• 한국세라믹학회지
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• 제39권12호
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• pp.1119-1123
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• 2002

Nanostructured spinel NiZn ferrites were prepared by the sol-gel method from metal nitrate raw materials. Analyses by X-ray diffraction and scanning electron microscopy showed the average particle size of NiZn ferrite was under 50 nm. The single phase of NiZn ferrites was obtained by firing at 250${\circ}C$, resulting in nanoparticles exhibiting normal ferrimagnetic behavior. The nanostructured $Ni_{1-X}Zn_XFe_2O_4$ (x=0.0∼1.0) were found to have the cubic spinel structure of which the lattice constants ${\alpha}_2$ increases linearly from 8.339 to 8.427 ${\AA}$ with increasing Zn content x, following Vegard's law, approximately. The saturation magnetization $M_s$ was 48 emu/g for x=0.4 and decreased to 8.0 emu/g for higher Zn contents suggesting the typical ferrimagnetism in mixed spinel ferrites. Pure NiZn ferrite phase substituted by Cu was observed before using the additive but hematite phase was partially appeared at $Ni_{0.2}Zn_{0.2}Cu_{0.6}Fe_2O_4$. On the other hand, the hematite phase in this NiZn Cu ferrite was disappeared after using the additive of acethyl aceton with small amount. The saturation magnetization Ms of $Ni_{0.2}Zn_{0.8-y}Cu_yFe_2O_4$(y=0.2∼0.6) as measured was about 51 emu/g at 77K and 19 emu/g at room temperature, respectively.

• Journal of the Korean Physical Society
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• 제73권9호
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• pp.1334-1339
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• 2018

Spherical nickel ferrite nanoparticles were synthesized using the thermal decomposition method and coated with cetyl trimethyl ammonium bromide (CTAB) after the synthesis. Transmission electron microscopy images showed that the average diameter of the particles was 9.40 nm. The status of the CTAB-coating on the surface of the particles was checked using Fourier-transform infrared spectroscopy. Their hysteresis curve showed that the particles exhibited a superparamagnetic behavior. The $T_1$ and the $T_2$ relaxations of the nuclear spins were observed in aqueous solutions of the particles with different particles concentrations by using a magnetic resonance imaging (MRI) scanner, which showed that the $T_1$ and the $T_2$ relaxivities of the particles in water were $0.57mM^{-1}{\cdot}s^{-1}$ and $10.42mM^{-1}{\cdot}s^{-1}$, respectively. In addition, using an induction heating system, we evaluated their potentials for magnetic hyperthermia applications. The aqueous solution of the particles with a moderate concentration (smaller than 6.5 mg/mL) showed a saturation temperature larger than the hyperthermia target temperature of $42^{\circ}C$. These findings show that the CTAB-coated nickel ferrite particles are suitable for applications as $T_2$ contrast agents in MRI and heat generators in magnetic hyperthermia.

• Archives of Metallurgy and Materials
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• 제65권4호
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• pp.1287-1291
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• 2020

The U-type ferrite is a kind of hexagonal ferrite, and it is known as a microwave absorber in the X-band. The magnetic and dielectric loss of the U-type ferrite change to the composition and coating layer, etc. In this study, the silicon oxide layer was coated on the substituted U-type ferrites to improve microwave absorption characteristics. The complex permittivity and complex permeability were measured using toroidal specimens that were press-molded and the measured frequency range was set from 2-18 GHz. The improvement of the microwave absorption rate was different according to the type of the substituted U-type ferrites. Only in the substituted U-type ferrites with nickel and zinc, an improvement in the microwave absorption rate due to enhancement of magnetic loss was confirmed. The highest microwave absorption was 99.9% at 9.6 GHz, which was S_Z_0.5U.

• Journal of Magnetics
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• 제20권4호
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• pp.460-465
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• 2015

The paper presents methodologies and results concerning one- and two-dimensional numerical modeling of radio frequency oscillations in a coaxial transmission line fed with a short pulse of electric current. The line is partially filled with a ferrite material, magnetized longitudinally close to saturation. The 2D model has permitted analyzing, for the first time in the art, the spatial structure and dynamics of the wave field within the radially non-uniform cross-section planes of the non-linear and dispersive guiding structure. This opens ways for optimizing size parameters of the line and the extent to which it is filled with the ferromagnetic material, thus increasing the line's electric strength and intensity of the r.f. oscillations.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 1998년도 추계종합학술대회 논문집
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• pp.613-616
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• 1998

In this paper, a model of a Eddy-current probe coil with a ferrite core in the presence of a half-space with a layer is developed. The half-space with a layer is accounted for by computing the appropriate Green's function by using Bessel transforms. Upon introducing equivalent Amperian currents within a core to explain effect to a impedance change in the coil due to a (ferrite) core, we derive a volume integral equation, The integral equation is transformed via the method of moments into a vector-matrix equation, which is then solved using a linear equation solver. Through the above processing, we computed impedance value in a Eddy-current probe coil due to a conductivity change of layer.

