlap of each rainfall event, especially for large duration and return period, we could see obvious increases of rainfall intensity. This result is normal as the rainfall intensity is calculated by considering both the overlap probability and return period. Also, the overlap effect for Seoul station is fecund much higher than that for Inchon station, which is mainly due to the different overlap probabilities calculated using different rainfall model parameter sets. (3) As the rectangular pulses Poisson processes model used in this study cannot consider the clustering characteristics of rainfall, the derived I-D-F curves show less rainfall intensities than those from the annual maxima series. However, overall pattern of both I-D-F curves are found very similar, and the difference is believed to be overcome by use of a rainfall model with the clustering consideration.

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Performance Evaluation and Offset Time Decision for Supporting Differential Multiple Services in Optical Burst Switched Networks (광 버스트 교환 망에서 차등적 다중 서비스 제공을 위한 offset 시간 결정 및 성능 평가)

  • So W.H.;im Y.C.K
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.41 no.1
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    • pp.1-12
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    • 2004
  • In this paper, we take advantage of the characteristics of optical burst switching (OBS) to support service-differentiation in optical networks. With the offset time between control packet and burst data, the proposed scheme uses different offset time of each service class. As contrasted with the Previous method, in which the high Priority service use only long offset time, it derives the burst loss rate as a QoS parameter in consideration of conservation law and given service-differential ratios and decides a reasonable offset time for this QoS finally Firstly proposed method classifies services into one of high or low class and is an algorithm deciding the offset time for supporting the required QoS of high class. In order to consider the multi-classes environment, we expand the analysis method of first algorithm and propose the second algorithm. It divides services into one of high or low group according to their burst loss rate and decides the offset time for high group, and lastly cumulates the offset time of each class. The proposed algorithms are evaluated through simulation. The result of simulation is compared with that of analysis to verify the proposed scheme.

A Study on the Financial Service Negotiations in the Korean-Chinese Free-Trade Agreement (FTA) with Respect to RMB Internationalization (위안화 국제화를 고려한 한·중 FTA 금융서비스 협상 전략에 관한 연구)

  • Kim, Sang-Su;Son, Sam-Ho
    • Journal of Distribution Science
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    • v.11 no.4
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    • pp.81-88
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    • 2013
  • Purpose - This paper analyzes the influence of the RMB internationalization on the KRW/dollar exchange rate using an autoregressive distributed lag model. Comparing the parameter estimators from the sample period before and after the global financial crisis, we found that the RMB/dollar exchange rate has increasingly become more influential on the KRW/dollar exchange rate. Moreover, for the past several years, the Chinese government has actively utilized the financial service FTA negotiation as a measure for the RMB internationalization. This paper simultaneously considers RMB internationalization and financial service negotiations in the Korean-Chinese FTA. The purpose of this paper is to explicitly suggest a direction for the financial service negotiations in the Korean-Chinese FTA considering the effects of RMB internationalization. Research design, data, and methodology - The research plan of this paper has two parts. First, for an empirical study, this paper uses the daily exchange rate of the U.S. dollar against the currencies of the ASEAN5, Taiwan,and Korea. By using an autoregressive distributed lag model, this paper studies the influence of the change in the RMB/dollar exchange rate on changes in the local currency/dollar exchange rate in seven economies neighboring China. Our sample periods are 06/2005 - 07/2008 and 06/2010 -02/2013. During these periods, China was under the multi-currency basket system. We exempted the period of 08/2008 - 05/2010 from the analysis because there was nearly no RMB/dollar exchange rate fluctuation during those months. Second, after analyzing the recent financial service liberalizations and deregulations in China, we recommend a direction for the financial service negotiations in the Korean-Chinese FTA. In the past several years,the main Chinese financial policy agenda has surrounded the RMB internationalization. Therefore, it is crucial to understand this in the search for strategies for the financial service negotiations in the Korean-Chinese FTA. This paper employs an existing literature survey and examines the FTA protocols in its research methodology. Results and Conclusions - After the global financial crisis, the Chinese government wanted to break away from the dollar influence and pursued independent RMB internationalization in order to continue the growth and stability of its economy. Hence, every neighboring economy of China has been strategically impacted by RMB internationalization. Nevertheless, there is little empirical study on the influence of RMB internationalization on the KRW/dollar exchange rate. This paper is one of the few studies to analyze this problem comprehensively. By using a relatively simple estimation model, we can confirm that the coefficient of the RMB/dollar exchange rate has become more significant, except in the case of Indonesia. Although Korea is not under the multi-currency basket system but under the weakly controlled floating exchange rate system, its coefficient appears as large as that of the ASEAN5. This is the basis of the currency cooperation that has grown from the expansion of trade between the two countries. These empirical results suggest that the Korean government should specifically consider the RMB internationalization in the Korean-Chinese FTA negotiations.

