• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.05b
• /
• pp.42-46
• /
• 2000

${\beta}{\cdot}In_2S_3$ 및 ${\beta}{\cdot}In_2S_3:Co^{2+}$ 은 $In_2S_3$+S+ZnS를 출발물질로 하여 ($ZnCl_2+I_2$)를 수송매체로 사용한 chemical transport reaction method로 성장시켰다. 성장된 단결정은 tetragonal structure를 갖고 298K에서 indirect optical energy gap은 2.240eV, 1.814eV로 각각 주어졌고, direct optical energy gap은 2.639eV, 2.175eV로 각각 주어졌다. ${\beta}{\cdot}In_2S_3:Co^{2+}$ single crystal에서 impurity optical absorption peak가 나타났으며, 이들 peaks의 origin은 $Co^{2+}(Td)$ ion의 energy level 간의 electron transition임을 crystal field theory를 적용하여 규명하였다.

• Journal of the Korean Chemical Society
• /
• v.31 no.2
• /
• pp.162-167
• /
• 1987

Four component $Ag_2S$-PbS-$PbHAsO_4-Cu_2S$ and three component $Ag_2S$-PbS-$PbHAsO_4$ electrodes have been prepared and evaluated for the direct measurement of monohydrogen arsenate. The 3.0 : 0.5 : 1.0 : 0.25 (mole ratio, $Ag_2S$:PbS:$PbHAsO_4:Cu_2S$) composition is superior in terms of potentiometric response, stability, rapidity of response and reproducibility. Testing was done over the concentration range $10^{-1}$~$10^{-4}M\;HA_SO_4^{2-}$in 0.1F NH4Ac-NH4OH buffer solution at pH 8.50 with constant ionic strength. Interfering ions were $CN^-,\;I^-,\;S^{-2}$ and $Cl^-$.

• Journal of the Korean Chemical Society
• /
• v.33 no.5
• /
• pp.516-521
• /
• 1989

Reaction between the $N_2O_2-type$ tetradentate ligand, ethylenediamine-N,N'-di-S-${\alpha}$-isobutylacetic acid (SS-emiba) and $RhCl_3{\cdot}3H_2O$ has yielded ${\Delta}-s-cis-\;and\;{\wedge}-uns-cis-[Rh(SS-eniba)Cl_2]-$. ${\Delta}-s-cis-[Rh(SS-eniba)Cl_2]^-$ has been utilized to react with S-methyl-L-cystcine(Smc) to give ${\Delta}-s-cis-[Rh(SS-eniba(Smc)]^+$. The oxidation of ${\Delta}-s-cis-[Rh(SS-eniba(Smc)]^+$ using $H_2O_2$ has produced ${\Delta}-s-cis-[Rh(SS-eniba)(Smc-o)]^+$, in which the coordinated sulfur has been converted into the sulfoxide group. In a separate series of experiments the S-methyl-L-cysteine is oxidized by $H_2O_2$ to give S-methyl-L-cysteine sulfoxide, which is then coordinated to ${\Delta}-s-cis-[Rh(SS-eniba)Cl2]^-$ to make the standard complet of ${\Delta}-s-cis-[Rh(SS-eniba)(Sme-o)]+$ for comparison with the complex obtained from the oxidation of ${\Delta}-s-cis-[Rh(SS-eniba)(Smc)]^+\;by\;H_2O_2.$

• Bulletin of the Korean Mathematical Society
• /
• v.30 no.1
• /
• pp.65-70
• /
• 1993

In this paper we will extend some notions of bounded linear operators to some unbounded linear operators. Let H be a complex separable Hilbert space and let B(H) denote the algebra of bounded linear operators. A closed densely defind linear operator S in H, with domain domS, is called subnormal if there is a Hilbert space K containing H and a normal operator N in K(i.e., $N^{*}$N=N $N^*/)such that domS .subeq. domN and Sf=Nf for f .mem. domS. we will show that the Radjavi and Rosenthal theorem holds for some unbounded subnormal operators; if $S_{1}$ and $S_{2}$ are unbounded subnormal operators on H with dom $S_{1}$= dom $S^{*}$$_{1}$ and dom $S_{2}$=dom $S^{*}$$_{2}$ and A .mem. B(H) is injective, has dense range and $S_{1}$A .coneq. A $S^{*}$$_{2}$, then $S_{1}$ and $S_{2}$ are normal and $S_{1}$.iden. $S^{*}$$_{2}$.2}$.X>.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.11a
• /
• pp.156-156
• /
• 2008

