• Title/Summary/Keyword: Reduction technology

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Protective Effect of Methanol Extract of Swietenia macrophylla Seeds on Oxidative States Associated with Streptozotocin Induced Diabetic Rats

  • Maiti, Anup;Dewanjee, Saikat;Kundu, Mintu;Mandal, Subhash C.
    • Natural Product Sciences
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    • v.13 no.4
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    • pp.295-299
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    • 2007
  • The methanol extract of seeds of Swietenia macrophylla King. (MESM) was studied for its antidiabetic activity in streptozotocin induced diabetic rats. It was principally aimed to correlate the efficacious role of MESM on reduction of oxidative state associated with diabetes. The extract was found to be potent antidiabetic evidenced by significant reduction of blood glucose level in diabetic rats (47.96% reduction of blood glucose level, at 300 mg/kg, on day 10). It was found that, MESM at 300 mg/kg, significantly decreased TBARS (35.03 and 22.22%) whilst increased GSH (86.75 and 31.45%), SOD (93.05 and 45.88%) and CAT (56.99 and 68.46%) levels in liver and kidney respectively in diabetic rats.

Synthesis of Co/PANi/CNT for PEMFC Non-precious Metal Catalyst (비백금 연료전지 촉매로서의 Co/PANi/CNT 합성 및 특성)

  • Lee, Hyo June;Ahn, Ji Eun;Kim, Hun-Jong;Han, M.K.;Kim, Hansung;Lee, H.W.
    • Applied Chemistry
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    • v.15 no.1
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    • pp.81-84
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    • 2011
  • Platinum catalyst activity and stability is excellent in terms of fuel cells as a catalyst here. Although it is widely used, to compensate for the high price issue non-precious fuel cell catalysts are being developed. In this study, Co/PANi/CNT composite and non-precious as a catalyst for oxygen reduction was applied. Polyaniline on the interaction between cobalt and the oxygen reduction reaction and the structural characteristics observed in the impact and heat treatment was carried out according to the improved catalytic performance. Potential range is oxygen reduction reaction 0.55 V to 0.78 V(vs. NHE) after pyrolysis. Through this study, Co /PANi/CNT composites as a potential catalyst for fuel cells were non-precious.

Carbon-Supported Ordered Pt-Ti Alloy Nanoparticles as Durable Oxygen Reduction Reaction Electrocatalyst for Polymer Electrolyte Membrane Fuel Cells

  • Park, Hee-Young;Jeon, Tae-Yeol;Lee, Kug-Seung;Yoo, Sung Jong;Sung, Young-Eun;Jang, Jong Hyun
    • Journal of Electrochemical Science and Technology
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    • v.7 no.4
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    • pp.269-276
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    • 2016
  • Carbon-supported ordered Pt-Ti alloy nanoparticles were prepared as a durable and efficient oxygen reduction reaction (ORR) electrocatalyst for polymer electrolyte membrane fuel cells (PEMFCs) via wet chemical reduction of Pt and Ti precursors with heat treatment at $800^{\circ}C$. X-ray diffraction analysis confirmed that the prepared electrocatalysts with Ti precursor molar compositions of 40% (PtTi40) and 25% (PtTi25) had ordered $Pt_3Ti$ and $Pt_8Ti$ structures, respectively. Comparison of the ORR polarization before and after 1500 electrochemical cycles between 0.6 and 1.1 V showed little change in the ORR polarization curve of the electrocatalysts, demonstrating the high stability of the PtTi40 and PtTi25 alloys. Under the same conditions, commercial carbon-supported Pt nanoparticle electrocatalysts exhibited a negative potential shift (10 mV) in the ORR polarization curve after electrochemical cycling, indicating degradation of the ORR activity.

