• Title/Summary/Keyword: Porosity Content

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Processing of Kaolin-Based Microfiltration Membranes

  • Eom, Jung-Hye;Kim, Young-Wook;Song, In-Hyuck
    • Journal of the Korean Ceramic Society
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    • v.50 no.5
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    • pp.341-347
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    • 2013
  • Kaolin-based membranes with a pore size of 0.30-0.40 ${\mu}m$ were successfully prepared by a simple pressing route using low-cost starting materials, kaolin and sodium borate. The prepared green bodies were sintered at different temperatures ranging between 900 and $1200^{\circ}C$. The sintered membranes were characterized by X-ray diffraction, mercury porosimetry, scanning electron microscopy, and capillary flowmetry. It was observed that the porosity decreased with an increase in both the sintering temperature and the sodium borate content, whereas the flexural strength increased with an increase in both the sintering temperature and the sodium borate content. The air flow rate decreased with an increase in the sodium borate content. The typical porosity, flexural strength, and specific flow rate of the kaolin-based membrane sintered with 5 wt% sodium borate at $1100^{\circ}C$ were 37%, 19 MPa, and $1{\times}10^{-3}L/min/cm^2$, respectively, at a p of 30 psi.

Physical Properties and Friction Characteristics of Fault Cores in South Korea (단층핵의 물리적 특성과 마찰 특성의 상관관계 분석)

  • Moon, Seong-Woo;Yun, Hyun-Seok;Seo, Yong-Seok
    • Economic and Environmental Geology
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    • v.53 no.1
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    • pp.71-85
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    • 2020
  • To understand behavior of fault cores in the field of geotechnical and geological engineering, we present an investigation of the physical properties (breccia and clay contents, unit weight, porosity, and water content) and friction characteristics (internal friction angle and cohesion) of fault cores, in granitic, sedimentary, and volcanic rocks in South Korea. The breccia contents in the fault cores are positively correlated with unit weight and negatively correlated with clay content, porosity, and water content. The inter-quartile ranges of internal friction angles and cohesion calculated from direct shear tests are 16.7-38.1° and 2.5-25.3 kPa, respectively. The influence of physical properties on the friction characteristics of the fault cores was analyzed and showed that in all three rock types the internal friction angles are positively correlated with breccia content and unit weight, and negatively correlated with clay content, porosity, and water content. In contrast, the cohesions of the fault cores are negatively correlated with breccia content and unit weight, and positively correlated with clay content, porosity, and water content.

Influence of Potassium on the Cement Clinker Formation : III. THe State and Formation Mechanism of Unstable Alkali (시멘트 클린커 생성과정에 미치는 Potassium의 영향 III. 불안정 알칼리의 상태 및 생성기구)

  • 서일영;최상홀
    • Journal of the Korean Ceramic Society
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    • v.22 no.3
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    • pp.60-66
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    • 1985
  • The formation mechanism of unstable alkali and its existing states in the clinker were studied. The relation of unstable alkali content vs. other water-soluble components porosity and the distributionof potassium were investigated. The results are as follows :1) Two states of unstable alkali seem to exist in clinker ie compounds of $K_2O-Al_2O_3$ system and free $K_2O$ 2) The content of water-soluble $Al_2O_3$ tends to increase with increase of unstable alkali content, 3) Most of alkalies in clinker are concentrated in liquid phase at high temperature. Therefore it is possible to make various $K_2O-Al_2O_3$ system compounds according to the content of $K_2O$ in the liquid phase of clinker. In this experiment we found out a $K_2O-Al_2O_3$ compound of high $Al_2O_3$ content (34%) and high $K_2O$ content (33%) in clinker with 1.09% unstable alkali. 4) The porosity of clinker tends to increase with increase of unstable alkali content. 5) The amount of trapped alkali vapor may increase in closed pore in the clinker with high alkali and low $SO_3$ condecent. Therefore free $K_2O$ is the condensed alkali on the wall of closed pore in the clinker.

