• Title/Summary/Keyword: Radiation induced degradation

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A Study on the Relationship of Change of Mechanical Properties and Carbonyl Index Induced through Short-wavelength Ultraviolet Radiation (254 nm) for High Density Polyethylene (단파장 자외선(254 nm)에 노출된 고밀도 폴리에틸렌 수지의 카르보닐 지수(CI)와 기계적 물성 변화의 관계에 관한 연구)

  • Kim, Chang-Hwan;Shin, Jin-Yong
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.138-143
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    • 2013
  • This paper studied the possibility to predict a mechanical property variation from changes in created carbonyl bands by irradiating the surface of high-density polyethylene with short-wavelength ultraviolet radiation of 254 nm to induce a fast chemical degradation. The meaning of this study lies in checking whether a mechanical property change with the same chemical property as the induced optical deterioration is caused by using a UVC lamp with high photon energy instead of optical deterioration via xenon arc light source and outdoor exposure test via natural sunlight requiring a long time. The mechanical strength of high-density polyethylene checked by a tensile test and a creep destruction test showed a similar tendency with CI changes. In particular, the yield strength and elongation had a close relationship with the exposure time to ultraviolet radiation. Accordingly, this paper presented a method to grasp the mechanical property change outdoors requiring a long time more fast through the relationship between the mechanical property change and the carbonyl index using a UVC lamp causing the fast surface degradation.

Structural Changes in $^{60}Co\;\gamma-Ray$ Irradiated Poly(vinylidene fluoride) ($^{60}Co\;\gamma$-선 조사에 의한 Poly(Vinylidene fluoride)의 구조적 변화)

  • Lee, Chung;Kim, Ki-Yup;Kim, Pyeong-Jong;Kim, Jin-Ah;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.437-440
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    • 2004
  • The radiation-induced changes taking place in poly(vinylidene fluoride)(PVDF) exposed to $^{60}Co\;\gamma-ray$ irradiation were investigated in correlation with the applied doses. Samples were irradiated in air at room temperature by $^{60}Co\;\gamma-ray$ to doses in the range of 200 to 1000 kGy. Various properties of the irradiated PVDF were studied using nm, differential scanning calorimetry(DSC) and gel fraction. $^{60}Co\;\gamma-ray$ irradiation was found to induce changes in chemical, thermal, structural properties of PVDF and such changes vary depending on the radiation dose.

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The Analysis of Total Ionizing Dose Effects on Analog-to-Digital Converter for Space Application (우주용 ADC의 누적방사선량 영향 분석)

  • Kim, Tae-Hyo;Lee, Hee-Chul
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.6
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    • pp.85-90
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    • 2013
  • In this paper, 6bit SAR ADC tolerant to ionizing radiation is presented. Radiation tolerance is achieved by using the Dummy Gate Assisted (DGA) MOSFET which was proposed to suppress the leakage current induced by ionizing radiation and its comparing sample is designed with the conventional MOSFET. The designed ADC consists of binary capacitor DAC, dynamic latch comparator, and digital logic and was fabricated using a standard 0.35um CMOS process. Irradiation was performed by Co-60 gamma ray. After the irradiation, ADC designed with the conventional MOSFET did not operate properly. On the contrary, ADC designed with the DGA MOSFET showed a little parametric degradation of which DNL was increased from 0.7LSB to 2.0LSB and INL was increased from 1.8LSB to 3.2LSB. In spite of its parametric degradation, analog to digital conversion in the ADC with DGA MOSFET was found to be possible.

Accumulation of Chlorogenic Acid as a near UV-shielding Compound in Cauliflower Grown under Enhanced UV-B Radiation

  • Shibata, Hitoshi;Tanaka, Tomoyuki;Yonemura, Takeshi;Sawa, Yoshihiro;Ishikawa, Takahiro
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.436-438
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    • 2002
  • Since solar radiation contains wavelength essential for photosynthesis accompanying with near-UV light, UV-B effects on biological parameters and acclimation mechanisms are influenced by photosynthetically active radiation (PAR). Therefore, to elucidate near-UV shielding mechanism in higher plants, we cultivated cauliflower under usual solar radiation and increased UV-B from fluorescent lamps, two- or three-fold excess over continuously estimated UV-B dose in PAR during daytime, using computer regulated systems. Increased UV-B radiation had little effect on growth expressed as fresh weigh and leaf area. Water soluble low molecular weight compounds showing absorption in near UV region were enhanced according to the irradiated UV-B dose. One of compounds in cauliflower leaves was identified as chlorogenic acid. This was found to have no near-UV photosenSitizerable activity and is known to have an ability to scavenge a wide species of active oxygen. Another pro-oxidant compound that generates superoxide anion radical under near-UV irradiation was not induced by increased UV-B during cultivation, and identified as lumazine, a degradation product from folic acid.

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X-ray and Plasma Process Induced Damages to PLZT Capacitor Characteristics for DRAM Applications

  • Kim, Jiyoung
    • The Korean Journal of Ceramics
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    • v.3 no.3
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    • pp.213-217
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    • 1997
  • In this paper, the imparct of X-ray and plasma process-induced-damages to La doped Lead Zirconate Titanate (PLZT, (Pb1-xLa)(Zr0.5Ti0.5)O3) capacitor characteristics have been investigated from the viewpoint of gigabit scale dynamic random access memory (DRAM) applications. Plamsa damage causes asymmetric degradation on hysteresis characteristics of PLZT films. On the other hand, X-ray damage results in a symmetrical reduction of charge storage densities (Qc's) for both polarities. As La concentration increases in the films, the radiation hardness of PLZT films on X-ray and plasma exposures is improved. It is observed that the damaged devices are fully recovered by thermal annealing under oxygen ambient.

