• 제목/요약/키워드: Quantum Confinement

검색결과 141건 처리시간 0.028초

나노-스케일 전계 효과 트랜지스터 모델링 연구 : FinFET (Modeling of Nano-scale FET(Field Effect Transistor : FinFET))

  • 김기동;권오섭;서지현;원태영
    • 대한전자공학회논문지SD
    • /
    • 제41권6호
    • /
    • pp.1-7
    • /
    • 2004
  • 본 논문에서는 2차원 양자 역학적 모델링 및 시뮬레이션(quantum mechanical modeling and simulation)으로써, 자기정렬 이중게이츠 구조(self-aligned double-gate structure)인 FinFET에 관하여 결합된 푸아송-슈뢰딩거 방정식(coupled Poisson and Schrodinger equations)를 셀프-컨시스턴트(self-consistent)한 방법으로 해석하는 수치적 모델을 제안한다. 시뮬레이션은 게이트 길이(Lg)를 10에서 80nm까지, 실리콘 핀 두께($T_{fin}$)를 10에서 40nm까지 변화시켜가며 시행되었다. 시뮬레이션의 검증을 위한 전류-전압 특성을 실험 결과값과 비교하였으며, 문턱 전압 이하 기울기(subthreshold swing), 문턱 전압 롤-오프(thresholdvoltage roll-off), 그리고 드레인 유기 장벽 감소(drain induced barrier lowering, DIBL)과 같은 파라미터를 추출함으로써 단채널 효과를 줄이기 위한 소자 최적화를 시행하였다. 또한, 고전적 방법과 양자 역학적 방법의 시뮬레이션 결과를 비교함으로써,양자 역학적 해석의 필요성을 확인하였다. 본 연구를 통해서, FinFET과 같은 구조가 단채널 효과를 줄이는데 이상적이며, 나노-스케일 소자 구조를 해석함에 있어 양자 역학적 시뮬레이션이 필수적임을 알 수 있었다.

Synthesis and Characterization of ZnO/TiO2 Photocatalyst Decorated with PbS QDs for the Degradation of Aniline Blue Solution

  • Lee, Jong-Ho;Ahn, Hong-Joo;Youn, Jeong-Il;Kim, Young-Jig;Suh, Su-Jeong;Oh, Han-Jun
    • 대한금속재료학회지
    • /
    • 제56권12호
    • /
    • pp.900-909
    • /
    • 2018
  • A $ZnO/TiO_2$ photocatalyst decorated with PbS quantum dots (QDs) was synthesized to achieve high photocatalytic efficiency for the decomposition of dye in aqueous media. A $TiO_2$ porous layer, as a precursor photocatalyst, was fabricated using micro-arc oxidation, and exhibited irregular porous cells with anatase and rutile crystalline structures. Then, a ZnO-deposited $TiO_2$ catalyst was fabricated using a zinc acetate solution, and PbS QDs were uniformly deposited on the surface of the $ZnO/TiO_2$ photocatalyst using the successive ionic layer adsorption and reaction (SILAR) technique. For the PbS $QDs/ZnO/TiO_2$ photocatalyst, ZnO and PbS nanoparticles are uniformly precipitated on the $TiO_2$ surface. However, the diameters of the PbS particles were very fine, and their shape and distribution were relatively more homogeneous compared to the ZnO particles on the $TiO_2$ surface. The PbS QDs on the $TiO_2$ surface can induce changes in band gap energy due to the quantum confinement effect. The effective band gap of the PbS QDs was calculated to be 1.43 eV. To evaluate their photocatalytic properties, Aniline blue decomposition tests were performed. The presence of ZnO and PbS nanoparticles on the $TiO_2$ catalysts enhanced photoactivity by improving the absorption of visible light. The PbS $QDs/ZnO/TiO_2$ heterojunction photocatalyst showed a higher Aniline blue decomposition rate and photocatalytic activity, due to the quantum size effect of the PbS nanoparticles, and the more efficient transport of charge carriers.

산화아연/황화아연 양자점 나노결정에서의 향상된 자외선 방출 (Enhanced UV-Light Emission in ZnO/ZnS Quantum Dot Nanocrystals)

  • 김기은;김웅;성윤모
    • 한국재료학회지
    • /
    • 제18권12호
    • /
    • pp.640-644
    • /
    • 2008
  • ZnO/ZnS core/shell nanocrystals (${\sim}5-7\;nm$ in diameter) with a size close to the quantum confinement regime were successfully synthesized using polyol and thermolysis. X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) analyses reveal that they exist in a highly crystalline wurtzite structure. The ZnO/ZnS nanocrystals show significantly enhanced UV-light emission (${\sim}384\;nm$) due to effective surface passivation of the ZnO core, whereas the emission of green light (${\sim}550\;nm$) was almost negligible. They also showed slight photoluminescence (PL) red-shift, which is possibly due to further growth of the ZnO core and/or the extension of the electron wave function to the shell. The ZnO/ZnS core/shell nanocrystals demonstrate strong potential for use as low-cost UV-light emitting devices.

