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http://dx.doi.org/10.9713/kcer.2015.53.4.425

Synthesis of ZSM-5 on the Surface of Foam Type Porous SiC Support  

Jung, Eunjin (Energy & Environmental Devision, Korea Institute of Ceramic Engineering and Technology)
Lee, Yoon Joo (Energy & Environmental Devision, Korea Institute of Ceramic Engineering and Technology)
Won, Ji Yeon (Energy & Environmental Devision, Korea Institute of Ceramic Engineering and Technology)
Kim, Younghee (Energy & Environmental Devision, Korea Institute of Ceramic Engineering and Technology)
Kim, Soo Ryong (Energy & Environmental Devision, Korea Institute of Ceramic Engineering and Technology)
Shin, Dong-Geun (Energy & Environmental Devision, Korea Institute of Ceramic Engineering and Technology)
Lee, Hyun Jae (Enbion Inc.)
Kwon, Woo Teck (Energy & Environmental Devision, Korea Institute of Ceramic Engineering and Technology)
Publication Information
Korean Chemical Engineering Research / v.53, no.4, 2015 , pp. 425-430 More about this Journal
Abstract
ZSM-5 crystals grew by hydrothermal synthesis method on the surface of foam type porous silicon carbide ceramics which fabricated by polymer replica method. Oxide layer was developed on the surface of the porous silicon carbide ceramics to induce growth of ZSM-5 from the surface. In this study, hydrothermal synthesis was carried out for 7 h at $150^{\circ}C$ using TEOS, $Al(NO_3){\cdot}9H_2O$ and TPAOH as raw materials in the presence of the porous silicon carbide ceramics. X-ray Powder Diffraction (XRD) and Scanning Electron Microscope (SEM) analyses were confirmed $1{\sim}3{\mu}m$ sized ZSM-5 crystals have grown on the surface of porous silicon carbide ceramics. BET data shows that small pores about $10{\AA}$ size drastically enhanced and surface area increased from $0.83m^2/g$ to $30.75m^2/g$ after ZSM-5 synthesis on the surface of foam type porous silicon carbide ceramics.
Keywords
Zeolite; ZSM-5; Porous; Silicon Carbide;
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Times Cited By KSCI : 1  (Citation Analysis)
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