• Title/Summary/Keyword: Pores

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Nonhomogeneity of the Electrical Properties with Deposition Position in an ITO Thin Film Deposited under a Given R.F. Magnetron Sputtering Condition (동일 증착 조건의 스퍼터링에 의해서 제작된 Indium Tin 산화물 박막의 증착위치에 따른 전기적 특성의 불균질성)

  • 유동주;최시경
    • Journal of the Korean Ceramic Society
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    • v.38 no.11
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    • pp.973-979
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    • 2001
  • Tin-doped indium oxide (ITO) thin films were deposited using r.f. magnetron reactive sputtering and the electrical properties, such as the resistivity, carrier concentration and mobility, were investigated as a function of the sample position under a given magnetron sputtering condition. The nonhomogeneity of the electrical properties with the sample position was observed under a given magnetron sputtering condition. The resistivity of ITO thin film on the substrate which corresponded to the center of the target had a minimum value, 2∼4$\times$10$\^$-4/$\Omega$$.$cm, and it increased symmetrically when the substrate deviated from the center. The density measurement result also showed that ITO thin film deposited at the center has a maximum density of 7.0g/cm$^3$, which was a relative density of about 97%, and the density decreased symmetrically as the substrate deviated from the center. The nonhomogeneity of electrical properties with the deposition position could be explained with the incidence angle of the source beam alpha, which is related with an atomic self-shadowing effect. It was confirmed experimentally that the density in film affect both the carrier mobility and the conductivity. In the case where the density of ITO thin film is 7.0g/cm$^3$, the magnitude of the mean free path was identical with that of the grain size(the diameter of column). However, in the other cases, the mean free path was smaller than the grain size. These results showed that the scattering of the free electrons at the grain boundary is the major factor for the electrical conduction in ITO thin films having a high density, and there exists other scattering sources such as vacancies, holes, or pores in ITO thin films having a low density.ing a low density.

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Properties of Extracts from Extruded Root and White Ginseng at Different Conditions (압출성형 공정변수에 따른 건조수삼과 백삼 압출성형물의 침출속도 및 침출물 특성)

  • Kim, Bong-Soo;Ryu, Gi-Hyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.2
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    • pp.306-310
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    • 2005
  • The comparison in release rate constant and properties of extracts from extruded raw ginseng and extruded white ginseng was conducted to apply extrusion process for manufacturing of released ginseng tea bag. Dry raw ginseng and white ginseng powder were extruded at 20∼30% moisture content and 200∼300 rpm by using an experimental twin-screw extruder. Browness and redness (both indicated the releasing of saponin and ginsenosides) were increased with the increase in the screw speed and the decrease of moisture content. Crude saponin and water solubility index (WSI) of both ginseng also share the same behaviour against the level of screw speed and moisture content, as well as browness and redness. The particle size effects of extruded raw ginseng at 20% and 28% moisture content on absorbance of released extract at 260 up to 560 nm, WSI, and water absorption index were determined. While particle size decreased from 800∼1000 nm to 200∼500 nm, absorbance and WSI are decreased. Absorbance and WSI shown increasing level while moisture content was decreased. In conclusion, the formation of pores by expansion and disruption of cell wall in extrusion cooking were obviously responsible to increase the amount of released extract of extruded ginseng and its WSI as well. The extrusion process turns out be the efficient process for manufacturing of commercial ginseng tea product than those of other thermal processes.

A Proposal of a Model for the Generation of Weathered Residual Soils (풍화잔류토의 생성모델의 제안)

  • Min Tuk-Ki;Lee Wan-Jin
    • Journal of the Korean Geotechnical Society
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    • v.20 no.9
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    • pp.47-56
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    • 2004
  • A new fragmentation model, called the GRS (the generation model of weathered residual soils) model, was proposed in this study, This model could identify the formation of a residual soil. This model is based on the phenomena that as the soil was weathered more highly, soil particles were smaller and pores were more expanded simultaneously. The possibility of fragmentation, $P_F,$ which was based on the fractal theory, was introduced in this model. There were some fundamental notions in the GRS model that soil particles were generated as the rock is fragmented, and the fragmentation of the rock was performed step by step. The $P_F,$ of the rock was not constant at each fragmentation steps. As a result of application on the GRS model, there were more residue where $P_{Fi}s$ were small at any particle size. There was a S-shape of PSD curve at the concave shape of $P_{Fi},$ and the PSD curve goes to a gaped graded curve at the convex shape of $P_{Fi}.$ The shape of PSD curve was concave in the case of small $P_{Fi}s.$ The value of $P_{Fi}$ increased with the coefficient of uniformity $(C_u)$ and the fragmentation fractal dimension $(D_r),$ but had no relation with the coefficient of gradation $(C_C)$.

