• Title/Summary/Keyword: SI units

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Electrolyzed Water Cleaning for Semiconductor Manufacturing (전리수를 이용한 반도체 세정 공정)

  • 류근걸;김우혁;이윤배;이종권
    • Journal of the Semiconductor & Display Technology
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    • v.2 no.3
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    • pp.1-6
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    • 2003
  • In the rapid changes of the semiconductor manufacturing technologies for early 21st century, it may be safely said that a kernel of terms is the size increase of Si wafer and the size decrease of semiconductor devices. As the size of Si wafers increases and semiconductor device is miniaturized, the units of cleaning processes increase. A present cleaning technology is based upon RCA cleaning which consumes vast chemicals and ultra pure water (UPW) and is the high temperature process. Therefore, this technology gives rise to environmental issue. To resolve this matter, candidates of advanced cleaning processes have been studied. One of them is to apply the electrolyzed water. In this work, electrolyzed water cleaning was compared with various chemical cleaning, using Si wafer surfaces by changing cleaning temperature and cleaning time, and especially, concentrating upon the contact angle. It was observed that contact angle on surface treated with Electrolyzed water cleaning was $4.4^{\circ}$ without RCA cleaning. Amine series additive of high pKa (negative logarithm of the acidity constant) was used to observe the property changes of cathode water.

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A Preliminary Study on Stratigraphy and Petrochemistry of the Okcheon Group, Southwestern Okcheon Metamorphic Belt (서남 옥천변성대 옥천층군의 층서 및 암석화학에 대한 예비연구)

  • 유인창;김성원;오창환;이덕수
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.511-525
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    • 2003
  • The Okcheon Group in the southwestern part of the Okcheon Metamorphic Belt is subdivided into two distinct tectonostratigraphic units: the Boeun unit in the south and the Pibanryeong unit in the north. The Boeun unit consists of petites, psammites, carbonaceous petites, limestones and pebble-bearing quartzites. The Pibanryeong unit is composed of petites, well-sorted fine-grained psammites, carbonaceous psammites and quartzites. In order to outlining stratigraphy and depositional environments of the Okcheon Group, detailed stratigraphic sections were measured in three locations; one section(Gosan section) of the Boeun unit and two sections(Sorungjae and Hwangryeongzae sections) of the Pibanryeong unit. The Gosan section of the Boeun unit is interpreted to be deposited in the shallow marine environments, whereas the Sorungjae and Hwangryeonaiae sections of the Pibanryeong unit appear to be deposited in slope and deep basin environments. This result indicates rapid subsidence between deposition of the Boeun and Pibanryeong units in sedimentary environment. The trace of sedimentological environments in the Hwasan area was investigated by geochemical analysis of 109 metapelitic and psammitic rock samples. Distinct chemical variations of politic and psammitic rocks from the Boeun and Pibanryeong units in the study area are evident from plots of major elements and $A1_2O_3$/$SiO_2$ versus Basicity Index($Fe_2O_3{+}MgO$)/($SiO_2{+}K_2O{+}Na_2O$). The rocks show a progressive chemical trend from the Boeun unit to the Pibanryeong unit on these diagrams. They in the southern sector of the Boeun unit display lower values and a comparatively wide range of $A1_2O_3$/$SiO_2$ and Basicity Index, as compared with those from the northern sector of the Boeun and Pibanryeong units. The southern sector of the Pibanryeong unit including narrow staurolite-bearing zone is characterized by values that are transitional between the Boeun and Pibanryeong units. These data, combined with depositional environment progressively deepened towards the northwest, support a half-graben model for the Okcheon basin, as proposed by Cluzel et al.(1990)

Quality of Image and Exposure Dose According to kVp, mA and Iterative Reconstruction in Computed Tomography (전산화단층촬영에서 관전압과 관전류, 통계적 반복재구성법에 따른 화질과 피폭선량)

  • Cha, Sang-Young;Park, Jae-Yoon;Lee, Yong-Ki;Kim, Jeon-Hun;Choi, Jae-Ho
    • Journal of radiological science and technology
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    • v.40 no.3
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    • pp.385-392
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    • 2017
  • The purpose of this study is to investigate the image quality and exposure dose according to kVp and mAs in CT and to confirm improvement in image quality according to None IR and IR(Iterative Reconstruction) levels. Measurement results of image quality using Image J, HU(Hounsfield units) and BN(Background Noise) are decreased, while SNR(Signal to Noise Ratio) and $CTDI_{vol}$(CT dose index volume) are increased as the kVp increases and there was no change of BHU(Background Hounsfield units). BN was reduced due to increased kVp, while SNR and $CTDI_{vol}$ were increased. Also, the higher IR stage, the lower BN, SI(Signal Intensity) and HU while SNR was improved by about 10~60%. Based on this, when applying IR for clinical applications, it is necessary to finely adjust kVp and mA with a phased approach.

