• Title/Summary/Keyword: QD

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Depositon of NiO films for Inorganic Hole-transporting Layer in QD-LED (QD-LED용 무기계 홀전도층 NiO 박막 증착 연구)

  • Chung, Kook-Chae;Oh, Seung-Kun;Kim, Young-Kuk;Choi, Chul-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.330-330
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    • 2009
  • For the high-performance Quantum dots-Light Emitting Diodes in the near-infrared and visible spectrum, adequate electro- and hole-transporting layers are required. The operation lifetimes of typical materials used in OLEDs are very limited and degraded especially by the oxygen and humid atmosphere. In this work, NiO was selected as a possible hole-transporting layer replacing the TPD film used in QD-LEDs. About 40-nm-thick NiO films have been deposited by the rf-sputtering method on various technical substrates such as FTO/glass, ITO/glass, and ITO/PEN. For the balance of charge carriers and quenching consideration, the resistivity of the deposited NiO films was investigated controlling the oxygen in the sputtering gas. NiO films were fabricated at room temperature and about 6mTorr using pure Ar, 2.5%-, 5%-, and 10%-mixed $O_2$ in Ar respectively. We also investigated the rf-power dependence on NiO films in the range of 80 ~ 200 Watts. The resistivity of the samples was varied from highly conductive to resistive state. Also discussed are the surface roughness of NiO films to provide the smooth surface for the deposition of QDs.

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Application of Quantum-dot Nanocrystals for Cyanobacterial Toxin-Microcystin Detection (나노크리스탈 Quantum-dot을 적용한 남조류 독소 Microcystin 탐지 연구)

  • Lee, Jinwook;Yu, Hye-Weon;Kim, In S.
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.705-711
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    • 2007
  • Green quantum-dot nanocrystal (QD525) with anti-microcystin monoclonal antibody was applied for detection of microcystin, a monocyclic peptide hepatotoxin, extracted from the culture of Microcystis aeruginosa. The presence of microcystin in the cell lysate was verified by HPLC analysis with UV absorbance at 238 nm. Microcystis cell extract exhibited fluorescence emission spectra, which peak was around 460 nm because of their complex organic substances. When a spherical QD525 antibody conjugates (10~20 nm in diameter) were bound to the microcystins in the Microcystis cell lysate, the fluorescence intensity of the primary peak at 525 nm diminished while the secondary emission peak at 460 nm slightly increased intensities. It is due to energy transfer from the primary (major) to the secondary (minor) peak, resulting from physical deformation of QD525 and different environmental factors. On the other hand, other cell extracts did not show any fluorescence emission change. This study is very available for detecting and monitoring the microcystin because it is one step assay without washing step and portable spectrophotometer makes on-site measurement possible. For health risk assessment of the microcystin, the reliable and rapid system to detect and quantify microcystin is seriously required.

Carrier Dynamics of P-modulation Doped In(Ga)A/InGaAsP Quantum Dots (P 변조도핑한 In(Ga)As/InGaAsP 양자점에 대한 운반자 동역학)

  • Jang, Y.D.;Park, J.;Lee, D.;Hong, S.U.;Oh, D.K.
    • Journal of the Korean Vacuum Society
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    • v.15 no.3
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    • pp.301-307
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    • 2006
  • We have investigated optical properties of p-modulation doped In(Ga)As quantum dots (QDs) on InP substrate with a comparison with the undoped QDs. Photoluminscence (PL) intensity of doped QDs at 10 K was about 10 times weaker than that of undoped QD sample. The decay time of doped QD sample at its PL peak, obtained from the time-resolved PL (TR-PL) experiment at 10 K, was very fast compared to that of undoped sample. We interpret that this fast decay time of the doped QD sample comes from the addition of non-radiative recombination paths, which are originated from the doping-related defects.

