• Title/Summary/Keyword: Pre-reforming

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Silver Services Demand and Manpower Supply of the Aging Society in Busan (부산지역 실버서비스 및 관련 인력수요에 대한 요구도)

  • Kim, Jeong-Soon;Jeoung, Ihn-Sook;Kim, Myoung-Soo
    • Journal of Korean Public Health Nursing
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    • v.21 no.2
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    • pp.182-192
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    • 2007
  • Purpose: The objectives of this study were to define basic data for developing silver services related to goods, medical care, finance, leisure and residence. Method: In this cross-sectional study, the subjects were 792 pre-elderly and 382 elderly. The data were collected 2005 by using a structured questionnaire from Aug. 19 to Sep. 5. Data were analyzed using descriptive statistics on the SPSS version 12.0 for windows. Result: The pre-elderly had the intention to use massage chair(36.6%), homecare service(29.8%), national pension(35.9%), sports(48.5%) and personal house(59.5%) in the ares of silver goods, medical care, finance, leisure and residence, respectively. The elderly wanted sphygmomanometer(38.7%), homecare service(27.7%), pocket money from their offspring (40.5%), sports(33.5%), and personal house(74.8%). They wanted manpower in the area of reforming of living place, leisure time and education, counseling of silver goods, and management of finance. Conclusion: Based on this study findings, the pre-elderly are thoroughly established for their future than the elderly. It is important to upgrade the silver services and to prepare the manpower for the pre-elderly and the elderly in the future of the aging society.

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Main Trends for Reforming the Duty of Utmost Good Faith in English Insurance Contracts Law - Focused on the Policyholder's Pre-Contractual Duty in Insurance Contracts for Business (영국 보험계약법 상 최대선의의무에 관한 주요 개혁동향)

  • Shin, Gun-Hoon
    • THE INTERNATIONAL COMMERCE & LAW REVIEW
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    • v.49
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    • pp.257-281
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    • 2011
  • The duty of utmost good faith is found in sections 17-20 of MIA 1906. Critics of the current legal regime on the pre-contractual duty from the viewpoint of the assured, have been concentrated on two points in particular. First, the scope of the duty is so wide that it imposes too high burden on the assured. The second criticism is directed at the remedy, prescribed by the MIA 1906, s.17, against breach of the duty. This article intends to analyse the legal implications of proposals in CP 2007 for reforming pre-contractual duty of utmost good faith of business assured in English insurance contracts law and the problems of proposals. The Law Commissions are proposing four fundamental changes to meet the long-standing criticism and the results of analysis are as following. First, the Law Commissions are proposing a change in the test of constructive knowledge in relation to the duty of disclosure so that a business assured will be obliged to disclose facts which he knows or a reasonable ought to know in the circumstances. Secondly, deviating from the current legal position, the Law Commissions are proposing that if a business assured has made a misrepresentation, but the assured honestly and reasonably believe what it said to be true, the insurer should not have any remedy due to the misrepresentation. The proposal is designed to protect the reasonable expectations of business assured at the pre-contractual stage. Thirdly, the Law Commissions are proposing to change the test for materiality by replacing the "prudent insurer" test by a "reasonable assured" test. The proposed test would focus on the question of what a reasonable assured in the circumstances would think what is relevant to the judgment of the insurer. Finally, the Law Commissions are proposing flexible remedies in case of the breach of the duty. The Law Commissions are proposing no remedy when an assured is acting honestly and reasonably, while avoidance in case of dishonesty. On the other hand, The Law Commissions seem to have an intention to introduce a compensatory remedy in case of negligent breach of the duty.

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FBR CFD Simulation of Steam Methanol Reforming Reaction using Intrinsic Kinetic Data of Copper-impregnated Hydrotalcite Catalyst (구리가 함침된 하이드로탈사이트 촉매의 고유 키네틱 데이터를 이용한 메탄올 수증기 개질반응의 고정층 반응기 CFD 시뮬레이션)

  • Jae-hyeok Lee;Dongil Shin;Ho-Geun Ahn
    • Journal of the Korean Institute of Gas
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    • v.27 no.1
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    • pp.78-85
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    • 2023
  • Fixed-bed reactor Computational Fluid Dynamics (CFD) simulation of methanol steam reforming reaction was performed using the intrinsic kinetic data of the copper-impregnated hydrotalcite catalyst. The activation energy of the copper hydrotalcite catalyst obtained from the previous study results was 97.4 kJ/mol, and the pre-exponential was 5.904 × 1010. Process simulation was performed using the calculated values and showed a similar tendency to the experimental results. And the conversion rate according to the change of the reaction temperature (200 - 450 ℃) and the molar ratio of methanol and water was observed using the intrinsic kinetic data. In addition, mass and heat transfer phenomena analysis of a commercial reactor (I.D. 0.05 - 0.1m, Length 1m) was predicted through axial 2D Symmetry simulation using the power law model of the above kinetic constants.