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Effect of Microstructure on Mechanical and Electrical Properties in Ni-YSZ of Anode Supported SOFC (연료극 지지체식 고체산화물 연료전지의 기계적 및 전기적 특성에 미치는 Ni-YSZ의 미세구조의 영향)

  • Choi, Mi-Hwa;Choi, Jin-Hyeok;Lee, Tae-Hee;Yoo, Young-Sung
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.592-598
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    • 2011
  • Electrode of solid oxide fuel cell must have sufficient porosity to allow gas transport to the interface with electrolyte effectively but high porosity has a negative impact on structural stability in electrode support. Thus, the upper limit of porosity is based on consideration of mechanical strength of electrode. In this study, the effect of microstructure of Ni-YSZ anode supported SOFC on the mechanical and electrical property was investigated. LSCF composite cathode and 8YSZ electrolyte were used. The porosity of the anode was modified by the amount of graphite powder and added graphite contents were 24, 18, 12 vol%, respectively. The higher the porosity, the better the electrical performance, $P_{max}$. While the flexural strength decreased with increasing the amount of graphite. But the rate of increase in electrical performance and the rate of decrease in mechanical strength were not directly proportional to amount of graphite. The optimum graphite content incorporating both electrical and mechanical performance was 18 vol%.

Fabrication and Characteristics of Anode-Supported Tube for Solid Oxide Fuel Cell (습식법에 의한 고체산화물 연료전지용 연료극 지지체관의 제조 및 특성 연구)

  • Kim, Eung-Yong;Song, Rak-Hyeon;Im, Yeong-Eon
    • Korean Journal of Materials Research
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    • v.10 no.10
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    • pp.659-664
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    • 2000
  • To develop anode-supported tubular cell with proper porosity, we have investigated the anode substrate and t the electrolyte-coated anode tube. The anode substrate was manufactured as a function of carbon content in the range of 20 to 50 vol.%. As the carbon COntent increased, the porosity of the anode substrate increased slightly and the carbon c content with proper porosity is found to be 30 vol.%. The anode-supported tube was fabricated by extrusion process a and the electrolyte layer was coated on the anode tube by slurry coating process. The anode-supported tube was cofired successfully at $^1400{\circ}C$ in air. The porosity of the anode tube was 35%. From the gas permeation test, the anode t tube was found to be porous enough for gas supply. On the other hand, the anode-supported tube with electrolyte layer indicated a very low gas permeation rate. This means that the coated electrolyte was dense.

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Effect of Packing Characteristics on the sintering Propertiesof Pyrophyllite (랍석분쇄물의 충전성이 그 소결성에 미치는 영향)

  • 지응업;최상욱;류태원
    • Journal of the Korean Ceramic Society
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    • v.14 no.4
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    • pp.236-241
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    • 1977
  • Three kinds of specimen, consisting of the graded pyrophyllite particles alone, a substituent of 8 percent fire clay for the finer portion ($F_2$) of it, and 0.8 percent inorganic binder-added composite were prepared under the following conditions respectively; moisture content=4.5~5.0%, forming pressure=250kg/$\textrm{cm}^2$ and sintering temperature=1, 000~1, 30$0^{\circ}C$. The various properties such as modulus of rupture, apparent porosity, bulk specific gravity, pore size and pore distributiion were measured in order to collaborate with sintering phenomena. The results obtained are as follows: (1) Apparent porosity isgradually decreased with rising the sintering temperature to 1, 25$0^{\circ}C$. (2) The binder-added specimen showed the lowest value in porosity. (3) The optimum sintering temperature of specimens was considered to be 1, 25$0^{\circ}C$. (4) The wider differences between pore volumes of specimens could be obtained by method of mercurypenetration porosimeter than by the conventional method for porosity.

