• Bulletin of the Korean Chemical Society
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• 제34권3호
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• pp.793-800
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• 2013

A few years ago, the plasmon-induced electronic coupling (PIEC) model was proposed in the literature to explain small changes in the surface-enhanced Raman scattering (SERS) in nanogap systems. If this model is correct, it will be very helpful in both basic and application fields. In light of this, we carefully reexamined its appropriateness. Poly(4-vinylpyridine) (P4VP) used in the earlier work was, however, never a proper layer, since most adsorbates not only adsorbed onto Ag nanoparticles sitting on P4VP but also penetrated into the P4VP layer deposited initially onto a flat Ag substrate, ultimately ending up in the SERS hot sites. Using 1,4-phenylenediisocyanide and 4-nitrophenol as the affixing layer and the foreign adsorbate, respectively, we could clearly reveal that the PIEC model is not suited for explaining the Raman signal in a nanogap system. Most of the Raman signal must have arisen from molecules situated at the gap center.

• 한국광학회지
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• 제1권2호
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• pp.142-148
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• 1990

Sarid형의 감쇠 전반사 구조를 통하여 장거리 표면 프라즈몬을 여기시켜 은-피리딘 경계면에서 표면증강 라만산란 실험을 수행하였다. 장거리 표면 플라즈몬의 여기를 확인하기 위해 은을 $100\AA$으로 증착하여 실험한 결과, 그 진행을 눈으로 볼 수 있었다. 이것을 이용해서 은 표면에 흡착된 피리딘의 라만신호를 관측하여 체적 상태 및 화학적 흡착이 있는 경우의 피리딘의 라만신호와 비교, 분석하였는데 장거리 표면 프라즈몬을 이용한 표면증강 라만산란 실험을 아직까지 보고된 바 없다.

• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.625-628
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• 2012

We investigated the interaction between polyynes (linear carbon chains) and various metal nanoparticles (Ag, Au, and Cu) to provide insight into the optical properties of metal-polyynes systems prepared by different experimental techniques. Polyynes were produced by laser ablation in deionized water, metal nanoparticles solutions, and copper chloride solution. Metal nanoparticles complexes with polyynes were analyzed by Raman, surface-enhanced Raman scattering, and UV-vis spectroscopy.

• Bulletin of the Korean Chemical Society
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• 제34권9호
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• pp.2833-2834
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• 2013

• Journal of the Optical Society of Korea
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• 제14권3호
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• pp.209-214
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• 2010

The Raman shift of water vapor is 3657 $cm^{-1}$, and this Raman signal can be easily separated from other Raman signals or elastic signals. However, it is difficult to make simultaneous Raman measurements on the three phases of water, namely, ice water, liquid water, and water vapor. This is because we must consider the overlap between their Raman spectra. Therefore, very few groups have attempted to make Raman simultaneous measurements even on two elements (water vapor and liquid water, or water vapor and ice water). We have made an effort to find three characteristic Raman wavelengths that correspond to the three phases of water after measuring full Raman spectra of water on particular days that are rainy, snowy or clear. Finally, we have found that the 401-nm, 404-nm, and 408-nm wavelengths are the most characteristic Raman wavelengths that are representative of the water phases when we are using the 355-nm laser wavelength for making measurements.

• 천문학회보
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• 제39권2호
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• pp.88.2-88.2
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• 2014

The symbiotic star V1016 Cygni shows the Raman scattered O VI features at $6825{\AA}$ and $7088{\AA}$. These are formed through inelastic scattering of O VI 1032, 1038 by atomic hydrogen. They exhibit characteristic double peak profiles with a stronger red peak, which is explained by the accretion flow around the white dwarf. In addition, the two Raman features have different profiles in such a way that the blue part of the Raman 7088 feature is relatively more suppressed than the Raman 6825 counterpart. We produced the Doppler maps of the two Raman features in order to trace the origin of the disparate profiles. We conclude that the profile difference is due to various O VI 1032 to O VI 1038 flux ratios in the accretion region. This is consistent with the picture where the slow stellar wind from the giant interacts with the accretion flow around the white dwarf.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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• pp.93-93
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• 2008

This paper presents the Raman scattering characteristics of poly (polycrystalline) 3C-SiC thin films deposited on AlN buffer layer by atmospheric pressure chemical vapor deposition (APCVD) using hexamethyldisilane (MHDS) and carrier gases (Ar + $H_2$).The Raman spectra of SiC films deposited on AlN layer of before and after annealings were investigated according to the growth temperature of 3C-SiC. Two strong Raman peaks, which mean that poly 3C-SiC admixed with nanoparticle graphite, were measured in them. The biaxial stress of poly 3C-SiC/AlN was calculated as 896 MPa from the Raman shifts of 3C-SiC deposited at $1180^{\circ}C$ on AlN of after annealing.

• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.805-808
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• 2011

We have determined the urea concentration in an aqueous solution using Raman spectroscopy by incorporating a Teflon tube as an effective intensity correction standard as well as sample container. A non-overlapping Teflon band was used as the reference peak to correct Raman intensity variations that occasionally resulted from changes in laser power. To increase the sensitivity, we positioned a copper reflector inside the Teflon tube to maximize the collection of Raman scattering. The obtained accuracy using Raman spectroscopy was 0.53 mM, close to the range of accuracy of previous NIR studies (0.15-0.52 mM).

• 한국진공학회지
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• 제15권2호
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• pp.162-167
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• 2006

[ $GaAs_{1-x}N_{x}$ ]의 전도띠 바닥전자상태의 특성을 Ge 기판위에 성장시킨 $GaAs_{1-x}N_{x}(x{\leq}0.7)$ 박막에 대한 공명라만산란 실험을 수행함으로써 조사하였다. LO(longitudinal optical)-phonon 라만세기의 강한 공명상승이 $E_+$ 뿐만 아니라 $E_0$ 전이에너지 근처에서 관측되었다. 그러나 $E_+$ 전이에너지 아래와 근처에서 관측되는 분명한 LO-phonon 선폭 공명상승과 다양한 X와 L 영역경계 (zone-boundary) phonon의 활성화와는 대조적으로, $E_0$ 전이에너지 근처에서는 어떠한 LO-phonon 선폭 확장공명이나 날카로운 영역경계 phonon의 활성화가 관측되지 않았다. 관찰된 공명라만산란 결과는 GaAsN의 전도띠 바닥전자상태가 비국소화된 bulk GaAs와 거의 흡사한 ${\Gamma}$대칭 상태로 구성되었다는 사실을 의미한다.

• 천문학회보
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• 제25권2호
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• pp.86-86
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• 2000