Single crystal of $In_2S_3$ and $In_2S_3:Co^{2+}$ were grown successfully with a good quality by the CTR(Chemical Transport Reaction)method. XRD analysis showed that the grown In2S3 and $In_2S_3:Co^{2+}$ single crystals were cubic structure. The optical absorption spectra of $In_2S_3:Co^{2+}$ single crystal showed impurity absorption peaks due to cobalt impurity. These impurity absorption pesks were assigned to the ligand transition between the split energy levels of $Co^{2+}$ ions with $T_d$ symmetry of these semiconductor host lattice.

• The Pure and Applied Mathematics
• /
• v.25 no.1
• /
• pp.31-38
• /
• 2018

In [4], the authors show that if ${\mathbb{X}}$ is a ${\mathbb{k}}-configuration$ in ${\mathbb{P}}^2$ of type ($d_1$, ${\ldots}$, $d_s$) with $d_s$ > $s{\geq}2$, then ${\Delta}H_{m{\mathbb{X}}}(md_s-1)$ is the number of lines containing exactly $d_s-points$ of ${\mathbb{X}}$ for $m{\geq}2$. They also show that if ${\mathbb{X}}$ is a ${\mathbb{k}}-configuration$ in ${\mathbb{P}}^2$ of type (1, 2, ${\ldots}$, s) with $s{\geq}2$, then ${\Delta}H_{m{\mathbb{X}}}(m{\mathbb{X}}-1)$ is the number of lines containing exactly s-points in ${\mathbb{X}}$ for $m{\geq}s+1$. In this paper, we explore a standard ${\mathbb{k}}-configuration$ in ${\mathbb{P}}^2$ and find that if ${\mathbb{X}}$ is a standard ${\mathbb{k}}-configuration$ in ${\mathbb{P}}^2$ of type (1, 2, ${\ldots}$, s) with $s{\geq}2$, then ${\Delta}H_{m{\mathbb{X}}}(m{\mathbb{X}}-1)=3$, which is the number of lines containing exactly s-points in ${\mathbb{X}}$ for $m{\geq}2$ instead of $m{\geq}s+1$.

• Current Photovoltaic Research
• /
• v.1 no.1
• /
• pp.52-58
• /
• 2013

Two different window-structured $CuInGaSe_2$(CIGS) solar cells, i.e., CIGS/thin-CdS/ZnO:B(sample A) and CIGS/very thin-CdS/Zn(S/O)/ZnO:B(sample B), were prepared, and the diffusivity of Zn, Cd, S, and B atoms, respectively, in the CIGS, ZnO or Zn(S/O) layer was estimated by a theoretical fit to experimental secondary ion mass spectrometer data. Diffusivities of Zn, Cd, S, and B atoms in CIGS were $2.0{\times}10^{-13}(1.5{\times}10^{-13})$, $4.6{\times}10^{-13}(4.4{\times}10^{-13})$, $1.6{\times}10^{-13}(1.8{\times}10^{-13})$, and $1.2{\times}10^{-12}cm^2/s$ at 423K, respectively, where the values in parentheses were obtained from sample B and the others from sample A. The diffusivity of the B atom in a Zn(S/O) of sample B was $2.1{\times}10^{-14}cm^2/sec$. Moreover, the diffusivities of Cd and S atoms diffusing back into ZnO(sample A) or Zn(S/O)(sample A) layers were extremely low at 423K, and the estimated diffusion coefficients were $2.2{\times}10^{-15}cm^2/s$ for Cd and $3.0{\times}10^{-15}cm^2/s$ for S.

