• Title/Summary/Keyword: Reduction process

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Development of an Oxide Reduction Process for the Treatment of PWR Spent Fuel (PWR 사용후핵연료 처리를 위한 금속전환공정 개발)

  • Hur, Jin-Mok;Hong, Sun-Seok;Jeong, Sang-Mun;Lee, Han-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.1
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    • pp.77-84
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    • 2010
  • Reduction of oxides has been investigated for the volume reduction and recycling of the spent oxide fuel from commercial nuclear power plants. Various oxide reduction methods were proposed and KAERI (Korea Atomic Energy Research Institute) is currently developing an electrochemical reduction process using a LiCl-$Li_2O$ molten salt as a reaction medium. The electrochemical reduction process, the front end of the pyroprocessing, can connect the PWR (Pressurized Water Reactor) oxide fuel cycle to a metal fuel cycle of the sodium cooled fast reactor. This paper summarizes KAERI efforts on the development, improvement, and scale-up of the oxide reduction process.

Optimal Imperfect-Quality Inventory Models for Continuous and Discrete Shipping with Process Improvement and Setup Reduction (프로세스 품질 개선과 셋업 절감을 고려한 연속 및 불연속 배송 환경에서의 최적 불완전 품질 재고 모형)

  • Kim, Dae-Soo;Yoo, Seung-Ho
    • Journal of the Korean Operations Research and Management Science Society
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    • v.34 no.1
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    • pp.11-28
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    • 2009
  • Intelligent investment in setup cost reduction and process reliability improvement is crucial to an emerging integrated lean six sigma practice today. This study examines a cost-minimizing problem of jointly determining production lot size, setup cost reduction, and process reliability improvement decisions for a manufacturer with an imperfect production process. We develop models for previously untapped discrete shipping in a supply chain context as well as continuous shipping and solve them optimally using differential calculus and nonlinear programming. We also conduct analytic and numerical sensitivity analyses to provide various important managerial insights into practices.

Evaluation of Excess Sludge Reduction in the OSA Process using Kinetic Parameter and Mass Balance (동역학계수 및 물질수지를 이용한 OSA공정의 잉여슬러지 감량능 평가)

  • Nam, Duck-Hyun;Jang, Hyung-Suk;Ha, Kuem-Ryul;Kim, Joon-Kyu;Ju, Jae-Young;Jung, In-Ho;Park, Chul-Hwi
    • Journal of Korean Society on Water Environment
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    • v.25 no.4
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    • pp.530-538
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    • 2009
  • The Oxic-Settling-Anaerobic (OSA) treatment process, a modified Conventional Activated Sludge (CAS) process, was developed for the purpose of sludge reduction. The insertion of a sludge holding tank into a sludge return line, an anaerobic reactor, forming an OSA process, may provide a cost-effective way of reducing excess sludge production during a process. The OSA process was evaluated for its sludge reduction ability by kinetic parameter and mass balance, with an observed excess sludge reduction of 63.5%, as $P_{X.VSS}$, compared with the conventional activated sludge process.

Comparison Study of the Synthesized Silver Nano-particles using Liquid Phase Reduction Method and Alcohol Reduction Process (액상환원법과 알코올환원법으로 제조한 은나노입자특성 비교에 관한 연구)

  • Son, Eun-Jong;Hwang, Young-Gu;Shin, Yu-Shik;Jeong, Sung-Hoon
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.146-153
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    • 2011
  • Silver nano-particles have been synthesized by liquid phase reduction method and alcohol reduction process. Silver nano-particles of the size 30 ~ 40 nm were formed successfully by alcohol reduction process. The formation, structure, morphology and size of silver nano-particles have been studied using FE-SEM, TEM, XRD, UV-visible spectroscopy. In particular high dispersion stability of the synthesized silver nano-particles could be obtained by PVP binding. Antibacterial activity of Ag/PET master batch sample made from its nano-silver particles showed excellent antibacterial activity against S. aureus and E. coli.

The Optimization of Hydrogen Reduction Process for Mass Production of Fe-8wt%Ni Nanoalloy Powder

  • Jung, Sung-Soo;Kang, Yun-Sung;Lee, Jai-Sung
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1331-1332
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    • 2006
  • The present investigation has attemped to optimize hydrogen reduction process for the mass production of Fe-8wt%Ni nanoalloy powder from ball milled $Fe_2O_3-NiO$ powder. In-situ hygrometry study was performed to monitor the reduction behavior in real time through measurement of water vapor outflowing rate. It was found that the reduction process can be optimized by taking into account the apparent influence of water vapor trap in the reactor on reduction kinetics which strongly depends on gas flow rate, reactor volume and reduction.