Improving the Color Gamut of a Liquid-crystal Display by Using a Bandpass Filter

  • Sun, Yan;Zhang, Chi;Yang, Yanling;Ma, Hongmei;Sun, Yubao
    • Current Optics and Photonics
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    • v.3 no.6
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    • pp.590-596
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    • 2019
  • To improve the color gamut of a liquid-crystal display (LCD), we propose a bandpass filter that is added to the backlight unit to optimize the backlight spectrum. The bandpass filter can only transmit red, green and blue light in the visible range, while reflecting the unwanted light. We study the optical properties of the bandpass filter using the transfer-matrix method, and the effect of the bandpass filter on the color gamuts of LCDs is also investigated. When a bandpass filter based on a 5-layer configuration comprising low and high refractive indices ((HL)2H) is used in phosphor-converted white-light-emitting diode (pc-WLED), K2SiF6:Mn4+ (KSF-LED), and quantum-dot (QD) backlights, the color gamuts of the LCDs improve from 72% to 95.3% of NTSC, from 92% to 106.7% of NTSC, and from 104.3% to 112.2% of NTSC respectively. When the incident angle of light increases to 30°, the color gamuts of LCDs with pc-WLED and KSF-LED backlights decrease by 2.9% and 1% respectively. For the QD backlight, the color gamut almost does not change. When the (HL)2H structure is coated on the diffusion film, the color gamut can be improved to 92.6% of NTSC (pc-WLED), 105.6% of NTSC (KSF-LED), and 111.9% of NTSC (QD). The diffusion film has no obvious effect on the color gamut. The results have an important potential application in wide-color-gamut LCDs.

Carrier Transport of Quantum Dot LED with Low-Work Function PEIE Polymer

  • Lee, Kyu Seung;Son, Dong Ick;Son, Suyeon;Shin, Dong Heon;Bae, Sukang;Choi, Won Kook
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.432.2-432.2
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    • 2014
  • Recently, colloidal core/shell type quantum dots lighting-emitting diodes (QDLEDs) have been extensively studied and developed for the future of optoelectronic applications. In the work, we fabricate an inverted CdSe/ZnS quantum dot (QD) based light-emitting diodes (QDLED)[1]. In order to reduce work function of indium tin oxide (ITO) electrode for inverted structure, a very thin (<10 nm) polyethylenimine ethoxylated (PEIE) is used as surface modifier[2] instead of conventional metal oxide electron injection layer. The PEIE layer substantially reduces the work function of ITO electrodes which is estimated to be 3.08 eV by ultraviolet photoemission spectroscopy (UPS). From transmission electron microscopy (TEM) study, CdSe/ZnS QDs are uniformly distributed and formed by a monolayer on PEIE layer. In this inverted QD LED, two kinds of hybrid organic materials, [poly (9,9-di-n-octyl-fluorene-alt-benzothiadiazolo)(F8BT) + poly(N,N'-bis (4-butylphenyl)-N,N'-bis(phenyl)benzidine (poly-TPD)] and [4,4'-N,N'-dicarbazole-biphenyl (CBP) + poly-TPD], were adopted as hole transport layer having high highest occupied molecular orbital (HOMO) level for improving hole transport ability. At a low-operating voltage of 8 V, the device emits orange and red spectral radiation with high brightness up to 2450 and 1420 cd/m2, and luminance efficacy of 1.4 cd/A and 0.89 cd/A, respectively, at 7 V applied bias. Also, the carrier transport mechanisms for the QD LEDs are described by using several models to fit the experimental I-V data.

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The direct digital frequency synthesizer of QD-ROM reduction using the differential quantization (차동 양자화를 사용한 QD-ROM 압축 방식의 직접 디지털 주파수 합성기)

  • Kim, Chong-Il;Lim, So-Young;Lee, Ho-Jin
    • Journal of the Institute of Convergence Signal Processing
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    • v.8 no.3
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    • pp.192-198
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    • 2007
  • In this paper, a new method to reduce the size of ROM in the direct digital frequency synthesizer(DDFS) is proposed. The new ROM compression method can reduce the ROM size by using the two ROM. The quantized value of sine is stored by the quantized-ROM(Q-ROM) and the differential ROM(D-ROM). To reduce the ROM size, we use the differential quantization technique with this two ROM. First, we quantize the quarter sine wave with the $2^L$ address and store the quantized value at the Q-ROM. Second, after the $2^L$ address are equally divided into $2^M$ sampling intervals, the sampling value is quantized. And the D-ROM store only the difference between this quantized value and the Q-ROM. So the total size of the ROM in the proposed DDFS is significantly reduced compared to the original ROM. The ROM compression ratio of 67.5% is achieved by this method. Also, the power consumption is affected mostly by this ROM reduction.

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Study on UV Opto-Electric Properties of ZnS:Mn/ZnS Core-Shell QD

