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http://dx.doi.org/10.9713/kcer.2018.56.1.96

Adsorption Characteristics of Coconut Shell-based Granular Activated Carbon on a Basic Dye Basic Blue 3  

Park, Ha Neul (Department of Ocean System Engineering, Gyeongsang National University)
Choi, Han Ah (Department of Marine Environmental Engineering and Institute of Marine Industry, Gyeongsang National University)
Won, Sung Wook (Department of Ocean System Engineering, Gyeongsang National University)
Publication Information
Korean Chemical Engineering Research / v.56, no.1, 2018 , pp. 96-102 More about this Journal
Abstract
In this study, adsorption characteristics of coconut shell-based granular activated carbon (CS-GAC) on Basic Blue 3 (BB3) were evaluated. As the dosage of CS-GAC increased, the removal efficiency of BB3 tended to increase and the initial dye concentration of 50 mg/L was completely removed at 0.2 g dosage. Adsorption equilibrium achieved within 270 and 420 min at the initial concentrations of 25 and 50 mg/L, respectively, and the experimental data were represented by the pseudo-second-order model. The maximum uptakes ($q_{max}$) predicted by the Langmuir model were 34.45, 46.63 and 53.10 mg/g at 298, 308 and 318 K, respectively. The $q_{max}$ value increased as the temperature increased. Also, the Gibbs free energy (${\Delta}G$) was changed to -7.37, -8.19 and -10.40 kJ/mol with increasing temperature. The enthalpy change (${\Delta}H$) and the entropy change (${\Delta}S$) were 34.47 kJ/mol and 0.15 J/mol K, respectively. Therefore adsorption of BB3 by CS-GAC was spontaneous and endothermic.
Keywords
Adsorption; Basic Blue 3; Activated carbon; Isotherm; Thermodynamic parameter;
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Times Cited By KSCI : 6  (Citation Analysis)
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