• Title/Summary/Keyword: Pseudo-R2

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Characteristics of Phosphate Adsorption using Prepared Magnetic Iron Oxide (MIO) by Co-precipitation Method in Water (공침법에 의해 제조된 Magnetic Iron Oxide (MIO)를 이용한 수중 인 흡착 특성)

  • Lee, Won-Hee;Chung, Jinwook;Kim, Jong-Oh
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.6
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    • pp.609-615
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    • 2015
  • This study was carried out for characterization of MIO synthesized in our laboratory by co-precipitation method and applied isotherm and kinetic models for adsorption properties. XRD analysis were conducted to find crystal structure of synthesized MIO. Further SEM and XPS analysis was performed before and after phosphate adsorption, and BET analysis for surface characterization. Phosphate stock solution was prepared by KH2PO4 for characterization of phosphate adsorption, and batch experiment was conducted using 50 ml conical tube. Langmuir and Freundlich models were applied based on adsorption equilibrium test of MIO by initial phosphate solution. Pseudo first order and pseudo second order models were applied for interpretation of kinetic model by temperature. Surface area and pore size of MIO were found $89.6m^2/g$ and 16 nm respectively. And, the determination coefficient ($R^2$) value of Langmuir model was 0.9779, which was comparatively higher than that of Freundlich isotherm model 0.9340.

STRONG CONVERGENCE OF HYBRID ITERATIVE SCHEMES WITH ERRORS FOR EQUILIBRIUM PROBLEMS AND FIXED POINT PROBLEMS

  • Kim, Seung-Hyun;Kang, Mee-Kwang
    • The Pure and Applied Mathematics
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    • v.25 no.2
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    • pp.149-160
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    • 2018
  • In this paper, we prove a strong convergence result under an iterative scheme for N finite asymptotically $k_i-strictly$ pseudo-contractive mappings and a firmly nonexpansive mappings $S_r$. Then, we modify this algorithm to obtain a strong convergence result by hybrid methods. Our results extend and unify the corresponding ones in [1, 2, 3, 8]. In particular, some necessary and sufficient conditions for strong convergence under Algorithm 1.1 are obtained.

Comparative Evaluation of Methylene Blue and Humic Acids Removal Efficiency Using Rice Husk Derived Biochars and Powdered Activated Carbon (쌀겨 바이오차와 분말 활성탄을 이용한 메틸렌 블루와 휴믹산 제거 효율 비교)

  • Lee, Juwon;Jeong, Eunju;Lee, Jungmin;Lee, Yong-Gu;Chon, Kangmin
    • Journal of Korean Society on Water Environment
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    • v.37 no.6
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    • pp.483-492
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    • 2021
  • This study evaluated the removal efficiencies of methylene blue (MB) and humic acids (HA) using a rice husk (RH) biochar and powdered activated carbon (PAC). The pseudo-second-order model better presented the adsorption of MB and HA onto a RH biochar than the pseudo-first-order model. Furthermore, better description of the adsorption behavior of MB and HA by the Langmuir isotherm model (R2 of the RH biochar: MB = 0.986 and HA = 0.984; R2 of PAC: MB = 0.997 and HA = 0.989) than the Freundlich isotherm model (R2 of the RH biochar: MB = 0.955 and HA = 0.965; R2 of PAC: MB = 0.982 and HA = 0.973) supports the assumption that monolayer adsorption played key roles in the removal of MB and HA using the RH biochar and PAC. Batch experiments were performed on the effects of dosage, temperature, and pH. For all experiments, PAC showed higher efficiencies than RH biochar and MB adsorption efficiencies were higher than those of HA. Adsorption efficiencies increased with increasing amounts of adsorbents and temperature. As the pH increased, adsorption efficiencies of MB were increased while adsorption efficiencies of HA were decreased.