  • Lee, Yun-Ji;Cha, Ji-Min;Yoon, Chang-Bun;Lee, Seong-Eui
    • Journal of the Korean Ceramic Society
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    • v.55 no.1
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    • pp.55-60
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    • 2018
  • In this study, quantum dots composed of $Mn^{2+}$ doped ZnS core and ZnS shell were synthesized using MPA precursor at room temperature. The ZnS: Mn/ZnS quantum dots were prepared by varying the content of MPA in the synthesis of ZnS shells. XRD, Photo-Luminescence (PL), XPS and TEM were used to characterize the properties of the ZnS: Mn/ZnS quantum dots. As a result of PL measurement using UV excitation light at 365 nm, the PL intensity was found to greatly increase when MPA was added at 15 ml, compared to the case with no MPA; the PL peaks shifted from 603 nm to 598 nm. A UV sensor was fabricated by using a sputtering process to form a Pt pattern and placing a QD on the Pt pattern. To verify the characteristics of the sensor, we measured the electrical properties via irradiation with UV, Red, Green, and Blue light. As a result, there were no reactions for the R, G, and B light, but an energy of 3.39 eV was produced with UV light irradiation. For the sensor using ZnS: Mn/ZnS quantum dots, the maximum current (A) value decreased from $4.00{\times}10^{-11}$ A to $2.62{\times}10^{-12}$ A with increasing of the MPA content. As the MPA content increases, the PL intensity improves but the electrical current value dropped because of the electron confinement effect of the core-shell.

InAs 양자점을 이용하여 Silicon (001) 기판위에 제작된 고품질 InSb layer의 특성 분석

  • Im, Ju-Yeong;Song, Jin-Dong;Jo, Nam-Gi;Park, Seong-Jun;Sin, Sang-Hun;Choe, Won-Jun;Lee, Jeong-Il;Kim, Gyeong-Ho;An, Jae-Pyeong;Kim, Hyeong-Jun;Yang, Hae-Seok;Choe, Cheol-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.110-110
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    • 2010
  • 본 실험에서는 Silicon (001) 기판을 사용하여 silicon 기판상에 modified Stranski-Krastanow(S-K) 방식으로 InAs quantum dot (QD) 을 성장하고 그 위에 InSb layer를 형성하였다. 기판온도 $390^{\circ}$에서 In injection period를 4번 반복하여 제작된 InAs quantum dot layer를 buffer로 사용하였으며, QD layer의 밀도는 $1{\mu}m^2$ 당 600개, height가 $6.2\;{\pm}\;2.0\;nm$, width가 $36.1\;{\pm}\;9.2\;nm$ 정도이다. 성장된 $2.8{\mu}m$ 두께의 InSb film의 특성을 분석해 보면 AFM 상에서의 root mean square (rms) roughness는 5.142nm정도이며, electron mobility는 340 K 에서 $41,352cm^2/Vs$, 1.8 K에서는 $4,215cm^2/Vs$ 정도를 나타내었다. 본 실험에서는 다른 실험과는 달리 InAs QD 을 buffer layer로 사용하였으며, silicon기판도 아무런 처리가 되지 않은 (001)기판을 사용하였으므로 기존의 다른 연구 결과와는 차별성을 가진다. 또한 buffer로 사용된 InAs quantum dot layer의 종류를 한 가지로 고정하고 실험을 하였지만 추후 더욱 다양한 밀도와 크기의 quantum dot layer를 적용시키고, 기존의 다른 논문에서 적용된 방법들을 추가로 적용시켜 본다면 mobility값은 더욱 증가할 것으로 생각된다. 이러한 연구를 통해 값이 싸고 구하기 쉬운 silicon기판상에 silicon에 비하여 더 좋은 특성을 갖는 III-V족 화합물 반도체 소자를 구현 할 수 있을 것으로 생각된다.

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Multi-condition optimization and experimental verification of impeller for a marine centrifugal pump

  • Wang, Kai;Luo, Guangzhao;Li, Yu;Xia, Ruichao;Liu, Houlin
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.12 no.1
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    • pp.71-84
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    • 2020
  • In order to improve the performance of marine centrifugal pump, a centrifugal pump whose specific speed is 66.7 was selected for the research. Outlet diameter D2, outlet width b2, blade outlet angle β2, blade wrap φ and blade number z of the impeller were chosen as the variables. The maximum weighted average efficiency and the minimum vibration intensity at the base were calculated as objectives. Based on the Latin Hypercube method, the impeller was numerically optimized. The numerical results show that after optimization, the amplitudes of pressure fluctuation on the main frequency at different monitoring points decrease in varying degrees. The radial force on impeller decreases obviously under off-design flow rates and is more symmetrical during the operation of the pump. The variation of the axial force is relatively small, which has no obvious relationship with the rotating angle of the impeller. The energy performance and vibration experiment was performed for verifying. The test results show that the weighted average efficiency under 0.8Qd, 1.0Qd and 1.2Qd increases by 4.3% after optimization. The maximal vibration intensity at M1-M4 on the pump base reduced from 0.36 mm/s to 0.25 mm/s, decreasing by 30.5%. In addition, the vibration velocities of bracket in pump side and outlet flange also have significant reductions.