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http://dx.doi.org/10.9713/kcer.2016.54.2.255

Equilibrium, Kinetic and Thermodynamic Parameter Studies on Adsorption of Acid Yellow 14 Using Activated Carbon  

Lee, Jong Jib (Division of chemical Engineering, Kongju National University)
Publication Information
Korean Chemical Engineering Research / v.54, no.2, 2016 , pp. 255-261 More about this Journal
Abstract
Adsorption experiments of Acid Yellow 14 dye using activated carbon were carried out as function of adsorbent dose, pH, initial concentration, contact time and temperature. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin isotherm model. The experimental data were best represented by Freundlich isotherm model. Base on the estimated Freundlich constant (1/n=0.129~0.212) and Langmuir separation factor ($R_L=0.202{\sim}0.243$), this process could be employed as effective treatment method. The heat of adsorption of Temkin isotherm model was 5.101~9.164 J/mol indicated that the adsorption process followed a physical adsorption. Adsorption kinetics experimental data were modeled using the pseudo-first-order and pseudo-second-order kinetic equation. It was shown that pseudo-second-order kinetic equation could best describe the adsorption kinetics. Base on the negative Gibbs free energy (-4.81~-10.33 kJ/mol) and positive enthalpy (+78.59 kJ/mol) indicate that the adsorption is spontaneous and endothermic process.
Keywords
Acid Yellow 14; dye adsorption; adsorption kinetic; adsorption; thermodynamic parameter;
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Times Cited By KSCI : 3  (Citation Analysis)
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1 Zhao, X., Ma, S. Q. and Lu, G. Q., "VOC Removal: Comparison of MCM-41 with Hydrophobic Zeolites and Activated Carbon," & Fuels, 12(6), 1051-1504(1998).   DOI
2 Yoshida, H., Okamoto, A. and Kataoka, T., "Adsorption of Acid Dye on Cross-Linked Chitosan Fibers: Equilibria," Chem. Eng. Sci. 48(12), 2267-2272(1993).   DOI
3 Fernandes, J., Kiwi, J., Lizama, C. Freer, J., Baeza, J. and Mansilia, H., "Fractoria Experimental Design of Orange II Photocatalytic Discoloration," J. Photochem. Photobiol. A151, 213-219(2002).
4 Samiey, B. and Toosi, A., "Kinetics and Thermodynamics Adsorption of Congo Red on Cellulose," Central Eur. J. Chem., 8, 906-912(2010).
5 Ismadji, S., Sudaryanto, Y., Hartono, S. B., Setiawan, L. E. K. and Ayucitra, A. "Activated Carbon from Char Obtained from Vacuum Pyrolysis of Teak Sawdust: Pore Structure Development and Characterization," Bioresour. Technol. 96, 1364-1369(2005).   DOI
6 Ashraf, M. A., Hussain, M., Mahmood, K., Wajid, A., Alias, M. Y. Y. and Yusoff, I., "Removal of Acid Yellow-17 Dye from Aqueous Solution Using Eco-Friendly Biosorbent," Desalin. Water Treat., 51(22-24), 4530-4545(2013).   DOI
7 Porselvi, E. and Krishnamoorthy, P., "Removal of Acid Yellow by Agricultural Waste Porselvi E," J. Mater. Environ. Sci., 5(2), 408-415(2014).
8 Lun, Y. K., Fung, L. K., Fong, M. S., Kwong, C. W., Nok, N. T. and Xinqing, C., "Assessment of Sericin Biosorbent for Selective Dye Removal," Chin. J. Chem. Eng., 20(3), 426-432(2012).   DOI
9 Malik, P. K., "Use of Activated Carbons Prepared from Sawdust and Rice-husk for Adsorption of Acid Dyes: a Case Study of Acid Yellow 36," Dye. Pig., 56(3), 239-249(2003).   DOI
10 Alkan, M., Demirbas, O. and Dogan, M., "Removal of Acid Yellow 49 from Aqueous Solution by Adsorption," Fresen. Environ Bull., 13(11a), 1112-1121(2004).
11 Iqbal, J. Wattoo, F. H., Wattoo, M. H. S, Malik, R., Tirmizi, S. A., Imran, M. and Ghangro, A. B., "Adsorption of Acid Yellow Dye on Flakes of Chitosan Prepared from Fishery Wastes," Arab. J. Chem., 4, 389-395(2011).   DOI
12 Ciobanu, G., Harja, M., Rusu, L., Mocanu, A. M. and Luca, C., "Acid Black 72 Dye Adsorption from Aqueous Solution by Hydroxyapatite as Low Cost Adsorbent," Korean J. Chem. Eng., 31(6), 1021-1027(2014).   DOI
13 Lee, J. J., "Isotherm, Kinetic and Thermodynamic Characteristics for Adsorption of Congo Red by Activated Carbon," Korean Chem. Eng. Res., 53(1), 1-7(2015).   DOI
14 Durala, M. U., Cavasa, L., Papageorgiouc, S. K. and Katsarosc, F. K., "Methylene Blue Adsorption on Activated Carbon Prepared from Posidonia Oceanica(L.) Dead Leaves: Kinetics and Equilibrium Studies," Chem.l Eng. J., 168, 77-85(2011).   DOI
15 Sivakumar, P. and Palanisamy, P. N., "Adsorption Studies of Basic Red 29 by a Non Conventional Activated Carbon Prepared from Euphorbia Antiquorum L," Int. J. Chem. Tech. Res, 1(3), 502-510(2009).
16 Lee, J. J., "Adsorption Kinetics and Thermodynamics of Adsorption Brilliant Blue FCF Dye onto Coconut Shell Based Activated Carbon," Korean Chem. Eng. Res., 53(3), 309-314(2015).   DOI
17 Ngah, W. S. W. and Hanafiah, M. A. K. M., "Adsorption of Copper on Rubber (Hevea Brasiliensis) Leaf Powder: Kinetic, Equilibrium and Thermodynamic Studies," Biochem. Eng. J., 39, 521-530(2008).   DOI
18 Monika, J., Garg, V. and Kadirvelu. D K., "Chromium (VI) Removal from Aqueous Solution, Using Sunflower Stem Waste," J. Hazard. Mater., 162, 365-372(2009).   DOI
19 Mital, A., "Adsorption Kinetics of Removal of a Toxic Dye, Malachite Green, from Wastewater by Using Hen Feathers," J. Hazard. Mater. B133, 196-201(2006).
20 Sulak, M. T. Demirbas, E. and Kobya, M., "Removal of Astrazon Yellow 7GL from Aqueous Solutions by Adsorption onto Wheat Bran," Bioresour. Technol., 98, 2590-2598(2007).   DOI