• Title/Summary/Keyword: Se(-II)

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MOVPE of ZnSe with DIPSe and DMZn

  • Soo, Huh-Jeung;Ok, Lim-Jeong
    • Journal of Korean Vacuum Science & Technology
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    • v.2 no.2
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    • pp.118-121
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    • 1998
  • Diisopropylselenide (DIPSe) is employed for the metalorganic vapor phase epitaxy (MOVPE) of ZnSe in order to eliminate premature gas phase reaction while maintaining negligible carbon incorporation and preserving relatively low growth temperature. In combination with dimethylzinc, single crystalline ZnSe layers were grown on GaAs at temperature around 450$^{\circ}C$. Secondary ion mass spectrometry showed a negligible carbon incorporation in ZnSe films grown from DIPSe even at high [Ⅵ]/[II] ratios, in contrast of a carbon concentration of 1021 cm-3 in ZnSe films grown from diallyselenide (DASe). Crystalline and interface quality are demonstrated by secondary electron microscopy, secondary ion mass spectroscopy and double crystal X-ray diffraction.

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Paleostress Reconstruction in the Tertiary Basin Areas in Southeastern Korea (한반도 동남부 제3기 분지지역에서의 고응력장 복원)

  • Moon, Tae-Hyun;Son, Moon;Chang, Tae-Woo;Kim, In-Soo
    • Journal of the Korean earth science society
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    • v.21 no.3
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    • pp.230-249
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    • 2000
  • Southeastern Korean Peninsula has undergone the polyphase deformations according to the changes of regional tectonic settings during the Cenozoic. Through analyses of more than 600 fault-slip data gathered in the study area, five tectonic events are revealed as the followings: (I) NW-SE transtension, (II) NW-SE transpression, (III) NE-SW pure or radial extension, (IV) NNE-SSW transpression, (V) NE or ENE-WSW transpression. Event I was induced by the pull-apart type extension of the East Sea during 24-16 Ma, which resulted in the NW-SE extension of the Tertiary Basins in SE Korea. Event II was resulted from the collision of SW Japan and Izu-Bonnin Arc (or Kuroshio Paleoland) on the Philippine Sea Plate at ${\sim}$ 15 Ma, which stopped the extension of the Tertiary Basins and originated the uplift of fault blocks in and around SE Korean Peninsula. It was continued until ${\sim}$ 10 Ma. Event III is interpreted as the post-tectonic event after the block-uplifts due to the event II, which indicates a temporal lull in activity of the Philippine Sea Plate since 10 Ma. Event IV was originated from the resumption in activity of the Philippine Sea Plate which was restarted to move toward north at ${\sim}$ 6 Ma. The event made the EW compressional structures behind SW Japan as well as in the Korea Straits, and thus the block-uplifts in SE Korea was resumed again. Lastly, event V was resulted from the gradual decrease in influence of the Philippine Sea Plate and the cooperative compression due to the subduction of the Pacific Sea Plate and the collision of the Indian Plate since 5-3.5 Ma, which generated the NS compressional structures in the offshore along the eastern coast of the Korean Peninsula and thrust up the fault-blocks toward west. This event is continuing so far, and thus is making the active faultings resulting in the present earthquakes of the Korean Peninsula.

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Comparison of the Stability Constants of Cd(II)-, Cu(II)-, and Pb(II)-Humate Complexes

  • Choi, Se-Young;Moon, Hi-Chung;Jun, Song-Hui;Chung, Kun-Ho
    • Bulletin of the Korean Chemical Society
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    • v.15 no.7
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    • pp.581-584
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    • 1994
  • A comparative investigation of the complexations of divalent metal ions (Cd, Cu, and Pb) by a well characterized soil humic acid (HA) from Okchun Metamorphic Belt was carried out in 0.05 M $KNO_3$ and pH of 4.5 using ion selective electrodes. A continuous distribution model based on the Scatchard Plot was used to determine the stability constants, because the constants obtained by this modeling technique takes the variations in binding energies into consideration without regards to the manner in which M(II) ion is bound on HA. The mean value of log $K_i$ were $4.05{\pm}0.60,\;4.92{\pm}0.36,\;and\;5.63{\pm}0.34\;{\ell}\;mol^{-1}$ for Cd(II)-, Pb(II), and Cu(II)-humate complexes respectively. The values of intrinsic constant (log $K_{int}$; binding at strongest site) were $7.12{\pm}0.30,\;6.59{\pm}0.32,\;and5.07{\pm}0.56\;{\ell}\; mol^{-1}$ in the order Cu(II) > Pb(II) > Cd(II) ion.

