• Title/Summary/Keyword: SWCNT

Search Result 116, Processing Time 0.032 seconds

Electrical Properties of Transparent Conductive Films of Single-Walled Carbon Nanotubes with Their Purities

  • Lee, Seung-Ho;Goak, Jeung-Choon;Lee, Chung-Yeol;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2010.06a
    • /
    • pp.56-56
    • /
    • 2010
  • Single-walled carbon nanotubes (SWCNTs) have attracted much attention as a promising material for transparent conducting films (TCFs), due to their superior electrical conductivity, high mechanical strength, and complete flexibility as well as their one-dimensional morphological features of extremely high length-to-diameter ratios. This study investigated three kinds of SWCNTs with different purities: as-produced SWCNTs (AP-SWCNTs), thermally purified SWCNTs (TH-SWCNTs), thermally and acid purified SWCNTs (TA-SWCNTs). The purity of each SWCNT sample was assessed by considering absorption peaks in the semiconducting ($S_{22}$) and metallic ($M_{11}$) tubes with UV-Vis NIR spectroscopy and a metal content with thermogravimetric analysis (TGA). The purity increased as proceeding the purification stages from the AP-SWCNTs through the thermal purification to the acid purification. The samples containing different contents of SWCNTs were dispersed in water using sodium dodecyl benzensulfate (SDBS). Aqueous suspensions of different purities of SWCNTs were prepared to have similar absorbances in UV-Vis absorption measurements so that one can make the TCFs possess similar optical transmittances irrespective of the SWCNT purity. Transparent conductive SWCNT networks were formed by spraying an SWCNT suspension onto a poly(ethyleneterephthalate) (PET) substrate. As expected, the TCFs fabricated with AP-SWCNTs showed very high sheet resistances. Interestingly, the TH-SWCNTs gave lower sheet resistances to the TFCs than the TA-SWCNTs although the latter was of higher purity in the SWCNT content than the former. The TA-SWCNTs would be shortened in length and be more bundled by the acid purification, relative to the TH-SWCNTs. For both purified (TH, TA) samples, the subsequent nitric acid ($HNO_3$) treatment greatly lowered the sheet resistances of the TCFs, but almost eliminated the difference of sheet resistances between them. This seems to be because the electrical conductivity increased not only due to further removal of surfactants but also due to p-type doping upon the acid treatment. The doping effect was likely to overwhelm the effect of surfactant removal. Although the nitric acid treatment resulted in the similar. electrical properties to the two samples, the TCFs of TH-SWCNTs showed much lower sheet resistances than those of the TA-SWCNTs prior to the acid treatment.

  • PDF

Dynamic bending response of SWCNT reinforced composite plates subjected to hygro-thermo-mechanical loading

  • Chavan, Shivaji G.;Lal, Achchhe
    • Computers and Concrete
    • /
    • v.20 no.2
    • /
    • pp.229-246
    • /
    • 2017
  • The dynamic bending response of single walled carbon nanotube reinforced composite (SWCNTRC) plates subjected to hygro-thermo-mechanical loading are investigated in this paper. The mechanical load is considered as wind pressure for dynamic bending responses of SWCNTRC plate. The dynamic version of the High Order shear deformation Theory (HSDT) for a composite plate with Matrix and SWCNTRC plate is first formulated. Distribution of fibers through the thickness of the SWCNTRC plate could be uniform or functionally graded (FG). The dynamic displacement response is predicted by using Nemarck integration method. The effective material properties of SWCNTRC are estimated by using micromechanics based modeling approach. The effect of different environmental condition, volume fraction of SWCNT, Width-to-thickness ratio, wind pressure, different SWCNTRC-FG plates, boundary condition, E1/E2 ratio, different temperature on dynamic displacement response is investigated. The dynamic displacement response is compared with the available literature and it shows good agreement.

Quantitative Evaluation of Non-Carbon Content in the Single Wall Carbon Nanotube Soot using Thermogravimetric Analysis

  • Han, J.H.;An, K.H.;Lee, N.S.;Goak, J.C.;Jeong, M.S.;Choi, Y.C.;Oh, K.H.;Kim, K.K.;Lee, Y.H.
    • Carbon letters
    • /
    • v.10 no.1
    • /
    • pp.5-8
    • /
    • 2009
  • We measured the non-carbon content of single-walled carbon nanotubes (SWCNTs) in SWCNT soot using thermogravimetric analysis. The weight increased percentage by the oxidation of metal in the raw soot is well obtained by TGA graph which was confirmed with ICP-AES, XRD, and XPS. This work will be very useful for the purity precise evaluation of SWCNT with UN-vis-NIR spectroscopy.

Observation of SWCNT Stretching in homogeneously aligned nematic liquid Crystal medium (수평 배향된 양의 액정 내에서의 단일벽 탄소 나노튜브 Stretching 관찰)

  • Yang, Gyu-Hyung;Kang, Byeong-Gyun;Lee, Seung-Hee;Lee, Kyu;Lee, Young-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2010.06a
    • /
    • pp.170-170
    • /
    • 2010
  • In this paper, we observed stretching of single-wall carbon nanotubes (SWCNTs) aggregates driven by the in-plane field in a homogeneously aligned nematic liquid crystal (LC) medium. Aggregates of SWCNTs started to stretch above the 0.5 V/${\mu}m$ and stretched up to $1.83\;{\mu}m$ from original size with $0.74\;{\mu}m$ at 3.5 V/${\mu}m$.