Synthesis of ZSM-5 on the Surface of Foam Type Porous SiC Support (폼 형태의 다공성 탄화규소 지지체 표면 위에 ZSM-5 합성)

  • Jung, Eunjin;Lee, Yoon Joo;Won, Ji Yeon;Kim, Younghee;Kim, Soo Ryong;Shin, Dong-Geun;Lee, Hyun Jae;Kwon, Woo Teck
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.425-430
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    • 2015
  • ZSM-5 crystals grew by hydrothermal synthesis method on the surface of foam type porous silicon carbide ceramics which fabricated by polymer replica method. Oxide layer was developed on the surface of the porous silicon carbide ceramics to induce growth of ZSM-5 from the surface. In this study, hydrothermal synthesis was carried out for 7 h at $150^{\circ}C$ using TEOS, $Al(NO_3){\cdot}9H_2O$ and TPAOH as raw materials in the presence of the porous silicon carbide ceramics. X-ray Powder Diffraction (XRD) and Scanning Electron Microscope (SEM) analyses were confirmed $1{\sim}3{\mu}m$ sized ZSM-5 crystals have grown on the surface of porous silicon carbide ceramics. BET data shows that small pores about $10{\AA}$ size drastically enhanced and surface area increased from $0.83m^2/g$ to $30.75m^2/g$ after ZSM-5 synthesis on the surface of foam type porous silicon carbide ceramics.

Electrochemical Properties of Activated Carbon Supecapacitor Containing Poly(acrylonitrile) Nonwoven Separator Coated by a Hydrogel Polymer Electrolyte (Poly(acrylonitrile) 부직포 분리막에 코팅된 하이드로겔 고분자 전해질을 포함하는 활성탄 수퍼커패시터 특성)

  • Latifatu, Mohammed;Ko, Jang Myoun;Lee, Young-Gi;Kim, Kwang Man;Jo, Jeongdai;Jang, Yunseok;Yoo, Jung Joon;Kim, Jong Huy
    • Korean Chemical Engineering Research
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    • v.51 no.5
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    • pp.550-555
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    • 2013
  • A hydrogel electrolyte consisting of potassium poly(acrylate) (PAAK) (3 wt%) in 6 M KOH aqueous solution is coated on poly(acrylonitrile) nonwoven separator to examine high-rate characteristics of activated carbon supercapacitor adopting the separator. The hydrogel is homogeneously coated on the surface pores of the nonwoven separator. The electrolyte uptake of the PAAK hydrogel maintains for 24 days higher than 230% and the coated separator shows slightly lower ionic conductivity ($2.9{\times}10^{-2}Scm^{-1}$) than that ($3.6{\times}10^{-2}Scm^{-1}$) of using 6 M KOH only. The activated carbon supercapacitor adopting the coated separator shows a specific capacitance higher than $27Fg^{-1}$ at $1000mVs^{-1}$ and a retention ratio higher than 97% after the 1000th cycle. This is due to strong interfacial contact of coated hydrogel electrolyte between the activated carbon electrode and the nonwoven separator.

Immuno-chromatographic Analysis for HPV-16 and 18 E7 Proteins as a Biomarker of Cervical Cancer Caused by Human Papillomavirus

  • Kim, Joo-Ho;Cho, Il-Hoon;Seo, Sung-Min;Kim, Ji-Sook;Oh, Kyu-Ha;Kang, Heun-Soo;Kim, In-Gyu;Paek, Se-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.2999-3005
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    • 2009
  • Among the more than 120 different types of human papillomavirus (HPV), types 16 and 18 have been known to be high risk agents that cause cervical cancer. We examined, in an immuno-chromatographic analysis, the potential of using the early gene product, E7 protein, as a diagnostic marker of cervical cancer caused by HPV. We developed monoclonal antibodies specific to HPV-16 and 18 E7 proteins that were produced from bacterial cells using gene recombinant technology. For each E7 protein, the optimal antibody pair was selected using the immuno-chromatographic sandwichtype binding system based on the lateral flow through membrane pores. Under these conditions, this rapid testing assay had a detection capability as low as 2 ng/mL of E7 protein. Furthermore, since viral analysis required the host cell to be lysed using chemicals such as detergents, it was possible that the E7 protein was structurally damaged during this process, which would result in a decrease in detection sensitivity. Therefore, we examined the detrimental effects caused by different detergents on the E7 protein using HeLa cells as the host. In these experiments, we found that the damage caused by the detergent, nonylphenylpolyethylene glycol (NP-40), was minimal relative to Triton X-100 commonly used for the cell lysis. Temperature also affected the stability of the E7 protein, and we found that the E7 protein was stabilized at 4$^{\circ}C$ for about 2 h, which was 4 times longer than at room temperature. Finally, a HPV-infected cervical cancer cell line, which was used as a real sample model, was treated using the optimized conditions and the presence of E7 proteins were analyzed by immuno-chromatography. The results of this experiment demonstrated that this rapid test could specifically detect HPV-infected samples.