The Results of the 125 kW External Reforming Type MCFC Stack Operation (125kW 외부개질 용융탄산염 연료전지(ER MCFC) 스택 운전)

  • Lee, Jung-Hyun;Kim, Beom-Joo;Kim, Do-Hyeong;Kang, Seung-Won;Kim, Eui-Hwan;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.5
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    • pp.419-424
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    • 2010
  • The 125kW external reforming (ER) type molten carbonate fuel cell (MCFC) system for developing a commercial prototype has been operated at Boryeong thermal power plant site since the end of 2009. The system consists of 125kW stack with $10,000 cm^2$ effective area, mechanical balance of plant (MBOP) with anode recycle system, and electrical balance of plant (EBOP). The 125kW MCFC stack installed in December, 2009 has been operated from January, 2010 after 20 days pre-treatment. The stack open circuit voltage (OCV) was 214V at initial load operation, which approaches the thermodynamically theoretical voltage. The stack voltage remained stable range from 160V to 180V at the maximum generating power of 120 kW DC. The stack has been operated for 3,270 hours and operated at rated power for 1,200 hours.

Parametric Study of SOFC System Efficiency Under Operation Conditions of Butane Reformer (부탄 개질기 운전조건에 따른 SOFC 시스템 효율에 대한 연구)

  • Kim, Sun-Young;Baek, Seung-Whan;Bae, Gyu-Jong;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.4
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    • pp.341-347
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    • 2010
  • In this study, the efficiency of a solid-oxide fuel cell (SOFC) system with a steam reformer or prereformer was analyzed under various conditions. The main components of the system are the reformer, SOFC, and water boiling heat recovery system. Endothermic and exothermic reactions occur in the reformer and SOFC, respectively. Hence, the thermal management of the SOFC system greatly influences the SOFC system efficiency. First, the efficiencies of SOFC systems with a steam reformer and a prereformer are compared. The system with the prereformer was more efficient than the one with steam reformer due to less heat loss. Second, the system efficiencies under various prereformer operating conditions were analyzed. The system efficiency was a function of the heat requirement of the system. The efficiency increased with an increase in the operating temperature of the prereformer, and the maximum system efficiency was observed at $450^{\circ}C$ for a S/C of 2.0.

Kinetic Investigation of CO2 Reforming of CH4 over Ni Catalyst Deposited on Silicon Wafer Using Photoacoustic Spectroscopy

  • Yang, Jin-Hyuck;Kim, Ji-Woong;Cho, Young-Gil;Ju, Hong-Lyoul;Lee, Sung-Han;Choi, Joong-Gill
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1295-1300
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    • 2010
  • The $CO_2-CH_4$ reaction catalyzed by Ni/silicon wafers was kinetically studied by using a photoacoustic technique. The catalytic reaction was performed at various partial pressures of $CO_2$ and $CH_4$ (50 Torr total pressure of $CO_2/CH_4/N_2$) in the temperature range of 500 - $650^{\circ}C$ in a static reactor system. The photoacoustic signal that varied with the $CO_2$ concentration during the catalytic reaction was recorded as a function of time. Under the reaction conditions, the $CO_2$ photoacoustic measurements showed the as-prepared Ni thin film sample to be inactive for the reaction, while the $CO_2/CH_4$ reactions carried out in the presence of the sample pre-treated in $H_2$ at $600^{\circ}C$ were associated with significant time-dependent changes in the $CO_2$ photoacoustic signal. The rate of $CO_2$ disappearance was measured from the $CO_2$ photoacoustic signal data in the early reaction period of 50 - 150 sec to obtain precise kinetic data. The apparent activation energy for $CO_2$ consumption was determined to be 6.9 kcal/mol from the $CO_2$ disappearance rates. The partial reaction orders, determined from the $CO_2$ disappearance rates measured at various $PCO{_2}'S$ and $PCH{_4}'S$ at $600^{\circ}C$, were determined to be 0.33 for $CH_4$ and 0.63 for $CO_2$, respectively. Kinetic data obtained in these measurements were compared with previous works and were discussed to construct a catalytic reaction mechanism for the $CO_2-CH_4$ reaction over Ni/silicon wafer at low pressures.

Study on Methanol Conversion Efficiency and Mass Transfer of Steam-Methanol Reforming on Flow Rate Variation in Curved Channel (곡유로 채널을 가지는 수증기-메탄올 개질기에서 유량 변화에 따른 메탄올 전환율 및 물질 전달에 관한 연구)

  • Jang, Hyun;Park, In Sung;Suh, Jeong Se
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.3
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    • pp.261-269
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    • 2015
  • In this study, numerical analysis of curved channel steam-methanol reformer was conducted using the computational fluid dynamics (CFD) commercial code STAR-CCM. A pre-numerical analysis of reference model with a cylindrical channel reactor was performed to validate the combustion model of the CFD commercial code. The result of advance validation was in agreement with reference model over 95%. After completing the validation, a curved channel reactor was designed to determine the effects of shape and length of flow path on methanol conversion efficiency and generation of hydrogen. Numerical analysis of the curved-channel reformer was conducted under various flow rate ($10/15/20{\mu}l/min$). As a result, the characteristics of flow and mass transfer were confirmed in the cylindrical channel and curved channel reactor, and useful information about methanol conversion efficiency and hydrogen generation was obtained for various flow rate.