• Transactions of the Korean hydrogen and new energy society
• /
• v.29 no.2
• /
• pp.170-180
• /
• 2018

After $MoS_2$ catalyst was prepared at 1, 30, and 70 atm, the hydrothermal pressure effect over preparation of $MoS_2$ was investigated in terms of catalyst characterization and direct methanation. Multifaceted characterization techniques such as XRD, BET, SEM, TPR, EDS, and XPS were used to analyze and investigate the effect of high pressure over the preparation of surface and bulk $MoS_2$ catalyst. Result from XRD, SEM, and BET demonstrated that $MoS_2$ was more dispersed as preparation pressure was increased, which resulted finer $MoS_2$ crystal size and higher surface area. EDS result confirmed that bulk composition was $MoS_2$ and XPS result showed that S/Mo mole ratio of surface was about 1.3. TPR showed that $MoS_2$ prepared at 30 atm possessed higher active surface sites than $MoS_2$ prepared at 1 atm and these sites could contribute to higher CO yield during methanation. Direct methanation was used to evaluate the CO conversion of the both catalysts prepared at 1 atm and 30 atm and reaction condition was at feed mole ratio of $H_2/CO=1$, GHSV=4800, 30 atm, temperature($^{\circ}C$) of 300, 350, 400, and 450. $MoS_2$ prepared at 30 atm showed more stable and higher CO conversion than $MoS_2$ prepared at 1 atm. Faster deactivation was occurred over $MoS_2$ prepared at 1 atm, which indicated that preparation pressure of $MoS_2$ catalyst was the dominant factor to improve the yield of direct methanation.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.30 no.3
• /
• pp.23-28
• /
• 2022

In order to investigate the degree of sewage sludge dewaterability using Fe(II)/Na₂S₂O₈, STTF, SCST, water content, TS, VS, TB-EPS as carbohydrate and Protein were measured. The dosage of Na₂S₂O₈ was varied from 0.4 to 0.7 mmol/gVS and molar ratio of Fe(II)/Na₂S₂O₈ was varied from 0.5 to 0.7 mol/mol. According to the increase of the dosage of Na₂S₂O₈ and Fe(II)/Na₂S₂O₈ molar ratio, STTF and SCST increased from 1.00 to 15.00 and 4.51, respectively. Water content decreased to 82.6%. TB-EPS as carbohydrate and protein decreasing rate also increased to 37.16% and 57.34%, respectively. Especially, Na₂S₂O₈ 0.6 mmol/gVS and Fe(II)/Na₂S₂O₈ 0.6 mol/mol condition, water content dercreased to 83.1%, STTF and SCST increased to 13.64 and 4.19 which showed the cost effective improvement of dewaterability. It is considered that SO₄^- radical generated by Fe(II)/Na₂S₂O₈ degraded EPS and converted bound water to free water.

• Fire Science and Engineering
• /
• v.32 no.5
• /
• pp.6-14
• /
• 2018

This study was carried out with respect to the heat release rate (HRR) properties of building wood. Heat release characteristics were measured using a cone calorimeter (ISO 5660-1) with four kinds of wood. The time to ignition measured after the combustion in $25kW/m^2$ external heat flux was 35 to 55 s. Time to ignition of both lauan and red pine was marked with the most delayed value in each of 54 s, 55 s. The maximum heat release rate ($HRR_{peak}$) was $156.87{\sim}235.1kW/m^2$, and the risk of early fire was highest in spruce. Total heat release of red pine was obtained in the highest value with $114.2MJ/m^2$. The mean effective heat of combustion of Japanese cedar was 19.1 MJ/kg and the highest among the samples. Fire risk of wood by FPI was orderly increased from lauan ($0.2468s{\cdot}m^2/kW$), red pine ($0.2339s{\cdot}m^2/kW$), spruce ($0.2308s{\cdot}m^2/kW$) to Japanese cedar ($0.2231s{\cdot}m^2/kW$). Fire risk of wood by FGI get increased from lauan ($0.5088kW/m^2{\cdot}s$), red pine ($0.5111kW/m^2{\cdot}s$), Japanese cedar ($2.8522kW/m^2{\cdot}s$) to spruce ($3.0662kW/m^2{\cdot}s$). Therefore, the risk of fire on the heat release characteristics of woods were found that spruce and Japanese cedar showed the high value compared with the other specimens.