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Study on the Improvement of Paper Sludge Dewatering by Adding Wastepaper Powders (고지 분말 첨가에 따른 제지 슬러지의 탈수성 개선에 관한 연구)

  • 이성호;임택준;조준형
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.2
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    • pp.47-53
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    • 2002
  • Three types of sludges including printing paper, newsprint and tissue paper were prepared at 5% concentration for filtration-expression operations. Filtration-expression characteristics of sludge were measured in different pressure and wastepaper powder dosage. Specific filtration resistance and porosity were calculated with theoretical formula. Higher pressure increased the progresses of filtration and expression while it decreased porosity. The addition of 5% wastepaper powder more accelerated the progresses of filtration and expression than that of 10% wastepaper powder. The lowest porosity value was also measured at 5% dosage of wastepaper powder. The decrease of porosity implied the decrease of moisture content in cake. The results indicated that dewatering of sludge was efficient in high pressure and 5% dosage of wastepaper powder.

Fabrication and Physical Properties of Honeycomb Type Cordierite Ceramic Filter Using Fly-Ash (플라이 애쉬를 이용한 코디어라이트 세라믹 하니컴 필터 제조 및 물성)

  • Kim, Sung-Jin;Bang, Hee-Gon;Park, Sang-Yeup
    • Journal of the Korean Ceramic Society
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    • v.43 no.6 s.289
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    • pp.351-357
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    • 2006
  • The fabrication process of the honeycomb filter was investigated using synthesized cordierite with the addition of pore former and extrusion additives (either organic matter or graphite). Also, the effect of additives on the resultant properties of honeycomb filter such as porosity, thermal expansion coefficient and mechanical strength were investigated. With increasing the organic matter up to 10 wt%, porosity was increased but compressive strength was decreased. With increasing the graphite content, however, both porosity and compressive strength were increased. The specimen with an optimum processing condition (C-17A30G, sintering at $1150^{\circ}C$) was demonstrated 59% in porosity, 69 MPa in compressive strength, and $2.4{\times}10^{-6}/^{\circ}C\;(25{\sim}1000^{\circ}C$) in thermal expansion coefficient, which physical properties are appropriate for the honeycomb filter applications.

Porosity Development on Activation of Char from Dry and Wet Babbool Wood

  • Manocha, Satish;Chauhan, Vanraj B.;Manocha, L.M.
    • Carbon letters
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    • v.3 no.3
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    • pp.133-141
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    • 2002
  • It is well known that the porosity and adsorption capacity in a carbon depends on the nature of precursor, pyrolysis and activation conditions and the ash content. The studies on carbon prepared from the dry and wet babbool wood were under taken to ascertain the effect of initial state of precursor on the development of porosity in the resulting activated carbon. The characterization and adsorption studies carried out shows the presence of mainly mesoporosity in the carbon prepared from dry wood while more of microporosity was observed in the activated carbon prepared from wet wood. The results on porosity in both the cases have been compared and correlated with their processing conditions.

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Drying Characteristics and Physicochemical Properties of Semi-Dried Restructured Sausage Depend on Initial Moisture Content

  • Kim, Dong-Hyun;Kim, Yea Ji;Shin, Dong-Min;Lee, Jung Hoon;Han, Sung Gu
    • Food Science of Animal Resources
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    • v.42 no.3
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    • pp.411-425
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    • 2022
  • Semi-dried restructured sausages are restructured meat products with a high nutritional and economic value. However, excessively long drying times can have negative effects on the energy consumption, texture, and sensory properties of semi-dried restructured sausages. The objective of this study was to investigate the effects of different water contents on the drying and physicochemical characteristics of semi-dried restructured sausages. Sausages were prepared with different initial moisture contents (0%-50%) and drying time (0-580 min). The drying characteristics, including the drying rate, effective moisture diffusivity, and water activity of sausage were significantly improved as the initial moisture content was increased. When the initial moisture content of the sausage was 50%, physicochemical properties, such as color, porosity, shear force, and volatile basic nitrogen, were improved the most along with the decreased drying time. Scanning electron microscopy data showed greater porosity and pore size in sausages with the increase of initial moisture content. Collectively, our data suggest that an increase in the initial moisture content of semi-dried restructured sausages improves their drying characteristics and physicochemical properties.