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Mechanical Effects of Pipe Drawing Angle and Reduction Rate on Material (파이프 인발 각도에 따른 기계적 효과 및 재료에 따른 감소율에 관한 연구)

  • Seo, Youngjin
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.12
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    • pp.8-13
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    • 2020
  • Seamless pipes are fabricated by drilling a hole in a cylindrical material and drawing the material to the desired diameter. These pipes are used in environments where high reliability is required. In this study, the pipe drawing process was simulated using DEFORM, a commercial finite element method (FEM) analysis program. The outer diameter of the steel cylinder used herein before drawing was 70 mm, and the target outer diameter was 58 mm. The drawing process consisted of two stages. In this study, the effect of cross-sectional reduction rate on the pipe was investigated by varying the cross-sectional reduction rate in each step to achieve the target outer diameter. The results of this study showed that the first section reduction rate of 26% and the second section reduction rate of 13.9% caused the lowest damage to the material. Moreover, the FEM simulation results confirmed the influence of the drawing die angle on the pipe drawing process. The drawing die angles of 15° in the first step and 9° in the second step caused the least damage to the material.

A Study on Characteristic of NO Reduction by High Level O2Gas in Selective Non-Catalystic Reaction (High Level O2배가스중 NO 저감에 대한 선택적비촉매환원 반응특성에 관한 연구)

  • 이강우;정종현;오광중
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.577-582
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    • 2002
  • Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

A Study on the Operation Condition for Carbon-Nitrogen Removal in Wastewater and Sludge Reduction using PVA-gel Immobilized Microorganism (PVA-gel 미생물 고정화 담체를 이용한 고도하수처리 및 슬러지 감량화 운전조건 연구)

  • Lee, Jin-Sook;Park, Hyung-Whan;Nam, Duk-Hyun;Park, Chul-Hwi;Jung, In-Ho;Yoo, Young-Kwan
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.6
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    • pp.875-883
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    • 2006
  • The carbon and nitrogen removal process using PVA-gel (Polyvinyl Alcohol) immobilized microorganisms was studied. The process has been operated under diverse process conditions for 12 months. The process consists of denitrification with internal recycle of 300%, nitrification, aerobic digestion reactors and settling tank. Nitrificatoin and nitrogen removal efficiency according to gel packing ratio and temperature were studied. Yield for Heterotrophs ($Y_H$), decay coefficient for Heterotrophs($b_H$) in aerobic digestion reactor were determined to seize sludge reduction mechanism and compared with typical data of activated sludge process. Then SRT in aerobic digestion reactor was determined on an experimental basis and sludge reduction efficiency was calculated. The process was implemented successfully with sludge reduction efficiency of 92.0~98.5% on a basis of biomass.

A Study on the Heat and Mass Balance of Smelting Reduction Process for Manganese Nodules (망간단괴 용융환원 제련공정의 물질 및 열수지 모델링)

  • Cho, Moon Kyung;Park, Kyung Ho;Min, Dong Joon
    • Korean Journal of Metals and Materials
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    • v.47 no.5
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    • pp.304-310
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    • 2009
  • Recently, manganese nodule has been focused on alternative resources because of its high grade of noble metallic elements such as Co, Ni, and Cu etc. From the viewpoint of an optimization the operating variables for energy efficiency of smelting reduction process, thermodynamic model for smelting reduction process of Manganese nodule was developed by using energy and material balance concept. This model provided that specific consumption of pure oxygen and coke was strongly depended on post combustion ratio (PCR) and heat transfer efficiency (HTE). The dressing and dehydrating process of low grade manganese can be proposed an essential process to minimize the specific energy consumption with decreasing slag volume. The effect of electricity coal base smelting reduction process was also discussed from the energy optimizing point of view.

A Study on the Treatment of Wastewater from the Weight-Reduction Process of Polyester (폴리에스테르 감량가공(減量加工) 폐수(廢水)의 최적(最適) 처리방안(處理方案)에 관한 연구(硏究))

  • Chung, Yoon Jin;Yang, Tae Du;Kim, Woong Ha
    • Journal of Korean Society of Water and Wastewater
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    • v.7 no.1
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    • pp.20-28
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    • 1993
  • The Wastewater from the weight reduction process of polyester is more difficult to be treated biologically than the general wastewater from dyeing and finishing processes in textile industries. Above wastewater shows high pH, high organic strength and wide variation of organic loading. These characteristics are due to TPA and EG resulting from alkaline weight-reduction process and make trouble in the operation of activated sludge process. Therefore, the objective of this study is to develop the pretreatment method for the successful operation of treatment process. For the successful pretreatment process, the wastewater from weight-reduction process should be segregated from other wastewater stream and then acidified with concentrated sulfuric acid to precipitate out TPA from DST solution. At the optimum pH of 2. 2, the initial $COD_{cr}$ 60,000mg/l is reduced to 11,500mg/l and the removal efficiency of $COD_{cr}$ is 81.1%. The required amount of sulfuric acid for pretreatment is not greater than the amount for the the existing neutralization process. Moreover, the supernatant of pretreatment process can be reused in acidification of wastewater.

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