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Rheological Properties of Rehydrated Suspensions of Freeze Dried Kochujang Powders (동결건조 분말고추장의 재수화시 리올로지 특성)

  • Kim, Suk-Shin;Chang, Kyu-Seob;Yoon, Han-Kyo;Lee, Sang-Kyu;Lee, Shin-Young
    • Korean Journal of Food Science and Technology
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    • v.19 no.2
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    • pp.81-88
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    • 1987
  • Rheological properties of rehydrated suspensions of two kinds of freeze dried Kochujang powders, processed at different freezing rates, were compared with raw Kochujang using Brookfield wide-gap rotational viscometer at $25^{\circ}C-60^{\circ}C$. Shear rates ranged from $0.1965\;sec^{-1}$ to $1.9650\;sec^{-1}$ and solid content ranged from 47% to 56%. Rehydrated suspensions of quickly frozen Kochujang powder and slowly frozen Kochujang powder, and raw Kochujang exhibited pseudoplastic behaviors with yield stress and presented thixotropic properties which followed the second-order kinetic behavior proposed by Tiu. Suspensions of Kochujang powders exhibited considerably higher decaying rates than raw Kochujang. The dependency of the equilibrium structure parameter on the shear rate was weak, and there were no significant differences among the values of structure parameters of three samples. The temperature dependency of the apparent viscosity of Kochujang suspension was fully expressed by Arrhenius equation and activation energies of suspensions of quickly frozen Kochujang powder and slowly frozen Kochujang powder, and raw Kochujang were 2.21, 2.18, and 2.32 Kcal/g.mole respectively. Consistency indices of three samples increased with solid content and decreased with temperature. Flow behavior indices of three samples showed no considerable dependency on the temperature and solid content. There were no significant differences in the rheological properties between two Kochujang powders.

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Kinetic Study on the Color Deterioration of Crude Anthocyanin Extract from Schizandra Fruit (Schizandra chinensis fructus) (오미자 색소 추출물의 가열 변색에 대한 속도론적 연구)

  • Cho, Sung-Bin;Kim, Hyun-Jung;Yoon, Jong-Il;Chun, Hyang-Sook
    • Korean Journal of Food Science and Technology
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    • v.35 no.1
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    • pp.23-27
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    • 2003
  • The effects of temperature and pH on color deterioration of anthocyanin in Schizandra fruit (Schizandra chinensis fructus) were determined with temperature range of $80{\sim}100^{\circ}C$ and pH range of $2.0{\sim}5.0$. Browning index was used as an index of color deterioration of crude anthocyanin extract from Schizandra fruit. As pH of crude anthocyanin extract was increased, color deterioration was accelerated, showing pH-dependency of thermal stability of anthocyanin extract from Schizandra fruit. Anthocyanin degradation could be modeled as a second-order rate reaction, with rate of $3.2{\times}10^{-3}\;h^{-1}\;(pH\;2.0){\sim}4.1{\times}10^{-3}\;h^{-1}\;(pH\;5.0)\;at\;100^{\circ}C$. Temperature dependence of deterioration was described by the Arrhenius relationship. Activation energies for pH $2.0{\sim}5.0$ ranged from $24.87{\sim}42.54\;kJ/mol^{-1}$.