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Radiation-induced Degradation and Immune Toxicity Reduction of Endosulfan (감마선 조사에 의한 endosulfan의 면역독성 저감)

  • Kim, Hyun-Joo;Kim, Tae-Hoon;Ham, Jun-Sang;Kim, Kee-Hyuk;Jo, Cheo-Run
    • Food Science and Preservation
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    • v.19 no.3
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    • pp.451-454
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    • 2012
  • Endosulfan is an organochlorine pesticide that is widely used throughout the world for higher agricultural production. Its extreme toxicity, however, has caused health and environment concerns that have led to an interest in detoxification. In this study, the radiolytic degradation of endosulfan was investigated. Endosulfan in methanol solution (100 ppm) was irradiated at 0, 10, 30, and 50 kGy, and subsequent changes in immune toxicity and degradation of endosulfan were observed. The concentration of endosulfan that was used in this experiment did not affect the cell proliferation. The irradiation of endosulfan decreased the production of NO, indicating a decrease in the immune toxicity of endosulfan by irradiation. The concentration of endosulfan was significantly reduced by irradiation in a dose-dependent manner. The results suggest that gamma irradiation can degrade endosulfan and can reduce its immune toxicity.

UV-B-Induced Changes in Carbohydrate Content and Antioxidant Activity in Rice Seedling

  • Sung Jwa-Kyung;Lee Su-Yeon;Park So-Hyun;Jang Byoung-Choon;Lee Sang-Min;Lee Yong-Hwan;Choi Du-Hoi;Song Beom-Heon
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.50 no.2
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    • pp.84-90
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    • 2005
  • The effects of UV-B radiation on the seedling growth, carbohydrate metabolism and antioxidants activities of rice (Oryza sativa L.) were investigated under environmentally controlled chamber. Supplementary UV­B radiation reduced dry matter as well as leaf area, there­fore, relative growth rates (RGR) of seedlings were decreased by up to half compared to control. Photosynthetic products such as soluble sugars and starch were rapidly and significantly reduced by within 1 day of enhanced UV-B radiation due to the inhibition and degradation of photosynthetic processes and thylakoid membrane integrity. In our study, nonstructural carbohydrate levels were proved to be a main indicator on UV-B­induced stress. The behavior of SOD, CAT, APX and POD activities was monitored in the leaves of rice seedlings subjected to UV-B radiation. Under UV-B treatments, SOD activity was initially increased, whereas CAT and POD activities were slowly and slightly increased. However, APX activity showed no presumable results with an increase of UV-B dose. In leaves of rice seedlings, supplementary UV-B radiation caused an increase in free putrescine and spermidine, however spermine remained unaltered, although 24-hrs UV-B treatment slightly increased. This result presumes that an excess UV-B dose may induce ethylene biosynthesis (senescence) rather than polyamine biosynthesis (defense).

Comparison of tdcA Expression Between Escherichia coli and Salmonella enterica Serovar Typhimurium

  • Kim, Min-Jeong;Lim, Sang-Yong;Ryu, Sang-Ryeol
    • Journal of Microbiology and Biotechnology
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    • v.21 no.3
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    • pp.252-255
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    • 2011
  • Both Escherichia coli (E. coli) and Salmonella enterica serovar Typhimurium (S. Typhimurium) have a tdc operon that encodes enzymes involved in a metabolic pathway for the degradation of L-serine and L-threonine. However, S. Typhimurium does not have the tdcR gene, which is a positive regulator in E. coli. In the present study, transcriptional analysis revealed that tdcA expression in E. coli is higher under anaerobic than aerobic growth conditions, but the opposite is true in S. Typhimurium. Interestingly, a tdcR mutant strain of E. coli showed a similar expression pattern to that observed in S. Typhimurium and was also induced by anaerobic shock. These results suggest that the induction of tdcA expression by anaerobic conditions is observable when tdcA expression is low owing to the absence of TdcR.

Aging Evaluation of Polymer Insulator Housing with UV Exposure (자외선 노출에 따른 폴리머애자 하우징의 열화특성평가)

  • 이병성;한재홍;김찬영;한용희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.214-217
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    • 1999
  • Polymeric composite insulators have been in use for outdoor insulation. However, our knowledge about their long-term performance in a outdoor environment is still very limited. Especially, these insulator are subjected to the environmental stress such as ultraviolet radiation. Hence, in this paper. the influence of UV radiation on the aging of the shed materials was evaluated. For the aging evaluation, these insulators studied by experiment methods such as contact angle measurement. oxidation induced time. SEM/EDX, FTRI-ATR, tracking test for the different insulator samples. With the increased UV exposure time, samples are shown to exhibit degradation comparable to those of new ones

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Dielectric Relaxation Properties for following the Ageing of Polyetheretherketone (열화에 따른 Polyetheretherketone의 유전완화특성)

  • Kim, Ki-Yup;Lee, Chung;Ryu, Boo-Hyung;Lim, Kee-Joe
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.4
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    • pp.396-403
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    • 2004
  • The dielectric properties of Y-ray irradiated and thermally aged polyetheretherketone (PEEK) have been investigated. Results of the temperature dependency of dielectric properties indicated that the glass transition temperature of aged PEEK increased as radiative and thermal ageing. The frequency dependency of dielectric properties implied that the magnitude of radiation and thermal induced dipoles, ions increased as radiative and thermal ageing. The values of relaxation intensity calculated using Cole-Cole's circular arc can be useful for evaluation of degradation level of PEEK.