THE CURVATURE TENSORS IN THE EINSTEIN′S *g- UNIFIED FIELD THEORY I. THE SE-CURVATURE TENSOR OF *g-SE $X_{n}$

  • Chung, Kyung-Tae;Chung, Phil-Ung;Hwang, In-Ho
    • Journal of the Korean Mathematical Society
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    • v.35 no.4
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    • pp.1045-1060
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    • 1998
  • Recently, Chung and et al. ([11], 1991c) introduced a new concept of a manifold, denoted by *g-SE $X_{n}$ , in Einstein's n-dimensional *g-unified field theory. The manifold *g-SE $X_{n}$ is a generalized n-dimensional Riemannian manifold on which the differential geometric structure is imposed by the unified field tensor * $g^{λν}$ through the SE-connection which is both Einstein and semi-symmetric. In this paper, they proved a necessary and sufficient condition for the unique existence of SE-connection and presented a beautiful and surveyable tensorial representation of the SE-connection in terms of the tensor * $g^{λν}$. This paper is the first part of the following series of two papers: I. The SE-curvature tensor of *g-SE $X_{n}$ II. The contracted SE-curvature tensors of *g-SE $X_{n}$ In the present paper we investigate the properties of SE-curvature tensor of *g-SE $X_{n}$ , with main emphasis on the derivation of several useful generalized identities involving it. In our subsequent paper, we are concerned with contracted curvature tensors of *g-SE $X_{n}$ and several generalized identities involving them. In particular, we prove the first variation of the generalized Bianchi's identity in *g-SE $X_{n}$ , which has a great deal of useful physical applications.tions.

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THE CURVATURE TENSORS IN THE EINSTEIN'S $^*g$-UNIFIED FIELD THEORY II. THE CONTRACTED SE-CURVATURE TENSORS OF $^*g-SEX_n$

  • Chung, Kyung-Tae;Chung, Phil-Ung;Hwang, In-Ho
    • Bulletin of the Korean Mathematical Society
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    • v.35 no.4
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    • pp.641-652
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    • 1998
  • Chung and et al. ([2].1991) introduced a new concept of a manifold, denoted by $^{\ast}g-SEX_n$, in Einstein's n-dimensional $^{\ast}g$-unified field theory. The manifold $^{\ast}g-SEX_n$ is a generalized n-dimensional Riemannian manifold on which the differential geometric structure is imposed by the unified field tensor $^{\ast}g^{\lambda \nu}$ through the SE-connection which is both Einstein and semi-symmetric. In this paper, they proved a necessary and sufficient condition for the unique existence of SE-connection and sufficient condition for the unique existence of SE-connection and presented a beautiful and surveyable tensorial representation of the SE-connection in terms of the tensor $^{\ast}g^{\lambda \nu}$. Recently, Chung and et al.([3],1998) obtained a concise tensorial representation of SE-curvature tensor defined by the SE-connection of $^{\ast}g-SEX_n$ and proved deveral identities involving it. This paper is a direct continuations of [3]. In this paper we derive surveyable tensorial representations of constracted curvature tensors of $^{\ast}g-SEX_n$ and prove several generalized identities involving them. In particular, the first variation of the generalized Bianchi's identity in $^{\ast}g-SEX_n$, proved in theorem (2.10a), has a great deal of useful physical applications.

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A Preliminary Design of Flight Test Conditions for a Sub-scale RBCC Engine using a Sounding Rocket

  • Kim, Hye-Sung;Kim, Kui-Soon;Oh, Se-Jong;Choi, Jeong-Yeol;Yang, Won-Seok
    • International Journal of Aeronautical and Space Sciences
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    • v.16 no.4
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    • pp.529-536
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    • 2015
  • Various R&D programs for rocket-based combined cycle (RBCC) engines have progressed worldwide for the space development and the defense applications. As a way toward indigenous domestic RBCC program, a preliminary design of flight test conditions was studied in this study for a sub-scale RBCC engine using a sounding rocket. Launch and flight profiles were calculated for several booster options and compared with that of HyShot II program. The result shows that the Korea Sounding Rocket-II (KSR-II) is a proper candidate to perform the flight test available in Korea. The recommend flight test conditions with KSR-II are Mach 6.0 with a test vehicle of 230 kg and Mach 7.4 with 50 kg. Present study will soon be followed by a design of sub-scale RBCC for a flight test using a sounding rocket.