Vibration reduction design of the Hangzhou Bay cable-stayed bridges

  • Liu, Weiqing;Xu, Xiuli;Wang, Rengui;Wang, Zijun;Wu, Xiaolan
    • Structural Engineering and Mechanics
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    • v.24 no.3
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    • pp.339-354
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    • 2006
  • Hangzhou Bay Bridge spans the Hangzhou Bay and is located at Zhejiang province in the southeast seacoast of China. The total length of the bridge is 36 km. The bridge is composed of bridge approaches made up of multi-span prestressed concrete box girders and two cable-stayed bridges over the north and south navigable spans respectively. The seismic response analysis of the bridge model shows that if the navigable spans are designed as the routine earthquake-resistance system, the displacements and internal forces in pylons, piers and deckes are too large to satisfy the anti-seismic requirement of the structure. Therefore, the seismic reduction design was carried out by using viscous dampers to dissipate the kinetic energy of the structure both longitudinally and transversely. Using the vibration reduction system and aiming at the reasonable optimal goal, the purpose to reduce the seismic responses in south and north navigable spans has been achieved.

Effects on bycatch reduction in a shaking cod end generated by canvas in a shrimp beam trawl

  • Kim, Yonghae;Whang, Dae-Sung
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.50 no.3
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    • pp.342-350
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    • 2014
  • An active stimulating device, such as a fluttering net or canvas attached to the end of a cod end generating a shaking motion, could help to encourage the escape of juvenile fish positioned passively near the net. Field fishing trials using a shrimp beam trawl were carried out to examine the effect on the reduction of juvenile fish or other discard catch by generating a shaking movement of the cod end using an unbiased cap-like round canvas. The mean period of the shaking motion with the round canvas was ~14 s, and the mean amplitude was 0.4 m as measured by peak event analysis and the global wavelet method. The bycatch of juvenile fish in 14 trials decreased by ~30% and by ~25% using a steady cod end for the total bycatch using a shaking cod end in the shrimp beam trawl, while the marketing catch was similar between steady and shaking cod ends. There was no difference in the body size of the shrimp or fish and species composition between the steady and shaking cod ends. Above results demonstrate a new method for bycatch reduction using an active stimulating device, although more detailed studies are needed.

Synthesis and Oxygen Reduction Reaction Evaluation of 20% Pt/C for Polymer Electrolyte Fuel Cell (고분자전해질 연료전지용 20% Pt/C 캐소드 촉매 제조 및 산소환원반응 평가)

  • Kim, Jinhwan;Kang, Suk-Min;Thube, Dilip. R.;Ryu, Hojin
    • Korean Journal of Metals and Materials
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    • v.47 no.7
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    • pp.454-459
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    • 2009
  • In order to commercialize Polymer Electrolyte Fuel Cell (PEFC), the cathode catalyst such as Platinum supported Carbon (Pt/C) need to have a high activity of Oxygen Reduction Reaction (ORR). In this study, the 20% Pt/C was synthesized using the chemical reduction method while the crystallinity of Platinum (Pt) particles were controlled under heat treatment conditions. The activity of synthesized Pt catalysts was evaluated using electrochemical measurement. Compared with the $i_{ORR}$ at 0.8 V of 20% Pt/C heat-treated at $500^{\circ}C$ and the 20% Pt/C that were not heated and commercial 20% Pt/C, the $i_{ORR}$ at 0.8 V of 20% Pt/C heattreated at $500^{\circ}C$ was 9.5 and 1.7 times higher than those of the 20% Pt/C and commercial 20% Pt/C that were not heated. It was considered that the crystallinity and particle size affect the ORR activity of the Pt/C catalysts.

Dissolution behavior of SrO into molten LiCl for heat reduction in used nuclear fuel

  • Kang, Dokyu;Amphlett, James T.M.;Choi, Eun-Young;Bae, Sang-Eun;Choi, Sungyeol
    • Nuclear Engineering and Technology
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    • v.53 no.5
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    • pp.1534-1539
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    • 2021
  • This study reports on the dissolution behavior of SrO in LiCl at varying SrO concentrations from low concentrations to excess. The amount of SrO dissolved in the molten salt and the species present upon cooling were determined. The thermal behavior of LiCl containing various concentrations of SrO was investigated. The experimental results were compared with results from the simulated results using the HSC Chemistry software package. Although the reaction of SrO with LiCl in the standard state at 650 ℃ has a slightly positive Gibbs free energy, SrO was found to be highly soluble in LiCl. Experimentally determined SrO concentrations were found to be considerably higher than those present in used nuclear fuel (<2 g/kg). As Sr-90 is one of the most important heat-generating nuclides in used nuclear fuel, this finding will be impactful in the development of fast, simple, and proliferation-resistant heat reduction processes for used nuclear fuel without the need for separating nuclear materials. Heat reduction is important as it decreases both the volume necessary for final disposal and the worker handling risk.

