Browse > Article
http://dx.doi.org/10.4191/kcers.2013.50.5.341

Processing of Kaolin-Based Microfiltration Membranes  

Eom, Jung-Hye (Functional Ceramics Laboratory, Department of Materials Science and Engineering, The University of Seoul)
Kim, Young-Wook (Functional Ceramics Laboratory, Department of Materials Science and Engineering, The University of Seoul)
Song, In-Hyuck (Engineering Ceramics Group, Korea Institute of Materials Science)
Publication Information
Abstract
Kaolin-based membranes with a pore size of 0.30-0.40 ${\mu}m$ were successfully prepared by a simple pressing route using low-cost starting materials, kaolin and sodium borate. The prepared green bodies were sintered at different temperatures ranging between 900 and $1200^{\circ}C$. The sintered membranes were characterized by X-ray diffraction, mercury porosimetry, scanning electron microscopy, and capillary flowmetry. It was observed that the porosity decreased with an increase in both the sintering temperature and the sodium borate content, whereas the flexural strength increased with an increase in both the sintering temperature and the sodium borate content. The air flow rate decreased with an increase in the sodium borate content. The typical porosity, flexural strength, and specific flow rate of the kaolin-based membrane sintered with 5 wt% sodium borate at $1100^{\circ}C$ were 37%, 19 MPa, and $1{\times}10^{-3}L/min/cm^2$, respectively, at a p of 30 psi.
Keywords
Membranes; Clay; Processing; Porosity; Permeability;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
연도 인용수 순위
1 D.-S. Bae, D.-S. Cheong, K.-S. Han, and S.-H. Choi, "Fabrication and Microstructure of $Al_2O_3/TiO_2$ Composite Membranes with Ultrafine pores," Ceram. Int., 24, 25-30 (1998).   DOI   ScienceOn
2 J. M. Benito, A. Conesa, F. Rubio, and M. A. Rodriguez, "Preparation and Characterization of Tubular Ceramic Membranes for Treatment of Oil Emulsions," J. Eur. Ceram. Soc., 25 [11] 1895-903 (2005).   DOI   ScienceOn
3 G. Pugagzhenthi, S. Sachan, N. Kishore, and A. Kumar, "Separation of Chromium (VI) using Modified Ultrafiltration Charged Carbon Membrane and its Mathematical Modeling," J. Membr. Sci., 254 [1-2] 229-39 (2005).   DOI   ScienceOn
4 T. B. Kim, S. Y. Choi, and G. D. Kim, "Characterization of Ceramic Composite-Membranes Prepared by TEOS-PEG Coating Sol," J. Kor. Ceram. Soc., 42 [3] 165-70 (2005).   과학기술학회마을   DOI   ScienceOn
5 P. K. Lin and D. S. Tsai, "Preparation and Analysis of a Silicon Carbide Composite Membrane," J. Am. Ceram. Soc., 80 [2] 365-72 (1997).