Formate Decarboxylation: Initial Step for Hydrogen Production by Enterobacter aerogenes (Enterobacter aerogenes에 의한 수소 생산 초기 단계인 포메이트 탈카복시 반응 연구)

  • Choi, Jinyoung;Jho, Young Choong;Ahn, Ik-Sung
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.449-452
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    • 2009
  • The absence of Fe, Se, and Mo in a minimal medium prevented the production of hydrogen from the anaerobic culture of Escherichia coli MC4100. Fe, Se, and Mo are known to be cofactors of formate dehydrogenase ($FDH_{II}$) of both E. coli and Enterobacter aerogenes. Hence when these trace elements are absent in the minimal medium, hydrogen production through formate dehydrogenation would be inhibited not only in E. coli but also in E. aerogenes. Hydrogen production by E. aerogenes 413 was delayed when lacking these trace elements. Therefore, it is believed that hydrogen production of E. aerogenes is initiated not by the reoxidation of nicotinamide adenine dinucleotide (NADH) but by formate decarboxylation.

Quantitative Structure-Activity Relationships of Salicylic Acid Derivatives by Quantum Chemical Calculations (양자화학적 계산에 의한 살리씰산유도체의 정량적 구조-활성 상관관계)

  • Rhee, Jong-Dal
    • YAKHAK HOEJI
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    • v.32 no.1
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    • pp.80-85
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    • 1988
  • QSAR of Salicylic acid derivatives, as anti-inflammatory agent, classified into Group I (not-having-5-phenyl ones) and Group II (having-5-phenyl ones) were investigated by quantum chemical calculations. The results are below: not significant statistically for both of Group I and Group II, but significant for each Group. $potency=-8.46X_{5}+1.639\;n=5\;r=0.77\;se=0.31\;for\;Group\;I.$ $({\pm}4.05)\;({\pm}0.5)$ where $X_5$ means charge of carbon atom bonded to hydroxyl radical. $potency=0.16X_{19}+7427.38HO-6629.85X_{15}+4977.40X_{10}+351.51X_5+3378.84$ $({\pm}0.17)\;({\pm}10.18)\;({\pm}11.70)\;({\pm}33.78)\;({\pm}4.41)\;({\pm}13.13)$ n=7 r=0.99 se=0.019 for Group II. where $X_{19}$ and $X_{15}$ stand for charges of the para carbon and the first carbon atoms in phenyl radical, respectively and $X_{10}$, charge of carboxylic carbon atom, HO, HOMO energy. It seems to be possible to qualitatively predict potency of drug by Pearson's HSAB theory. It means that drug should possess low LUMO energy and high HOMO energy.

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IGRINS NIR Spectroscopy of Diffuse Sources around MWC 1080

  • Kim, Il-Joong;Oh, Heeyoung;Jeong, Woong-Seob;Lee, Jae-Joon
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.48.1-48.1
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    • 2019
  • We found a diffuse Hα feature with a large size of ~2' around a Herbig star, MWC 1080. It shows a strong correlation with the elongated outflow cavity centered on the star. To investigate the diffuse Hα source and the molecular cavity in detail, we carried out the high-resolution NIR spectroscopy using IGRINS. We detected six hydrogen Brackett line series, seven H2 lines, and an [Fe II] forbidden line. With the obtained spatial, kinematic, and line ratio results, we discuss the characteristics of the central MWC 1080A, the NE outflow cavity, and the SE molecular cloud regions separately. Most of the bright Brγ sources around MWC 1080A were found to be reflection nebulae, but a point-like Brγ source close to another young star, MWC 1080E, was identified as a distinct source due to MWC 1080E itself. The narrow components of the H2 lines observed around MWC 1080A were found to trace PDRs located on the wall of the main outflow cavity. Based on the shock-excited H2 and [Fe II] lines detected just inside a bow-shock shape Hα feature, we suggest that it represents the actual shock at the head of the NE outflow from MWC 1080A. Also, we newly detected the shock-excited H2 and [Fe II] lines with highly blueshifted velocities in the SE molecular cloud region. They could be related to unrevealed outflows from other young stars existing around MWC 1080A.

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Cathodic Stripping Voltammetric Study of Tin(Ⅱ)-Cupferron Complex (Tin(Ⅱ)-Cupferron 착물에 대한 음극벗김전압전류법적 연구)

  • Sohn, Se Chul;Seo, Moo Yul;Jee, kwang Yong;Choi, In kyu
    • Journal of the Korean Chemical Society
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    • v.39 no.1
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    • pp.23-28
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    • 1995
  • Differential-pulse cathodic stripping voltammetry was applied to the Sn(II)-cupferron complex in 0.1 M acetate buffer solution (pH 4.20). Effects of solution pH, ligand concentration, accumulation potential, and accumulation time on the reduction peak current for the adsorptive complex of Sn(II)-cupferron were investigated. Interferences by other metal cations that affected on reduction peak current were also discussed. The detection limit was 3.1${\times}$10-9 M (0.37 ppb) of Sn(II) with 60 seconds accumulation time. The relative standard deviation (n=8) for 5${\times}$10-8 M Sn(II) was 3.0%.

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