• Title/Summary/Keyword: Polyphosphate

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Recovery of phosphorus from waste activated sludge by microwave heating and MAP crystallization (잉여 슬러지의 마이크로웨이브 가온과 MAP 결정화를 이용한 인산염 회수)

  • Ahn, Johwan
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.4
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    • pp.291-297
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    • 2019
  • Phosphorus is a vital resource for sustaining agriculture and nutrition, but a limited non-renewable resource. Thus, the recovery of phosphorus from waste activated sludge(WAS) was attempted by microwave heating and magnesium ammonium phosphorus(MAP) crystallization. Polyphosphate-accumulating organisms(PAOs) in WAS release phosphate from the cell when they are exposed to high temperature environments. Microwave heating caused phosphorus and ammonia to release from WAS. The amount was increased with increasing temperature, showing that 88.5% of polyphosphate present in the cells were released in the form of phosphate at $80^{\circ}C$. A similar result was also observed in the release of ammonia. On the other hand, both phosphorus and ammonia were crystallized with magnesium, and then was harvested as MAP. Phosphorus recovery rate reached almost 97.8%, but the ammonia was about 13.4%. These results cleary indicate that phosphorus could be recovered from WAS using a physiological trait of PAOs. Heavy metal analyses also show that the MAP crystal is useful and safe as a phosphorus fertilizer.

Release of Nutrients from Different Wasted Activated Sludges by Microwave Heating (다양한 활성 슬러지 공정에서 얻은 잉여 슬러지의 마이크로웨이브 가온과 영양물질의 방출)

  • Yang, Hoiweon;Ahn, Johwan;Kim, Jangho;Kim, Junghwan
    • Journal of Korea Society of Waste Management
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    • v.35 no.8
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    • pp.701-708
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    • 2018
  • Chemical batch tests were conducted to investigate the amount of nutrients that were released from the wasted activated sludge during microwave heating. For this study, three types of activated sludge were obtained from $A_2/O$, MLE and oxidation ditch (OD) processes. Polyphosphate-accumulating organisms in the activated sludge have a unique trait: they releases phosphate from the cell when they are exposed to high temperatures. The sludge obtained from the $A_2/O$ process released the largest amount of phosphate, followed by those from the MLE and OD processes. The release of phosphate increased with increasing polyphosphate content in the sludge under strongly alkaline or acidic conditions. Furthermore, ammonia and heavy metals were released with phosphorous. The largest amount of ammonia was observed from the sludge obtained from the MLE process. The release of heavy metals strongly depends on the pH conditions. Therefore, the chemical analysis results strongly suggest that both phosphorus and ammonia react with $Mg^{2+}$ or $Ca^{2+}$ to form metal complexes such as magnesium ammonium phosphate or hydroxyapatite under alkaline conditions.

Degradation rate of several types of Calcium Polyphosphate;Long term results (다양한 형태의 다공질 Calcium Polyphosphate의 생분해성에 관한 장기적인 연구)

  • Yang, S.M.;Seol, Y.J.;Kye, S.B.;Lee, I.K.;Lee, C.W.;Kim, S.Y.;Lee, Yong-Mu;Ku, Y.;Han, S.B.;Chung, C.P.;Choi, S.M.;Rhyu, I.C.
    • Journal of Periodontal and Implant Science
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    • v.33 no.2
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    • pp.301-310
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    • 2003
  • The purpose of this study is to evaluate the biocompatibility and the biorsorbability of several types of calcium polyphosphate made through change of manufacturing process for 12 month. To solve limitation of calcium phosphate, we developed a new ceramic, Calcium Polyphosphate(CPP), and report the biologic response to CPP in extraction sites of beagle dog. Porous CPP blocks were prepared by condensation of anhydrous $Ca(H_2PO_4)_2$ to form non-crystalline $Ca(PO_3)_2$ and then milled to produce CPP powder. CPP powder, CPP block, and CPP granules added with $Na_2O$ were implanted in extraction sockets and histologic observation were performed at 12 months later. Like 3 months results, histologic observation at 12 months revealed that CPP matrix were mingled with and directly apposed to new bone without any adverse tissue reaction, CPP powder show direct bony contact, but new bone formation and fibrous tissue encapsulation showed in CPP block. 10% $Na_2O$ CPP granules show more inflammatory cells infiltration around graft materials compared at 3 month, but 15% $Na_2O$ CPP granules show less. This result revealed that regardless of addition of $Na_2O$, CPP had a high affinity for bone and had been resorbed slowly. From this results, it was suggested that CPP is promising ceramic as a bone substitute and addition of $Na_2O$ help biodegradation but optimal concentration of $Na_2O$ and other additive component to increase degradation rate should be determined in further study.