Synthesis and Properties of Arylacetylene Resins with Siloxane Units

  • Gao, Fei;Zhang, Lingling;Tang, Lemin;Zhang, Jian;Zhou, Yan;Huang, Farong;Du, Lei
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.976-980
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    • 2010
  • A series of arylacetylene resins with siloxane units were synthesized by the condensation reactions of m-diethynylbenzene magnesium reagents with various $\alpha,\omega$-bis(chloro)dimethylsiloxanes. These resins are liquids and are miscible with common organic solvents at room temperature. The structures of the resins were characterized by FT-IR, $^1H$ NMR, $^{13}C$ NMR, $^{29}Si$ NMR, and gel permeation chromatography (GPC). The thermal behaviors of the resins were examined with differential scanning calorimetry (DSC). These resins have good processability. They can be thermally cross-linked through the ethynyl groups to produce cured resins. The thermal and thermooxidative stabilities of the cured resins were studied by thermogravimetric analysis (TGA). The cured resins possess high thermal and thermooxidative stability. Their decomposition occurs at above $500^{\circ}C$ in both $N_2$ and air. With increasing the length of siloxane units in the resins, the thermal stability of the cured resins decreases in $N_2$. When the cured resins were sintered above $1450^{\circ}C$ under argon, hard and glassy SiOC ceramics were obtained. These SiOC ceramics have the decomposition temperatures at 5% weight loss above $800^{\circ}C$ in air.

Bench-scale Test of Sulfuric Acid Decomposition Process in SI Thermochemical Cycle at Ambient Pressure (SI 열화학싸이클 황산분해공정의 Bench-scale 상압 실험)

  • Jeon, Dong-Keun;Lee, Ki-Yong;Kim, Hong-Gon;Kim, Chang-Soo
    • Journal of Hydrogen and New Energy
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    • v.22 no.2
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    • pp.139-151
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    • 2011
  • The sulfur-iodine (SI) thermochemical water splitting cycle is one of promising hydrogen production methods from water using high-temperature heat generated from a high temperature gas-cooled nuclear reactor (HTGR). The SI cycle consists of three main units, such as Bunsen reaction, HI decomposition, and $H_2SO_4$ decomposition. The feasibility of continuous operation of a series of subunits for $H_2SO_4$ decomposition was investigated with a bench-scale facility working at ambient pressure. It showed stable and reproducible $H_2SO_4$ decomposition by steadily producing $SO_2$ and $O_2$ corresponding to a capacity of 1 mol/h $H_2$ for 24 hrs.

Zeolitization of the Dacitic Tuff in the Miocene Janggi Basin, SE Korea (장기분지 데사이트질 응회암의 불석화작용)

  • Kim, Jinju;Jeong, Jong Ok;Shinn, Young-Jae;Sohn, Young Kwan
    • Economic and Environmental Geology
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    • v.55 no.1
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    • pp.63-76
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    • 2022
  • Dacitic tuffs, 97 to 118 m thick, were recovered from the lower part of the subsurface Seongdongri Formation, Janggi Basin, which was drilled to assess the potential for underground storage of carbon dioxide. The tuffs are divided into four depositional units(Unit 1 to 4) based on internal structures and particle componentry. Unit 1 and Units 3/4 are ignimbrites that accumulated in subaerial and subaqueous settings, respectively, whereas Unit 2 is braided-stream deposits that accumulated during a volcanic quiescence, and no dacitic tuff is observed. A series of analysis shows that mordenite and clinoptilolite mainly fill the vesicles of glass shards, suggesting their formation by replacement and dissolution of volcanic glass and precipitation from interstitial water during burial and diagenesis. Glass-replaced clinoptilolite has higher Si/Al ratios and Na contents than the vesicle-filling clinoptilolite in Units 3. However, the composition of clinoptilolite becomes identical in Unit 4, irrespective of the occurrence and location. This suggests that the Si/Al ratio and pH in the interstitial water increased with time because of the replacement and leaching of volcanic glass, and that the composition of interstitial water was different between the eastern and western parts of the basin during the formation of the clinoptilolite in Units 1 and 3. It is also inferred that the formation of the two zeolite minerals was sequential according to the depositional units, i.e., the clinoptilolite formed after the growth of mordenite. To summarize, during a volcanic quiescence after the deposition of Unit 1, pH was higher in the western part of the basin because of eastward tilting of the basin floor, and the zeolite ceased to grow because of the closure of the pore space as a result of the growth of smectite. On the other hand, clinoptilolite could grow in the eastern part of the basin in an open system affected by groundwater, where braided stream was developed. Afterwards, Units 3 and 4 were submerged under water because of the basin subsidence, and the alkali content of the interstitial water increased gradually, eventually becoming identical in the eastern and western parts of the basin. This study thus shows that volcanic deposits of similar composition can have variable distribution of zeolite mineral depending on the drainage and depositional environment of basins.