A Stochastic Numerical Analysis of Groundwater Fluctuations in Hillside Slopes for Assessing Risk of Landslides (산사태 위험도 추정을 위한 지하수위 변동의 추계론적 수치 해석)

  • 이인모
    • Geotechnical Engineering
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    • v.3 no.4
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    • pp.41-54
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    • 1987
  • A stochastic numerical analysis for predicting the groundswater fluctuations in hillside slopes is performed in this paper to account for the uncertainties associated with the rainfall and site characteristics. The effect of spatial variabilities of aquifer parameters and the effect of temporal variability of recharge on the groundwater fluctuations are studied in depth. The Kriging is used to account for the spatial tariabilities of aquifer parameters. This technique prolevides the best linear unbiased estimator of a parameter and its minimum variance from a litsitem number of measured data. A stochastic one-dimensional numerical model is delreloped b) combining the groundwater flow model, the Kriging, and the first-order second-moment analysis. In addition, a two dimensional detelministic groundwater model is developed to study the change of ground water surfas in the transverse direction as well as in the downslope direction. It is revealed that the undulations of the impervious bedrock in addition to the permeability and the specific yield have an important influence on the fluctuations of the groundwater surface. It is also found that th'e groundwater changes significantly in the transverse direction as well as in the downslope direction. The results obtained in this analysis may be used for evaluation of landslide risks due to high porewater pressure.

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Adsorption Characteristics of Coconut Shell-based Granular Activated Carbon on a Basic Dye Basic Blue 3 (염기성 염료 Basic Blue 3에 대한 야자계 입상활성탄의 흡착 특성)

  • Park, Ha Neul;Choi, Han Ah;Won, Sung Wook
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.96-102
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    • 2018
  • In this study, adsorption characteristics of coconut shell-based granular activated carbon (CS-GAC) on Basic Blue 3 (BB3) were evaluated. As the dosage of CS-GAC increased, the removal efficiency of BB3 tended to increase and the initial dye concentration of 50 mg/L was completely removed at 0.2 g dosage. Adsorption equilibrium achieved within 270 and 420 min at the initial concentrations of 25 and 50 mg/L, respectively, and the experimental data were represented by the pseudo-second-order model. The maximum uptakes ($q_{max}$) predicted by the Langmuir model were 34.45, 46.63 and 53.10 mg/g at 298, 308 and 318 K, respectively. The $q_{max}$ value increased as the temperature increased. Also, the Gibbs free energy (${\Delta}G$) was changed to -7.37, -8.19 and -10.40 kJ/mol with increasing temperature. The enthalpy change (${\Delta}H$) and the entropy change (${\Delta}S$) were 34.47 kJ/mol and 0.15 J/mol K, respectively. Therefore adsorption of BB3 by CS-GAC was spontaneous and endothermic.

Development of Scaled Explosion Logit Model Considering Reliability of Ranking Data (SP 순위 자료별 오차를 고려하는 순위로짓 모형 추정에 관한 연구)

  • Kim, Kang-Soo;Cho, Hye-Jin
    • Journal of Korean Society of Transportation
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    • v.22 no.6
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    • pp.197-206
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    • 2004
  • In ranking data, respondents are required to rank a number of alternatives in order of their preferences and an exploded logit model is generally used. It assumes that each rank contains the same amount of random noise. This study investigates the reliability of ranking data and identifies whether there are different decision rules at each rank stage. The results show that there were differences in the amount of unexplained variation in different ranking stage. A single scaling parameter could not explain the difference of variations of individual coefficients between two ranking data average difference of variations. This paper also investigated the optimal explosion depth in the exploded logit model by using the suggested scaling approach. The scaling approach should be based on particular variables which have different variances rather than based on the whole data set. The empirical analysis show that an explosion depth of 2 is appropriate after scaling the second rank data set, while an explosion including the third rank is inappropriate even though the third rank data set is scaled.