• 한국재료학회지
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• 제1권4호
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• pp.221-228
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• 1991

본 연구는 computerdisk drive와 VTR head에 사용되어 지고 있는 ferrite head cores의 gap 형성에 적합한 유리의 봉착특성에 관하여 고찰하였다. 유리의 특성측정은 열팽창 계수, 미세경도, 내마모성을 측정하였으며 계면에서의 원소 농도분포는 WDS에 의해 관찰하였고 젖음성은 고온 현미경으로 측정하였다. 그 결과는 다음과 같다. 1. $PbO-B_2O_3$계 봉착용 유리에 있어서 PbO의 함량이 증가함에 따라 열팽창계수와 마모량이 증가하였으며 $B_2O_3$함량이 증가함에 따라서는 열팽창계수와 마모량이 감소하였다. 2. $PbO-B_2O_3$계 유리에 있어서 contact angle은 PbO함량에 주로 영향을 받는다. 3. 열팽창계수의 증가에 따라 봉착온도는 비례적으로 낮아지는 경향을 나타내었다. 4. Mn-Zn single crystal ferrite와 $PbO-B_2O_3$계 봉착용유리의 융착 계면에서의 확산은 ferrite성분이 glass측으로 소량확산이 이루어졌으며 봉착 열처리 시간에 따라서는 거의 영향을 받지 않았다.

• The Korean Journal of Ceramics
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• 제6권3호
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• pp.315-317
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• 2000

A magnetoplumbite type of Ba ferrite(BaM) layers were deposited on Pt(111) and Pt(200) layers, and their c-axis orientation and magnetic characteristics were compared each other. The as-deposited BaM layer on Pt(111) one at the substrate temperature $T_s$ above $500^{\circ}C$ revealed remarkable c-axis orientation. The saturation magnetization 4$\piM_s$ and the perpendicular coercivity $H_{c⊥}$ of the films as-deposited at $T_s$ of $600^{\circ}C$ were 4.0kG and 2.5kOe, respectively. On the other hand, BaM ferrite layer deposited on Pt(200) layer at $T_s$ as relatively low as $500^{\circ}C$ also revealed weak c-axis orientation as well as (107) one and the films as-deposited at $T_s$ of $600^{\circ}C$ exhibited 4$\piMs_{and}$ $H_{c⊥}$ of 2.8kG and 2.5kOe, respectively. It was suggested that although chemical activity of Pt surface was effective for the formation of BaM crystallites, the lattice matching was also important for obtaining BaM layer with good c-axis orientation and large perpendicular anisotropy.sotropy.

• 한국세라믹학회지
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• 제38권12호
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• pp.1162-1166
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• 2001

석유화학 공정 중 Styrene(SM) 공정에서 발생되는 산화철 폐촉매는 산업 폐기물로서 전량 매립되고 있는데, 이를 출발 원료로 사용하여 NiZn-페라이트를 합성하였고 그 자기적 특성을 조사하였다. 산화철 폐축매 펠렛을 분쇄한 후 NiO 및 ZnO를 혼합하여 90$0^{\circ}C$에서 하소하고 123$0^{\circ}C$에서 5시간 소결하여 스핀넬형 페라이트 소결체를 얻었다. N $i_{x}$ Z $n_{1-x}$F $e_2$ $O_4$(x=0.36, 0.50, 0.66)조성에 대하여 초투자율을 측정하였고, S-parameter를 측정하여 반사 감쇄량을 계산하였다. 산화철 폐촉매를 이용하여 X-band 주파수 영역에서 높은 전자파 흡수능을 갖는 전파흡수체를 제조할 수 있음을 확인하였다.다.

• Journal of Magnetics
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• 제18권1호
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• pp.43-49
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• 2013

A pulsed ferrite magnetic field generator (FMFG) was designed for the use in the 1000 m long through-the-earth (TTE) communication system for mining disaster situations. To miniaturize the TTE system, a ferrite core having 10,000 of permeability was used for the FMFG. Attenuation of the magnetic field intensity from the FMFG (200-turn and 0.18 m diameter) was calculated to be 89.95 dB at 1000 m depth soil having 0.1 S/m of conductivity. This attenuation was lower than 151.13 dB attenuation of 1 kHz electromagnetic wave at the same conditions. Therefore, the magnetic-field was found to be desirable as a signal carrier source for TTE communications as compared to the electromagnetic wave. The designed FMFG generates the magnetic field intensity of $1{\times}10^{-10}$ Tesla at 1000 m depth. This magnetic field is detectable by compact magnetic sensors such as flux gate or magnetic tunneling junction sensor. Therefore, the miniature FMFG TTE communication system can replace the conventional electromagnetic wave carrier type TTE system and allow reliable signal transmission between rescuer and trapped miners.

• Journal of Welding and Joining
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• 제16권3호
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• pp.111-120
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• 1998

To predict and evaluate metallurgical and mechanical behavior of th welds, it is essential to understand solidification behavior and microstructural evolution experienced in the welds, neither of which follows the equilibrium phase diagram because of rapid heating and cooling conditions. Metallurgical phenomena in austenitic stainless steel fusion welds, types 304, 309S, 316L, 321 and 304N, were investigated in this study. Autogenous GTA welding was performed on weld coupons, and primary solidification mode and phase distribution were investigated from the welds. Varestraint test was employed to evaluate solidification cracking susceptibilities of the alloys. GTA weld fusion zones in type 304, 321 and 304N stainless steels experienced primary ferrite solidification while those in type 309S primary austenite solidification. Type 316L exhibited a mixed type of primary ferrite and primary austenite solidification. The primary solidification mode strongly depended on $Cr_{eq}/Ni_{eq}$ ratio. In terms of solidification cracking susceptibility, type 309S that solidified as primary austenite exhibited high cracking susceptibility while the alloys experienced primary ferrite solidification showed low cracking susceptibility. The relative ranking in solidification cracking susceptibility was type 304=type 304N < type 321 < type 316L < type 309S.