Purity assessment using quantitative NMR: establishment of SI traceability in organic analysis

  • Choi, Kihwan
    • Journal of the Korean Magnetic Resonance Society
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    • v.24 no.1
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    • pp.30-37
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    • 2020
  • Quantitative nuclear magnetic resonance (qNMR) has been gaining attention as a purity assessment method. In particular, qNMR is recognized as the primary method to realize the Internal System of Units (SI) in organic analysis. The capability of quantitative analysis is recognized as the beginning of NMR development. NMR signals are proportional to the number of nuclei and qNMR has been used in various fields, such as metabolomics and food and pharmaceutical analysis. However, careful sample preparation and thorough optimization of measurement parameters are required to obtain accurate and reliable results. In this review, quantitative methods used in qNMR are discussed, and the important factors to be considered also introduced. The recent development of qNMR techniques including combination with chromatography and, multidimensional NMR are also presented.

A Study on the Spatial Units Adequacy for the Regional Pricing of Electricity: Based on Electricity Self-sufficiency Rates by Si·Gun·Gu (지역별 차등 전기요금제 적용을 위한 공간 단위 검토: 시·군·구별 전력 자급률을 기준으로)

  • Chung Sup Lee;Kang-Won Lee
    • Journal of the Economic Geographical Society of Korea
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    • v.26 no.2
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    • pp.96-109
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    • 2023
  • Recently, there has been a lot of discussion about the regional pricing of electricity and electricity self-sufficiency. In Korea, power generation facilities are highly ubiquitous and there is an imbalance between electricity production and consumption regions. So it is proposed to charge different price by region, instead of the current nationwide uniform price, and the regional electricity self-sufficiency rate is proposed as a criterion for identifying electricity production and consumption regions. However, many discussions set the spatial unit for measuring electricity self-sufficiency by 17 Si·Do, which needs to be analyzed for its appropriateness. In this study, we analyzed the electricity self-sufficiency rate using 17 provinces and 229 Si·Gun·Gu as the spatial unit. As a result of the analysis, there are 7 and 10 electricity producing and consuming regions at Si·Do level, but 38 and 191 at Si·Gun·Gu level. In addition, although the electricity self-sufficiency rate measurement has the advantage of identifying electricity production and consumption areas in a simple and intuitive way, we points out that it has some problems with the criteria for regional pricing of electricity.

Development of Land Suitability Classification System for Rational Agricultural Land Use Planning (농지이용계획의 합리적 책정을 위한 농지적성 평가기법의 개발)

  • 황한철;최수명
    • Journal of Korean Society of Rural Planning
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    • v.3 no.2
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    • pp.102-111
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    • 1997
  • For rational agricultural land use planning, it is quite necessary to get hold of land suitability precisely and to make decision on land use patterns accordingly. In the methodological viewpoint, objective and scientific evaluation techniques for land suitability classification should be supported for the systematic land use planning. As one of technical development approaches to rational land use planning, this study tried to frame a land suitability evaluation system for agricultural purposes. Evaluation unit is defined as a tract of land bounded by road, other land units and topographical features. And quantification theory was applied in the determination works of evaluation criteria. The administrative area of Namsa-myon(district), Yongin-si(city), Kyunggi-do(province) was selected for the case study. In order to check the feasibility of the evaluation system developed in the study, field check team, consisting of 2 government officers and 2 representative farmers, carried out evaluation works by observation on 148 sample land units, 10% of total 1,480 ones. Between estimated and observed results, there showed very good relationship of its multiple correlation coefficient, R=0.9467.

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Urokinase Conjugated with Water-Soluble Dextran

  • Kim Nam Deuk;Kim Hyun-Pyo;Byun Si Myung;Kim Sung Wan
    • Bulletin of the Korean Chemical Society
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    • v.6 no.4
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    • pp.210-214
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    • 1985
  • Urokinase, a plasminogen activator, was conjugated with dextran by the cyanogen bromide activation-coupling method. The resulting water-soluble conjugate was purified by gel permeation chromatography on Sephadex G-200. The maximal activity was obtained when the ratio of urokinase/dextran was 1/20 for the coupling. The final preparation showed 5 CTA units/mg conjugate, 300 CTA units/mg protein, 8.4 % activity retention, and 47 % protein retention. The urokinase-dextran conjugate had good thermal, pH and storage stabilities. In addition, it showed greater resistance to the inhibitory effect of human plasma than native urokinase. Also in vitro biological half-life of urokinase increased 40 times by this conjugation. In view of activity, excellent stability and increased half-life, the conjugate can be a potential fibrinolytic agent in an injectable form.