실리콘 나노결정 박막에서 수소 패시베이션 효과 (Effect of hydrogen on the photoluminescence of Silicon nanocrystalline thin films)

  • 전경아;김종훈;김건희;이상렬
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
    • /
    • pp.1033-1036
    • /
    • 2004
  • Si nanocrystallites thin films on p-type (100) Si substrate have been fabricated by pulsed laser deposition using a Nd:YAG laser. After deposition, samples were annealed at the temperatures of 400 to $800^{\circ}C$. Hydrogen passivation was then performed in the forming gas (95% $N_2$ + 5% $H_2$) for 1 hr. Strong violet-indigo photoluminescence has been observed at room temperature from nitrogen ambient-annealed Si nanocrystallites. The variation of photoluminescence (PL) Properties of Si nanocrystallites thin films has been investigated depending on annealing temperatures with hydrogen passivation. From the results of PL, Fourier transform infrared (FTIR), and high-resolution transmission electron microscopy (HRTEM) measurements, it is observed that the origin of violet-indigo PL from the nanocrystalline silicon in the silicon oxide film is related to the quantum size effect of Si nanocrystallites and oxygen vacancies in the SiOx(x : 1.6-1.8) matrix affects the emission intensity.

  • PDF

전압에 의하여 구동 가능한 12-Laser Diode Array의 광통신에의 응용 (Application of Voltage-Controlled 12-Laser Diode Array in the Optical Fiber Communication)

  • 이상신;지윤규
    • 대한전자공학회논문지
    • /
    • 제27권11호
    • /
    • pp.1-8
    • /
    • 1990
  • 4개의 Quantum well을 갖는 GRINSCH InGaAs/Inp Buried Heterostructure의 laser diode 12개로 구성되어 있는 12-laser diode array를 제작하여, 각 laser diode의 전자 흡수 영역의 인가 전압에 의하여 lasing 작용을 조절할 수 있는 가능성을 조사하였다. 12개의 V가 홈을 갖는 Si V-groove와 12개의 광섬유를 이용하여 12-laser diode array의 빛출력을 coupling하여 전자 흡수영역의 인가 전압의 변화에 따른 각 laser diode의 여러특성을 조사하였다. 마지막으로 12-laser diode array와 Si V-Groove와 광섬유를 이용하여 디지털 논리 gate들로 구성되어 있는 전자 회로 board들 간의 광대역 근거리 통신 및 B-ISDN을 위한 central office와 가입자 간의 통신을 구현하는 방법에 대하여 생각해 보았다.

  • PDF

Energy separation and carrier-phonon scattering in CdZnTe/ZnTe quantum dots on Si substrate

  • 만민탄;이홍석
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
    • /
    • pp.191.2-191.2
    • /
    • 2015
  • Details of carrier dynamics in self-assembled quantum dots (QDs) with a particular attention to nonradiative processes are not only interesting for fundamental physics, but it is also relevant to performance of optoelectronic devices and the exploitation of nanocrystals in practical applications. In general, the possible processes in such systems can be considered as radiative relaxation, carrier transfer between dots of different dimensions, Auger nonradiactive scattering, thermal escape from the dot, and trapping in surface and/or defects states. Authors of recent studies have proposed a mechanism for the carrier dynamics of time-resolved photoluminescence CdTe (a type II-VI QDs) systems. This mechanism involves the activation of phonons mediated by electron-phonon interactions. Confinement of both electrons and holes is strongly dependent on the thermal escape process, which can include multi-longitudinal optical phonon absorption resulting from carriers trapped in QD surface defects. Furthermore, the discrete quantized energies in the QD density of states (1S, 2S, 1P, etc.) arise mainly from ${\delta}$-functions in the QDs, which are related to different orbitals. Multiple discrete transitions between well separated energy states may play a critical role in carrier dynamics at low temperature when the thermal escape processes is not available. The decay time in QD structures slightly increases with temperature due to the redistribution of the QDs into discrete levels. Among II-VI QDs, wide-gap CdZnTe QD structures characterized by large excitonic binding energies are of great interest because of their potential use in optoelectronic devices that operate in the green spectral range. Furthermore, CdZnTe layers have emerged as excellent candidates for possible fabrication of ferroelectric non-volatile flash memory. In this study, we investigated the optical properties of CdZnTe/ZnTe QDs on Si substrate grown using molecular beam epitaxy. Time-resolved and temperature-dependent PL measurements were carried out in order to investigate the temperature-dependent carrier dynamics and the activation energy of CdZnTe/ZnTe QDs on Si substrate.