6 Y. Dong, X. Feng, D. Dong, S. Wang, J. Yang, J. Gao, X. Liu, and G. Meng, "Elaboration and Chemical Corrosion Resistance of Tubular Macro-Porous Cordierite Ceramic Membrane Supports," J. Membr. Sci., 304 [1-2] 65-75 (2007).   DOI   ScienceOn
7 S. Emani, R. Uppsluri, and M. K. Purkait, "Preparation and Characterization of Low Cost Ceramic Membranes for Mosambi Juice Clarification," Desalination, 317, 32-40 (2013).   DOI   ScienceOn
8 J. H. Eom, Y.-W. Kim, and I. H. Song, "Effects of the Initial ${\alpha}$-SiC Content on the Microstructure, Mechanical Properties, and Permeability of Macroporous Silicon Carbide Ceramics," J. Eur. Ceram. Soc., 32 [6] 1283-90 (2012).   DOI   ScienceOn
9 S. Ding, Y. Zeng, and D. Jiang, "Gas Permeability Behavior of Mullite-Bonded Porous Silicon Carbide Ceramics," J. Mater. Sci., 42, 7171-75 (2007).   DOI
10 P. Monash and G. Pugazhenthi, "Effect of $TiO_2$ Addition on the Fabrication of Ceramic Membrane Supports: A Study on the Separation of Oil Droplets and Bovine Serum Albumin (BSA) from its Solution," Desalination, 279 [1-3] 104-14 (2011).   DOI   ScienceOn
11 M. Kazemimoghadam and T. Mohammadi, "Preparation of Nano Pore Hydroxysodalite Zeolite Membranes using of Kaolin Clay and Chemical Sources," Desalination, 278 [1-3] 438-42 (2011).   DOI   ScienceOn
12 M. Abbasi, M. Mirfendereski, M. Nikbakht, M. Golshenas, and T. Mohammadi, "Performance Study of Mullite and Mullite-Alumina Ceramic MF Membranes for Oily Wastewater Treatment," Desalination, 259 [1-3] 169-78 (2010).   DOI   ScienceOn
13 G. Chen, H. Qi, W. Xing, and Xu, "Direct Preparation of Macroporous Mullite Supports for Membranes by in situ Reaction Sintering," J. Membr. Sci., 318 [1-2] 38-44 (2008).   DOI   ScienceOn
14 K. Y. Lim, Y.-W. Kim, and I. H. Song, "Porous Sodium Borate-Bonded SiC Ceramics," Ceram. Int., 39, 6827-34 (2013).   DOI   ScienceOn
15 B. K. Nandi, R. Uppaluri, and M. K. Purkait, "Identification of Optimal Membrane Morphological Parameters During Microfiltration of Mosambi Juice using Low Cost Ceramic Membranes," LWT-Food Sci. Technol., 44 [1] 214-23 (2011).   DOI   ScienceOn
16 D. Vasanth, R. Uppaluri, and G. Pugazhenthi, "Influence of Sintering Temperature on the Properties of Porous Ceramic Supports Prepared by Uniaxial Dry Compaction Method using Low Cost Raw Materials for Membrane Applications," Sep. Sci. Technol., 46, 1241-49 (2011).   DOI   ScienceOn
17 S. Khemakhem, A. Larbot, and R. Ben Amar, "New Ceramic Microfiltration Membranes from Tunisian Natural Materials: Application for the Cuttlefish Effluents Treatment," Ceram. Int., 35, 55-91 (2009).   DOI   ScienceOn
18 J. H. Eom, Y.-W. Kim, I. H. Song, and H. D. Kim, "Microstructure and Properties of Porous Silicon Carbide Fabricated by Carbothermal Reduction and Subsequent Sintering Process," Mater. Sci. Eng. A, 464, 129-34 (2007).   DOI   ScienceOn
19 S. Kroll, L.Treccani, K. Rezwan, and G. Grathwohl, "Development and Characterization of Functionalized Ceramic Micro-tubes for Bacteria Filtration," J. Membr. Sci., 365 [1-2] 447-55 (2010).   DOI   ScienceOn
20 L. L. O. Silva, D. C. L. Vasconcelos, E. H. M. Nunes, L. Caldeira, V. C. Costa, A. P. Musse, S. A. Hatimondi, J. F. Nascimento, W. Grava, and W. L. Vasconcelos, "Processing, Structural Characterization and Performance of Alumina Supports used in Ceramic Membranes," Ceram. Int., 38, 1943-49 (2012).   DOI   ScienceOn