The Effect by Aqueous NH4OH Treatment on Ru Promoted Nickel Catalysts for Methane Steam Reforming (암모니아 용액 처리에 의한 Ru-Ni/Al2O3 촉매의 메탄 수증기 개질 반응에 미치는 영향)

  • Lee, Jung Won;Jeong, Jin Hyeok;Seo, Dong Joo;Seo, Yu Taek;Seo, Yong Seog;Yoon, Wang Lai
    • Applied Chemistry for Engineering
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    • v.17 no.1
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    • pp.87-92
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    • 2006
  • The steam reforming of methane over Ru-promoted $Ni/Al_2O_3$ was carried out. Compared with $Ni/Al_2O_3$, which needs pre-reduction by $H_2$, $Ru/Ni/Al_2O_3$ catalysts exhibited relatively higher activity than conventional $Ni/Al_2O_3$. According to $H_2-TPR$ of reduced or used catalysts and $CH_4-TPR$, it was revealed that the reduction of $RuO_x$ by $CH_4$ decomposition begins at a lower temperature ($220^{\circ}C$) and the reduced Ru facilitates the reduction of NiO, and leads to self-activation. To improve metal dispersion, the catalyst was soaked in 7 M aqueous $NH_4OH$ for 2 h at $45^{\circ}C$ while stirring. As a result, $Ru/Ni/Al_2O_3$ catalysts with aqueous $NH_4OH$ treatment have higher activity, larger metal surface area (by $H_2$-chemisorption), and small particle size (by XRD and XPS). It is noted that the amount of noble metal could be reduced by aqueous $NH_4OH$ treatment.

Nickel Catalysts Supported on Ash-Free Coal for Steam Reforming of Toluene (무회분탄에 분산된 니켈 촉매의 톨루엔 수증기 개질)

  • PRISCILLA, LIA;KIM, SOOHYUN;YOO, JIHO;CHOI, HOKYUNG;RHIM, YOUNGJOON;LIM, JEONGHWAN;KIM, SANGDO;CHUN, DONGHYUK;LEE, SIHYUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.6
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    • pp.559-569
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    • 2018
  • Catalytic supports made of carbon have many advantages, such as high coking resistance, tailorable pore and surface structures, and ease of recycling of waste catalysts. Moreover, they do not require pre-reduction. In this study, ash-free coal (AFC) was obtained by the thermal extraction of carbonaceous components from raw coal and its performance as a carbon catalytic support was compared with that of well-known activated carbon (AC). Nickel was dispersed on the carbon supports and the resulting catalysts were applied to the steam reforming of toluene (SRT), a model compound of biomass tar. Interestingly, nickel catalysts dispersed on AFC, which has a very small surface area (${\sim}0.13m^2/g$), showed higher activity than those dispersed on AC, which has a large surface area ($1,173A/cm^2$). X-ray diffraction (XRD) analysis showed that the particle size of nickel deposited on AFC was smaller than that deposited on AC, with the average values on AFC ${\approx}11nm$ and on AC ${\approx}23nm$. This proved that heteroatomic functional groups in AFC, such as carboxyls, can provide ion-exchange or adsorption sites for the nano-scale dispersion of nickel. In addition, the pore structure, surface morphology, chemical composition, and chemical state of the prepared catalysts were analyzed using Brunauer-Emmett-Taylor (BET) analysis, transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, and temperature-programmed reduction (TPR).

100 kW급 용융탄산염 연료전지 발전시스템 개발

  • Im, Hui-Cheon;Kim, Do-Hyeong;Seo, Hye-Gyeong;Park, Seong-Yeon;An, Gyo-Sang
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.140-148
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    • 2005
  • The molten carbonate fuel cell (MCFC) is endowed with the high potential especially in future electric power generation industry by its own outstanding characteristics. KEPCO (KEPRI) started a 100 kW MCFC system development program in 1993 and has been executed 100kW system develpilot plant successfully completed first phaseopment by 2005 on the basis of successful results of 25kW system development. In this program, the components and mechanical structure for 100 kW stack and system construction were completed on last year and now system pre - commissioning was being executed. A 100 kW MCFC power plant was constructed at the site of Boryeong Thermal Power Plant. A 100 kW MCFC system has characterized as a high pressure operation mode, CO2 recycle, and externally reforming power generation system. The 100 kW MCFC system consisted with stacks which was made by two 50 kW sub-stacks, 90 cells with 6,000 cm2 active area and BOP including a reformer, a recycle blower, a catalytic burner, an inverter, and etc. The system has been operated from 13th of September on this year and produced 50 kW AC under atmospheric pressure condition and expected to operate by the end of this year.

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