• Title/Summary/Keyword: Rate Capability

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Rate Capability of LiFePO4 Cathodes and the Shape Engineering of Their Anisotropic Crystallites

  • Alexander, Bobyl;Sang-Сheol, Nam;Jung-Hoon, Song;Alexander, Ivanishchev;Arseni, Ushakov
    • Journal of Electrochemical Science and Technology
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    • v.13 no.4
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    • pp.438-452
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    • 2022
  • For cuboid and ellipsoid crystallites of LiFePO4 powders, by X-ray diffraction (XRD) and microscopic (TEM) studies, it is possible to determine the anisotropic parameters of the crystallite size distribution functions. These parameters were used to describe the cathode rate capability within the model of averaging the diffusion coefficient D over the length of the crystallite columns along the [010] direction. A LiFePO4 powder was chosen for testing the developed model, consisting of big cuboid and small ellipsoid crystallites (close to them). When analyzing the parts of big and small rate capabilities, the fitting values D = 2.1 and 0.3 nm2/s were obtained for cuboids and ellipsoids, respectively. When analyzing the results of cyclic voltammetry using the Randles-Sevcik equation and the total area of projections of electrode crystallites on their (010) plane, slightly different values were obtained, D = 0.9 ± 0.15 and 0.5 ± 0.15 nm2/s, respectively. We believe that these inconsistencies can be considered quite acceptable, since both methods of determining D have obvious sources of error. However, the developed method has a clearly lower systematic error due to the ability to actually take into account the shape and statistics of crystallites, and it is also useful for improving the accuracy of the Randles-Sevcik equation. It has also been demonstrated that the shape engineering of crystallites, among other tasks, can increase the cathode capacity by 15% by increasing their size correlation coefficients.

Evaluation of Ramping Capability for Day-ahead Unit Commitment considering Wind Power Variability (풍력발전의 변동성을 고려한 기동정지계획에서의 적정 Ramping 용량 산정)

  • Lyu, Jae-Kun;Heo, Jae-Haeng;Park, Jong-Keun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.4
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    • pp.457-466
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    • 2013
  • Wind energy is rapidly becoming significant generating technologies in electricity markets. As probabilistic nature of wind energy creates many uncertainties in the short-term scheduling, additional actions for reliable market operation should be taken. This paper presents a novel approach to evaluate ramping capability requirement for changes in imbalance energy between day-ahead market and real-time market due to uncertainty of wind generation as well as system load. Dynamic ramp rate model has been applied for realistic solution in unit commitment problem, which is implemented in day-ahead market. Probabilistic optimal power flow has been used to verify ramping capability determined by the proposed method is reasonable in economic and reliable aspects. This approach was tested on six-bus system and IEEE 118-bus system with a wind farm. The results show that the proposed approach provides ramping capability information to meet both forecasted variability and desired confidence level of anticipated uncertainty.

Investigating the Determinants of Public Servant Income Management

  • Zin, Md Lazim Mohd;Ibrahim, Hadziroh;Sulaiman, Ahmad Zafwan
    • Asian Journal of Business Environment
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    • v.8 no.2
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    • pp.33-41
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    • 2018
  • Purpose - This study aims to examine the determinants of income management of the public servant. Three independent variables are examined such as attitude towards money, financial capability and debt management while the dependent variable is financial wellbeing of public servants. Research design, data, and methodology - Quantitative research is applied in this study, and data are collected by using cross sectional approach. Survey questionnaires are obtained from 270 respondents, which represents 79% response rate. The multiple regressions are used to examine the influence of attitude towards money, financial capability and debt management towards financial wellbeing. Results - The result of the multiple regression indicated positive influences of attitude towards money and financial capability on financial wellbeing. However, debt management found no significant influence on financial wellbeing. Conclusions - Research findings show that people have different attitudes towards money and different trends of expenditure. It is also crucial to be highlighted that employees' attitude and financial capability have a greater influence on overall satisfaction with employees' financial wellbeing. Some would want to show off their luxury items they bought to close friends or relatives and some are very prudent in making expenditures even for necessity items.

CMC Evaluation of Flowmeter Calibration System for Liquid (액체용 유량계교정시스템의 교정측정능력 평가)

  • Lee, Dong-Keun;Kim, Jong-Seob;Park, Tae-Jin;Park, Jong-Ho
    • The KSFM Journal of Fluid Machinery
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    • v.17 no.4
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    • pp.5-10
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    • 2014
  • It is possible for the nation's largest flowmeter calibration system in K-water to calibrate flow rate up to $2,700m^3/h$ and diameter 800mm. However, the calibration and measurement capability of K-water's system is not satisfied in comparison with other developed countries. In this study, we find the dominant factors related to the uncertainty of weight and time measurement for gravimetric flowmeter calibration system. As a results of improving the system, the combined standard uncertainty has been improved $1.099{\times}10^{-3}$ to $2.332{\times}10^{-4}$. So calibration and measurement capability got 0.08 percent of the relative expanded uncertainty for maximum flow rate using the coverage factor(k=2).