The Removal of Hexavalent Chromium from Aqueous Solutions Using Modified Holly Sawdust: Equilibrium and Kinetics Studies

  • Siboni, M. Shirzad;Samarghandi, M.R.;Azizian, S.;Kim, W.G.;Lee, S.M.
    • Environmental Engineering Research
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    • v.16 no.2
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    • pp.55-60
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    • 2011
  • The removal of hexavalent chromium from aqueous solutions onto modified holly sawdust was studied at varying initial hexavalent chromium concentrations, adsorbent doses, pHs and contact times. The removal of hexavalent chromium from aqueous solutions increased with increasing adsorbent dosage and contact time. The percentage of hexavalent chromium removed from the aqueous solutions decreased with increasing hexavalent chromium concentration and pH of the solution. The kinetics of the adsorption of hexavalent chromium onto modified holly sawdust was analyzed using pseudo first-order and pseudo second-order models. The pseudo second-order model described the kinetics of adsorption of hexavalent chromium. The Langmuir and Freundlich isotherm models were used for modeling of the adsorption equilibrium data. The Langmuir isotherm model well described the equilibrium data for the removal of hexavalent chromium by modified holly sawdust. The obtained maximum adsorption capacity was 18.86 mg/g at pH 7. The results showed that modified holly sawdust can be used as a low cost adsorbent for the treatment of aqueous solutions containing chromium.

Synthesis and Evaluation of N-(2,3-dihydroxypropyl)-N,N-dimethyldodecane-1-amine chloride (N-(2,3-dihydroxypropyl)-N,N-dimethyldodecane-1-amine chloride의 합성과 평가)

  • Cho, Wan-Goo;Choi, Jeong-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.1
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    • pp.23-31
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    • 2008
  • In general, anionic and cationic surfactants are incompatible because their mixtures form insoluble complexes. There are, however, some complexes that are soluble and behave like regular surfactants, specifically like nonionic surfactants, thus named pseudo-nonionic surfactant complexes. Pseudo-nonionic complexes are more effective and efficient than their ionic surfactant components as shown by their equilibrium and dynamic surface tensions and interfacial tensions. They pack at the interface more than their ionic components. Since, pseudo-nonionic complexes show their own characteristics, they can be treated as separate classes of surfactants distinct from ionic and nonionic surfactants. Novel cationic surfactant was synthesized, having the polyhydroxyl group at the head group. We found that aqueous mixtures of our cationic surfactant and usual anionic surfactant(SDS) could form homogeneous solutions even at high concentration. The properties of mixed surfactant solutions were measured. Foam stability, CMC(critical micelle concentration), water hardness tolerance and thickening effect were tested. The foam stability of mixed surfactants was very good and various synergy effects were observed.

PROJECTIONS OF PSEUDOSPHERE IN THE LORENTZ 3-SPACE

  • Birman, Graciela S.;Desideri, Graciela M.
    • Bulletin of the Korean Mathematical Society
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    • v.44 no.3
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    • pp.483-492
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    • 2007
  • In this paper, we study the map projections from pseudo-sphere $S_1^2$ onto the non-lightlike surfaces in the 3-dimensional Lorentzian space, $L^3$, with curvature zero. We show geometrical means and properties of $\mathbb{R}{\times}S_1^1-cylindrical$, $S^1{\times}L-cylindrical$ and $\mathbb{R}{\times}H_0^1-cylindrical$ projections defined on $S_1^2$ to cylinders $\mathbb{R}{\times}S_1^1,\;S^1{\times}L$ and $\mathbb{R}{\times}H_0^1$, respectively, and orthographic and stereographic projections on $S_1^2$ to Lorentzian plane, $L^2$.

A Study of the Output Characteristics of a 1-kW-class Narrow-bandwidth PM Fiber Laser Depending on Its Pumping Structure (펌핑 구조에 따른 1 kW급 협대역 편광 유지 광섬유 레이저의 출력 특성 연구)

  • Kim, Tae Hyoung;Jeong, Seong Mook;Kim, Ki Hyuck;Lee, Sung Hun;Yang, Hwan Seok
    • Korean Journal of Optics and Photonics
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    • v.32 no.4
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    • pp.187-194
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    • 2021
  • This paper presents a study of laser output characteristics. We fabricated a MOPA (master oscillator power amplifier)-type high-power, narrowbandwidth fiber laser with a bidirectional pumping configuration in its main amplifier. As signal beams, light sources with bandwidths of 3 GHz and 10 GHz-phase-modulated through a PRBS (pseudo-random binary sequence)-were used interchangeably. Furthermore, the characteristics of the SBS (stimulated Brillouin scattering) were analyzed using a signal beam with 3 GHz bandwidth, by adjusting the forward to backward pumppower ratio. Moreover, the characteristics of the transverse mode instability were analyzed by adjusting the forward to backward pump-power ratio, using a signal beam with 10-GHz bandwidth. Finally, the output power from 10 GHz bandwidth was amplified to more than 1 kW using a forward to backward pump-power ratio of 1.6. The beam quality M2 was measured to be approximately 1.36, and the optical-to-optical efficiency was 80% at maximum output power.