Ultrastructural Characteristics of Antennal Sensilla and Hair-pencils on the Cotton Caterpillar, Palpita indica (Lepidoptera: Pyralidae) Using Scanning Electron Microscope (주사전자현미경을 이용한 목화바둑명나방의 더듬이 감각기와 꼬리털의 외부 형태적 특징)

  • Lee, Dae-Hong;Kang, Myong-Ki;Lee, Hee-Jin;Seok, Hee-Bong;Park, Sun-Nam;Kang, Eun-Jin;Seo, Mi-Ja;Yu, Yong-Man;Youn, Young-Nam
    • Korean journal of applied entomology
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    • v.46 no.2
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    • pp.183-191
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    • 2007
  • The external ultrastructural morphology and distribution of antennal sensilla and hair-pencils of Palpita indica (Saunder) were examined by scanning electron microscopy. The antennal flagellum of male and female has six types of sensilla: long trichodea, short trichodesa, chaetica, coeloconicum around spines, camaniformia and styloconica. There are sexual differences in antennae of P. indica. The female antenna has a coeloconicum sensillum without spines nearby the long trichodea sensilla on ninth flagellomere. Otherwise, auricillica sensilla are distribute on the basal segment of male antenna. These structures are not showed in the female antenna. There are a lot of pores on the hair tufts of the male hair-pencils.

Pre-treatment condition and Curing method for Fabrication of Al 7075/CFRP Laminates (Al 7075/CFRP 적층 복합재료 제조를 위한 전처리 조건과 경화방법 연구)

  • 이제헌;김영환
    • Composites Research
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    • v.13 no.4
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    • pp.42-53
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    • 2000
  • A study has been made to establish an optimum condition in the surface treatment and curing method that is important for the fabrication of Al 7075/CFRP laminates. PAA(Phosphoric Acid Anodizing) provided a good adhesive strength and FPL(Sulfuric / Sodium Dichromate Acid Etching) had a similar adhesive strength with PAA. On the other hand, the poor adhesive strength was shown on vapor degrease and CAA(Chromic Acid Anodizing). By using the atomic force microscope(AFM), it was found that the PAA oxide surface obviously had a greater degree of microroughness as compared to vapor degrease, CAA and FPL treated surfaces. These results support the concept of a mechanical interlocking of the adhesive with-in the oxide pores as the predominant adhesion mechanism. In curing methods, the adhesive strength of co-curing method was higher than that of secondary curing method. With respect to stability of specimen shape, the secondary curing method was better than co-curing method. DMA(Dynamic Mechanical Analysis) test revealed $T_g$ in curing times over 60 min is nearly same, so it is estimated they will have similar degree of curing and joint durability in using FM300M adhesive film.

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The Prototype Study of Resistivity and Porosity Measurement for the Samples Collected Near Marine Hydrothermal Deposit (해저열수광상 주변 암석 시료의 공극률과 전기비저항 측정 기초실험)

  • Lee, Sang-Kyu;Lee, Seong-Kon
    • Geophysics and Geophysical Exploration
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    • v.13 no.4
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    • pp.378-387
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    • 2010
  • We present the results of laboratory measurement of porosity and electrical resistivity for the samples collected near marine hydrothermal deposit to provide fundamental perspective of physical properties for future electromagnetic survey. The rock cores are sampled from the host rock, pumice, hydrothermal altered zone, and chimney. These samples are featured as easily brittle, rough surface with large pores, having components easily solvable in the water. We suggest systematic approach for measuring weights, volumes of core samples to calculate density and porosity. Measurements reveal that the resistivities of black host rock, gray host rock, pumice and chimney are 102, 39, 11, 0.1 ohm-m, respectively, when the core samples are saturated with saline water of $32,000\;{\mu}S$/cm (0.5 ohm-m) at temperature of $2.5^{\circ}C$ and these correspond to the factors of 5 for sea water, 110 for pumice and 390~1020 for host rocks with respect to the resistivity of chimney. We also confirm that resistivity of rock samples saturated with water decrease with temperature linearly over the temperature range of $20{\sim}80^{\circ}C$.

Numerical Modeling of Dehydration of Subducting Slab and Behavior of Expelled Water: A Preliminary Study (섭입해양판의 탈수 및 탈수된 물의 거동 수치모델링: 선행 연구)

  • Lee, Changyeol
    • Geophysics and Geophysical Exploration
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    • v.21 no.3
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    • pp.198-206
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    • 2018
  • In this preliminary study, dehydration of the subducting slab and behavior of the expelled water are numerically modeled using 2-dimensional model scheme. The hydrated minerals in the oceanic crust of the subducting slab experience dehydration by increases in temperature and pressure and expel their water into the overlying mantle wedge. Behavior of the expelled water is governed by both the corner flow in the mantle wedge and porous flow of the expelled water through the pores of the mantle minerals. The effects of convergence rate and age of the subducting slab as well as grain size of the minerals on the dehydration of the subducting slab and behavior of the expelled water are evaluated. The water solubility of the oceanic crust measured from the laboratory experiments is considered for modeling dehydration of the oceanic crust. The model calculations show most of the hydrated minerals in the oceanic crust is dehydrated by a depth of 100 km and the effects of the convergence rate and age of the subducting slab on the dehydration of the subducting slab and behavior of the expelled water are not significant. The larger grain size allows faster porous flow of the expelled water through the oceanic crust, mantle wedge and overlying continental crust and reduces the volume fraction of the expelled water there. The developed technique will be used for future studies on arc volcanism and has a potential implication for the other fields such as seismic tomographic study.