21 J. Cui, X. Zhang, H. Liu, S. Liu, and K. L. Yeung, "Preparation and Application of Zeolite/Ceramic Microfiltration Membranes for Treatment of Oil Contaminated Water," J. Membr. Sci., 325 [1] 420-26 (2008).   DOI   ScienceOn
22 F. Bouzerara, A. Harabi, S. Achour, and A. Larbot, "Porous Ceramic Supports for Membranes Prepared from Kaolin and Doloma Mixtures," J. Eur. Ceram. Soc., 26 [9] 1663-71 (2006).   DOI   ScienceOn
23 M. R. Weir, E. Rutinduka, C. Detellier, C. Y. Feng, Q. Wang, T. Matsuura, and R. LeVanMao, "Fabrication, Characterization and Preliminary Testing of All-Inorganic Ultrafiltration Membranes Composed Entirely of a Naturally Occurring Sepiolite Clay mineral," J. Membr. Sci., 182 [1-2] 41-50 (2001).   DOI   ScienceOn
24 S. Khemakhem, A. Larbot, and R. B. Amara, "Study of Performances of Ceramic Microfiltration Membrane from Tunisian Clay Applied to Cuttlefish Effluents Treatment," Desalination, 200 [1-3] 307-09 (2006).   DOI   ScienceOn
25 N. Saffaj, M. Persin, S. A. Younsi, A. Albizan, M. Cretin, and A. Larbot, "Elaboration and Characterization of Micro-Filtration and Ultra-Filtration Membranes Deposited on Raw Support Prepared from Natural Moroccan Clay: Application to Filtration of Solution Containing Dyes and Salts," Appl. Clay Sci., 31 [1-2] 110-19 (2006).   DOI   ScienceOn
26 D. Vasanth, G. Puggazhenthi, and R. Uppaluri, "Fabrication and Properties of Low Cost Ceramic Microfiltration Membranes for Separation of Oil and Bacteria from its Solution," J. Membr. Sci., 379 [1-2] 154-63 (2011).   DOI   ScienceOn
27 X. Ding, Y. Fan, and N. Xu, "A New Route for the Fabrication of $TiO_2$ Ultrafiltration Membranes with Suspension Derived from a Wet Chemical Synthesis," J. Membr. Sci., 270 [1-2] 179-86 (2006).   DOI   ScienceOn
28 I. M. Kwon, I. H. Song, Y. J. Park, J. W. Lee, H. S Yun, and H. D. Kim, "The Synthesis and Pore Property of Hydrogen Membranes Derived from Polysilazane as Inorganic Polymer," J. Kor. Ceram. Soc., 46 [5] 462-66 (2009).   과학기술학회마을   DOI   ScienceOn
29 B. Michen, A. Diatta, J. Fritsch, C. Aneziris, and T. Graule, "Removal of Colloidal Particles in Ceramic Depth Filters Based on Diatomaceous Earth," Sep. Purif. Technol., 81, 77-87 (2011).
30 J. H. Eom, Y.-W. Kim, S. S. Lee, and D. H. Jeong, "Processing and Vermiculite-silica Composites with Prefer-Oriented Rod Like Pores," J. Kor. Ceram. Soc., 49 [4] 347-51 (2012).   과학기술학회마을   DOI   ScienceOn
31 S. Vercaluteren, K. Keizer, E. F. Vansant, J. Luyten, and R. Leysen, "Porous Ceramic Membranes: Preparation, Transport Properties and Applications," J. Porous Mater., 5, 241-58 (1998).   DOI   ScienceOn
32 R. D. Colle, C. A. Fortulan, and S. R. Fontes, "Manufacture and Characterization of Ultra and Microfiltration Ceramic Membranes by Isostatic Pressing," Ceram. Int., 37, 1161-68 (2011).   DOI   ScienceOn
33 Y. H. Wang, X. Q. Liu, and G. Y. Meng, "Dispersion and Stability of 8 mol.% Yttria Stabilized Zirconia Suspensions for Dip-Coating Filtration Membranes," Ceram. Int., 33, 1025-31 (2007).   DOI   ScienceOn
34 K. A. Defriend, M. R. Wiesner, and A. R. Barron, "Alumina and Aluminate Ultrafiltration Membranes Derived Alumina Nanoparticles," J. Membr. Sci., 224 [1-2] 11-28 (2003).   DOI   ScienceOn
35 H. Qi, Y. Fan, W. Xing, and L. Winnubst, "Effect of $TiO_2$ Doping on the Characteristics of Macroporous $Al_2O_3/TiO_2$ Membrane Supports," J. Eur. Ceram. Soc., 30 [6] 1317-25 (2010).   DOI   ScienceOn