Biosorption of Methylene Blue from Aqueous Solution using Dried Rhodotorula glutinis Biomass

  • Dae Haeng Cho;Jaesung Lee;Eui Yong Kim
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.273-277
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    • 2023
  • The biosorption of methylene blue (MB) from aqueous solution was investigated using dried Rhodotorula glutinis as the biosorbent. The effects of pH, initial dye concentration, biosorbent dosage, and kinetic studies were determined to obtain valuable information for biosorption. Results indicated that most of the adsorbed MB bound within 30 minutes of contact and the MB adsorption capacity increased from 21.1 to 101.8 mg/g with the initial MB concentration increased from 50 to 300 mg/L. Additionally, the MB adsorption capacity gradually increased from pH 4.0 to 9.0, reaching its peak at an initial pH of 9.0. As the biomass load was increased from 0.25 to 4.0 g/L, the MB removal efficiency increased from 14.1 to 84.5%. The Langmuir model provided the best fit throughout the concentration range, and the maximum adsorption capacity (qmax) and Langmuir constant (b) were determined to be 135.14 mg/g and 0.026 l/mg, respectively. Furthermore, the biosorbent process of R. glutinis was found to follow pseudo-second-order kinetics and the calculated qeq,cal value showed good agreement with the experimental qeq value. Overall, the biosorption of MB by R. glutinis can be characterized as a monolayer, single site type phenomenon, and the rate-limiting step was determined to be the chemical reaction between the adsorbent and the adsorbate.

Equilibrium, Kinetic and Thermodynamic Parameter Studies on Adsorption of Acid Yellow 14 Using Activated Carbon (활성탄을 이용한 Acid Yellow 14 흡착에 대한 평형, 동역학 및 열역학 파라미터의 연구)

  • Lee, Jong Jib
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.255-261
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    • 2016
  • Adsorption experiments of Acid Yellow 14 dye using activated carbon were carried out as function of adsorbent dose, pH, initial concentration, contact time and temperature. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin isotherm model. The experimental data were best represented by Freundlich isotherm model. Base on the estimated Freundlich constant (1/n=0.129~0.212) and Langmuir separation factor ($R_L=0.202{\sim}0.243$), this process could be employed as effective treatment method. The heat of adsorption of Temkin isotherm model was 5.101~9.164 J/mol indicated that the adsorption process followed a physical adsorption. Adsorption kinetics experimental data were modeled using the pseudo-first-order and pseudo-second-order kinetic equation. It was shown that pseudo-second-order kinetic equation could best describe the adsorption kinetics. Base on the negative Gibbs free energy (-4.81~-10.33 kJ/mol) and positive enthalpy (+78.59 kJ/mol) indicate that the adsorption is spontaneous and endothermic process.

Investigation of Pressure Drop for a Pseudo-plastic Fluid Flow in Isosceles Triangle Pipes (이등변삼각형 단면을 갖는 파이프 내의 Pseudo-Plastic 유체유동에 대한 압력강하의 연구)

  • Lee, D.R.
    • Journal of Power System Engineering
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    • v.13 no.2
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    • pp.30-35
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    • 2009
  • Numerical Calculations for dimensionless pressure drop (friction factor times Reynolds number) have been obtained for fully developed laminar flow of MPL(Modified Power Law) fluid in isosceles triangle pipes. The solutions are valid for Pseudoplastic fluids over a wide range from Newtonian behavior at low shear rates through transition region to power law behavior at higher shear rates. The analysis identified a dimensionless shear rate parameter which for a given set of operating conditions specifies where in the shear rate range a particular system is operating, i.e., Newtonian, transition or power law region. The numerical calculation data of the dimensionless pressure drop for the Newtonian and power law regions are compared with previously published asymptotic results presenting within 0.16 % in Newtonian region and 2.98 % in power law region.

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