Response Time Index and Suppression Capability of Standard and Quick Response Sprinkler Head (표준형 및 속동형 스프링클러헤드의 반응시간지수와 소화성능)

  • 정길순;이병곤
    • Journal of the Korean Society of Safety
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    • v.13 no.4
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    • pp.59-70
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    • 1998
  • In this study, response time index(RTI) of standard and quick response type sprinkler head are measured and compared through ramp and plunge test in heated wind tunnel. Also discharge rate and water distribution, actual delivered density(ADD), fire test with wood cribs are performed to compare the fire suppression capability and the operation time and temperature between standard and quick response type sprinkler head.

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Effect of Composite Conductor on Characteristics of Electric Double Layer Capacitor (전기이중층 커패시터의 특성에 미치는 혼성 도전재의 영향)

  • 김익준;이선영;문성인
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.1
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    • pp.107-111
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    • 2004
  • This work describes the effect of composite conductor on the characteristics of electric double layer capacitor. Test cell, which was fabricated with conducting composite consisted of 80% of SPB and 20% of VGCF, exhibits the better tate capability and the lower resistance than those of the cells fabricated with single electronic conductor. These enhanced properties could be related with the decrease of contact resistance between the activated carbon powders.

Improvement of Electrochemical Reaction Kinetics in Lithium Manganese Oxide Thin Films (리튬 망간산화물 박막에서의 전극 반응의 개선)

  • Park Young-Shin;Kim Chan-Soo;Joo Seung-Ki
    • Journal of the Korean Electrochemical Society
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    • v.3 no.2
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    • pp.96-99
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    • 2000
  • In order to improve the rate capability of lithium manganese oxide thin film, we prepared the patterned cathode films by conventional lithography and etching techniques. From the investigation of discharge current density effects on discharge curves of cathode films, the rate capability was greatly improved due to increase of lithium intercalation kinetics fur charge transfer.

Service Resource, Capability and Performance: an Exploratory Study on Hotel Industry (호텔 서비스 자원에 따른 운영역량과 성과의 차이에 관한 연구)

  • Cho, Jungeun
    • Journal of Korean Society for Quality Management
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    • v.41 no.4
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    • pp.513-525
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    • 2013
  • Purpose: The purpose of this paper are to propose a strategic map for hotel industry through analyzing the relationship between service resource, operational capabilities, and performance. Methods: A phone survey was conducted among Korean hotels, and 102 data sets were collected. Measurement items are assessed using both cognitive and objective scales. Results: As results, 'superior group', which is superior in both physical resources and human resources, is excellent in all capabilities and also in room occupancy rate. On the other hands, 'inferior group', which is inferior in both physical resources and human resources, shows lower achievements is in most areas except speed. In addition, physical superior group is better than human superior group in most capabilities except speed, but human superior group shows better results than physical superior group in both room occupancy rate and customer satisfaction. Conclusions: Through the empirical analysis, the conclusions attained are as follows; First, human resources affect customer satisfaction more directly that physical resources. Second, the balancing between physical resources and human resources has an importance to improve operational capabilities.

Effect of Conducting Composite on Characteristics of Electric Double Layer Capacitor (전기이중층 캐패시터의 특성에 미치는 혼성 도전재의 영향)

  • Kim, Ick-Jun;Lee, Sun-Young;Do, Chil-Hoon;Moon, Seong-In;Choi, Sung-Ok;Son, Young-Mo;Kim, Kyung-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1140-1143
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    • 2002
  • This work describes the effect of conducting composite on the characteristics of electric double layer capacitor. The cell, which was fabricated with conducting composite consisted of 50 wt.% of SPB and 50 wt.% of VGCF, exhibits the higher specific capacitance, the lower resistance and the better rate capability than those of the cells fabricated with each single electronic conductor. These enhanced properties could be related with the dense structure of electrode.

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Influence of Carbon Black as a Conductor on Electrode Characteristics for Lithium Secondary Battery

  • Yoon, Se-Rah;Lee, Joong-Kee;Ju, Jae-Beck;Cho, Byung-Won;Park, Dal-Keun
    • Carbon letters
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    • v.3 no.1
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    • pp.17-24
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    • 2002
  • The electrochemical behavior of the $LiCoO_2$ electrode, containing carbon black as a conductor, depends upon the nature and characteristics of carbon black. In this study, six different kinds of carbon blacks were employed to investigate the relationship between the properties of carbon blacks and electrochemical characteristics of the electrode. The larger amount of surface oxygen functional groups brought the lower electrical conductivity for the carbon blacks. The electrical conductivity of carbon blacks was closely related to the impurities such as ash and volatile content. The rate capability and cyclability of the electrode were improved with the higher conductivity of carbon blacks used. So, it can be concluded that high conductive carbon black plays an important role as a conductor for high rate of charge-discharge capability and initial efficiency.

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