  • PDF

고출력 $Al_{0.07}$$Ga_{0.93}$As 레이저 다이오드 어레이 제작 (Fabrication of High Power $Al_{0.07}$$Ga_{0.93}$As Laser Diode Array))

  • 손노진;박성수;안정작;권오대;계용찬;정지채;최영수;강응철;김재기
    • 전자공학회논문지A
    • /
    • 제32A권10호
    • /
    • pp.43-50
    • /
    • 1995
  • A laser diode(LD) structure consisting of a single 150$\AA$ $Al_{0.07}$Ga$_{0.93}$As quantum well active region operating at ${\lambda}$=809nm, cladded with an AlGaAs graded-index separate confinement heterostructure, has bes been grown by MOCVD. Temperature coefficient of wavelength is approximately 0.2nm $^{\circ}C$ for the diode. The active aperture consists of five emitters separated from each other by means of SiO$_{2}$ deposition and stripe formation, which creates insulating regions that channel the current to 100-$\mu$m-wide stripes placed on 450-$\mu$m centers. From a typical uncoated LD, the output power of 0.8W has been obtained at a 1$\mu$s, 1kHz pulsed current level of 2.0$\AA$, which results in about 64% external quantum efficiency. The threshold current density is 736A/cm$^{2}$ for the case of 500$\mu$m cavity length LD's. The measure of an internal quantum efficiency was 75.8% and the internal loss 4.83$cm^{-1}$ . Finally, 3.1W output power has been obtained at a 1$\mu$s, 1kHz pulsed current level of 9A from the 500$\mu$m-aperture LD array with 460-$\mu$m- cavity length.

  • PDF

다층 InAs 양자점을 이용한 장파장 적외선 수광소자에 관한 연구 (Studies on Long-wavelength Infrared Detector using Multiple Stacked InAs Quantum Dot Layers)

  • 김종욱;오재응;홍성철
    • 대한전자공학회논문지SD
    • /
    • 제37권8호
    • /
    • pp.42-47
    • /
    • 2000
  • 분자선결정성장법을 이용하여 자기구성 양자점들을 high electron mobility transistor (HEMT)의 체널 영역에 삽입하여, 양자점내의 inter-subband transition을 이용한 전파장 적외선 수광소자를 제작하였다. 제작된 소자는 180 K 이상의 온도에서 InAs 양자점의 전자에 대한 강한 구속력으로 인해 낮은 암전류 특성을 보이며 7${\mu}m$에서 11${\mu}m$까지의 넓은 수광영역을 나타내었다. 9.4${\mu}m$에서 peak 광전류가 검출되었으며 이때의 검출율은 $1.93{\times}10^{10}cmHz^{1/2}/W$ 였다. 장파장 적외선 검출에 따른 광전류는 가해진 전압에 대하여 전계효과트랜지스터와 같은 전류-전압 특성을 가지며, 인가된 전압이 증가함에 따라 증가된 암전류에 의하여 광전류가 감소하는 특성을 보여주고 있다.

  • PDF

Encapsulated Silicon Nanocrystals Formed in Silica by Ion Beam Synthesis

  • Choi, Han-Woo;Woo, Hyung-Joo;Kim, Joon-Kon;Kim, Gi-Dong;Hong, Wan-Hong;Ji, Young-Yong
    • Bulletin of the Korean Chemical Society
    • /
    • 제25권4호
    • /
    • pp.525-528
    • /
    • 2004
  • The photoluminescence (PL) emission of Si nanocrystals synthesized by 400 keV Si ion implanted in $SiO_2$ is studied as a function of ion dose and annealing time. The formation of nanocrystals at around 600 nm from the surface was confirmed by RBS and HRTEM, and the Si nanocrystals showed a wide and very intense PL emission at 700-900 nm. The intensity of this emission showed a typical behaviour with a fast transitory increase to reach a saturation with the annealing time, however, the red shift increased continuously because of the Ostwald ripening. The oversaturation of dose derived a decrease of PL intensity because of the diminishment of quantum confinement. A strong enhancement of PL intensity by H passivation was confirmed also, and the possible mechanism is discussed.

InGaAs/InGaAsP GRINSCH MQW 구조의 파동길잡이 성질 연구 (A study on waveguide properties of InGaAs/InGaAsP GRINSCH MQW laser)

  • 김동철;유건호
    • 한국광학회지
    • /
    • 제7권3호
    • /
    • pp.272-279
    • /
    • 1996
  • 이차원 파동길잡이의 성질을 분석할 수 있는 간단한 넘김행렬 풀이법을 개발하였다. 이 풀이법을 변형된 InGaAs/ImGaAsP GRINSCH MQW 레이저 구조에 적용하여 방식 이득을 계산하는데 필요한 광학가둠 인자, 유효꺽임율 등이 파동길잡이 너비, GRIN의 모양, 양자우물의 갯수 등의 구조 변수에 어떻게 의존하는지 살펴보았다. 특히 GRIN 파동길잡이를 이해하는데 유효 파동길잡이 너비의 개념이 유용함을 보였다.

  • PDF