Self-centering passive base isolation system incorporating shape memory alloy wires for reduction in base drift

  • Sania Dawood;Muhammad Usman;Mati Ullah Shah;Muhammad Rizwan
    • Smart Structures and Systems
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    • v.31 no.5
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    • pp.531-543
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    • 2023
  • Base isolation is one of the most widely implemented and well-known technique to reduce structural vibration and damages during an earthquake. However, while the base-isolated structure reduces storey drift significantly, it also increases the base drifts causing many practical problems. This study proposes the use of Shape Memory Alloys (SMA) wires for the reduction in base drift while controlling the overall structure vibrations. A multi-degree-of-freedom (MDOF) structure along with base isolators and Shape-Memory-Alloys (SMA) wires in diagonal is tested experimentally and analytically. The isolation bearing considered in this study consists of laminates of steel and silicon rubber. The performance of the proposed structure is evaluated and studied under different loadings including harmonic loading and seismic excitation. To assess the seismic performance of the proposed structure, shake table tests are conducted on base-isolated MDOF frame structure incorporating SMA wires, which is subjected to incremental harmonic and historic seismic loadings. Root mean square acceleration, displacement and drift are analyzed and discussed in detail for each story. To better understand the structure response, the percentage reduction of displacement is also determined for each story. The result shows that the reduction in the response of the proposed structure is much better than conventional base-isolated structure.

Electrocatalytic Reduction of CO2 by Copper (II) Cyclam Derivatives

  • Kang, Sung-Jin;Dale, Ajit;Sarkar, Swarbhanu;Yoo, Jeongsoo;Lee, Hochun
    • Journal of Electrochemical Science and Technology
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    • v.6 no.3
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    • pp.106-110
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    • 2015
  • This study investigates Cu(II) complexes of cyclam, propylene cross-bridged cyclam (PCB-cyclam), and propylene cross-bridged cyclam diacetate (PCB-TE2A) as homogeneous electrocatalysts for CO2 reduction in comparison with Ni(II)-cyclam. It is found that Cu(II)-cyclam can catalyze CO2 reduction at the potential close to its thermodynamic value (0.75 V vs. Ag/AgCl) in tris-HCl buffer (pH 8.45) on a glassy carbon electrode. Cu(II)-cyclam, however, suffers from severe demetalation due to the insufficient stability of Cu(I)-cyclam. Cu(II)-PCB-cyclam and Cu(II)-PCB-TE2A are revealed to exhibit much less demetalation behavior, but poor CO2 reduction activities as well. The inferior electrocatalytic ability of Cu(II)-PCB-cyclam is ascribed to its redox potential that is too high for CO2 reduction, and that of Cu(II)-PCB-TE2A to the steric hindrance preventing facile contact with CO2 molecules. This study suggests that in addition to the redox potential and chemical stability, the stereochemical aspect has to be considered in designing efficient electrocatalysts for CO2 reduction.

A Study on Optimization of Noise Reduction of Auxiliary Power Unit for Military Tracked Vehicle (군용 궤도장비 보조동력장치의 소음저감 최적화 연구)

  • Lee, Ju-Seung;Kim, Byeong-Ho;Kim, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.8
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    • pp.336-342
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    • 2018
  • Noise reduction is an important issue in auxiliary power unit(APU) of tracking equipments for using military. In this study, we designed and tested reduction methods of structure borne noise and airborne source noise at the auxiliary power unit. From the bench test results, it is found that the effect of noise reduction is about 22 dB(A) if the silencer is redesigned, which is the rescue structure. However, the influence of noise reduction by air is insufficient. In addition, it is confirmed that the effect of noise reduction is excellent when structure borne noise reduction is applied to the vehicle. We expected that the test results of this study are used as basic data to reduce the noise of other tracking equipment developed later.