  • PDF

Photocurrent of CdSe nanocrystals on singlewalled carbon nanotube-field effect transistor

  • Jeong, Seung-Yol;Lim, Seung-Chu;Lee, Young-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2010.03b
    • /
    • pp.40-40
    • /
    • 2010
  • CdSe nanocrystals (NCs) have been decorated on singlewalled carbon nanotubes (SWCNTs) by combining a method of chemically modified substrate along with gate-bias control. CdSe/ZnS core/shell quantum dots were negatively charged by adding mercaptoacetic acid (MAA). The silicon oxide substrate was decorated by octadecyltrichlorosilane (OTS) and converted to hydrophobic surface. The negatively charged CdSe NCs were adsorbed on the SWCNT surface by applying the negative gate bias. The selective adsorption of CdSe quantum dots on SWCNTs was confirmed by confocal laser scanning microscope. The measured photocurrent clearly demonstrates that CdSe NCs decorated SWCNT can be used for photodetector and solar cell that are operable over a wide range of wavelengths.

  • PDF

Bending behavior of SWCNT reinforced composite plates

  • Chavan, Shivaji G.;Lal, Achchhe
    • Steel and Composite Structures
    • /
    • v.24 no.5
    • /
    • pp.537-548
    • /
    • 2017
  • In this paper presents bending characteristic of single wall carbon nanotube reinforced functionally graded composite (SWCNTRC-FG) plates. The finite element implementation of bending analysis of laminated composite plate via well-established higher order shear deformation theory (HSDT). A seven degree of freedom and $C^0$ continuity finite element model using eight noded isoperimetric elements is developed for precise computation of deflection and stresses of SWCNTRC plate subjected to sinusoidal transverse load. The finite element implementation is carried out through a finite element code developed in MATLAB. The results obtained by present approach are compared with the results available in the literatures. The effective material properties of the laminated SWCNTRC plate are used by Mori-Tanaka method. Numerical results have been obtained with different parameters, width-to-thickness ratio (a/h), stress distribution profile along thickness direction, different SWCNTRC-FG plate, boundary condition, through the thickness (z/h) ratio, volume fraction of SWCNT.

Stochastic bending characteristics of finite element modeled Nano-composite plates

  • Chavan, Shivaji G.;Lal, Achchhe
    • Steel and Composite Structures
    • /
    • v.26 no.1
    • /
    • pp.1-15
    • /
    • 2018
  • This study reported, the effect of random variation in system properties on bending response of single wall carbon nanotube reinforced composite (SWCNTRC) plates subjected to transverse uniform loading is examined. System parameters such as the SWCNT armchair, material properties, plate thickness and volume fraction of SWCNT are modelled as basic random variables. The basic formulation is based on higher order shear deformation theory to model the system behaviour of the SWCNTRC composite plate. A C0 finite element method in conjunction with the first order perturbation technique procedure developed earlier by the authors for the plate subjected to lateral loading is employed to obtain the mean and variance of the transverse deflection of the plate. The performance of the stochastic SWCNTRC composite model is demonstrated through a comparison of mean transverse central deflection with those results available in the literature and standard deviation of the deflection with an independent First Order perturbation Technique (FOPT), Second Order perturbation Technique (SOPT) and Monte Carlo simulation.

Gate-modulated SWCNT/SnO2 nanowire hetero-junction arrays on flexible polyimide substrate

  • Park, Jae-Hyeon;Bae, Min-Yeong;Ha, Jeong-Suk
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.08a
    • /
    • pp.273-273
    • /
    • 2010
  • Recently, extensive research on hetero-junction arrays has been reported owing to its unique band gaps dissimilar to that of homo-junctions. These hetero-junction devices can be used in laser, solar cells, and various sensors. We report on the facile method to fabricate SWCNTs/SnO2 nanowires hetero-junction arrays on flexible polyimide substrate. Each SWCNT field effect transistor (FET) and SnO2 nanowire FET exhibits the purely p- and n-type charactersistics with ohmic contact properties. Such formed pn-junctions showed rectification behaviors reproducibly with a rectification ratio of ${\sim}3{\times}103$ at 1 V and ideality factors about 12. The pn-junctions also showed a good gate modulation behavior.

  • PDF

Fabrication of a Resonator using suspended Multi-wall Carbon Nanotubes (다중벽 탄소나노튜브를 이용한 공진기 제작)

  • Lee J.H.;Seo H.W.;Song J.W.;Han C.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 2006.05a
    • /
    • pp.465-466
    • /
    • 2006
  • A single-wall carbon nanotube (SWCNT) has been studied as a material of Nano-Eletro-Mechanical-System (NEMS) device together with various nanowires. In order for oscillation of a multi-wall carbon nanotube (MWCNT) or a single-walled carbon nanotube (SWCNT) on plane surface, it needs suspension of a CNT across trench electrodes. So we propose fabrication method of a MWCNT resonator using dielectrophoresis and show successful results of suspeneded MWNT. Thin electrodes with large gaps could not suspend small diameter MWNT but thicker electrodes could. Thin MWNT could be suspended only when the electrode gap was reduced.

  • PDF

Characterization of SWCNT Field Effect Transistor via Edison Simulation

  • Piao, Mingxing;Lee, Sang-Jin;Na, In-Yeob
    • Proceeding of EDISON Challenge
    • /
    • 2013.04a
    • /
    • pp.260-263
    • /
    • 2013
  • A semiconducting single-walled carbon nanotube (SWCNT) field-effect transistor (FET) in a top-gate model was constructed. The effect of different high-${\kappa}$ dielectric materials ($Al_2O_3$, $HfO_2$ and HfSiON) and various temperatures with a wide range from 50K to 500K on the performance of such nominal device were investigated. Several key device parameters including the on/off ratio of the current, transconductance ($g_m$), subthreshold swing, and carrier mobility were used to evaluate the device performance. The simulated results fit well with the experiment results previously published.

  • PDF