EFFECTS OF POLYPHOSPHATE MIXED IN ACRYLIC RESIN ON THE ATTACHMENT AND GROWTH OF ORAL BACTERIA (Acrylic Resin에 혼합된 Polyphosphate가 미생물의 부착 및 성장에 미치는 영향)

  • Hong, Sun-Hee;Choi, Yeong-Chul
    • Journal of the korean academy of Pediatric Dentistry
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    • v.30 no.1
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    • pp.69-79
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    • 2003
  • The purpose of this present study was to develop a new way of self-curing acrylic resin, using commercially available polyphosphate, Calgon, which is known to be antimicrobial and safe. For the study, polyphosphate(polyP) was blended with acrylic powder and devided into four groups as follows: no polyP(control), 1% polyP, 2% polyP, and 3% polyP. For the experiment, Streptococcus mutans GS5, Streptococcus sobrinus 6715, Streptococcus gordonii G9B and Challis, Porphyromonas gingivalis 2561, and Candida albicans ATCC 90027 were used. Resin specimens in each group were tested in vitro for the purpose of investigating the effect of polyP on the microbial attachment, growth and hydrophobicity of the resin surface. The results were as follows. 1. PolyP added to the acrylic resin decreased attachment of S. mutans GS5, S. sobrinus 6715, S. gordonii G9B. The greater binding inhibition was found in acrylic resin polymerized with polyP at higher concentrations. 2. The addition of polyP to acrylic resin failed to significantly affect the growth of the tested microorganisms. 3. The addition of polyP to acrylic resin seemed to reduce hydrophobicity of the acrylic resin. PolyP in acrylic resin does not seem to exert a direct antibacterial activity, but rather inhibit attachment of oral bacteria, especially mutans streptococci to saliva-coated acrylic resin. The acrylic resin reduces attachment of streptococci may be due to the decreased hydrophobicity caused by polyP added to the resin. PolyP may be included to acrylic resin to inhibit dental caries which often occurs when removable acrylic resin appliance is placed.

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Effect of Cryoprotectants on Quality Properties of Chicken Breast Surimi Manufactured by pH Adjustment (냉동변성방지제 조건에 따른 닭가슴살 수리미의 저장특성)

  • Jin, S.K.;Kim, I.S.;Choi, Y.J.;Park, G.B.;Yang, H.S.;Kim, B.G.
    • Journal of Animal Science and Technology
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    • v.50 no.1
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    • pp.99-110
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    • 2008
  • This study was conducted to determine the effect of pH adjustment and the addition of cryoprotectants on the storage properties of chicken breast surimi. Surimi as a control was prepared with Alaska pollack by two times of washing treatment and addition of cryoprotectants(4% sugar, 5% sorbitol and 0.3% polyphosphate). Three types of surimi were manufactured by different cryoprotectant conditions(T1: 5% sorbitol+0.3% polyphosphate, T2: 4% sugar+5% sorbitol+0.3% polyphosphate, T3: 2% salt+4% sugar+5% sorbitol+0.3% polyphosphate) and frozen after adjusting the surimi to pH 11.0. The amino acid and saturated fatty acid composition were significantly higher in the control. EAA(essential amino acid), FAA(amino acid in relation to flavor), SAAA(amino acid in relation to saccarinity) and FRAA (fragrant amino acid) were significantly higher in the control. The TBARS(thiobarbituric acid reactive substances) and VBN(volatile basic nitrogen) were increased with storage times. TBARS and VBN values were significantly higher in the control and T3 than the other treatments. The VBN was significantly higher in control and T3 than other surimi samples. Chicken breast surimi adjusted to pH 11.0 had higher in microorganisms than the control, and T1 sample had the highest total plate count. Sensory evaluations were significantly higher in the control and T3 than the other samples. Especially, the overall acceptability of T3 was similar to the control.

Effect of Cryoprotectants on the Quality Characteristics of Chicken Breast Surimi Manufactured by pH Adjustment during Freezing Storage (pH 조절법으로 제조한 닭가슴살 수리미의 저장 중 품질특성에 미치는 냉동변성방지제 첨가 효과)

  • Jin, Sang-Keun;Kim, Il-Suk;Choi, Yeung-Joon;Yang, Han-Sul;Park, Gu-Boo
    • Food Science of Animal Resources
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    • v.27 no.3
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    • pp.320-328
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    • 2007
  • This study was conducted to determine the effect of pH adjustment and the addition of cryoprotectants on the quality characteristics of chicken breast surimi. We prepared surimi from Alaska pollack, as a the control, by two time washing times and the addition of cryoprotectants. Different preparations of surimi were manufactured by adjusting to pH 11.0 and the addition of different addition cryoprotectants during frozen storage (T1 : 5% sorbitol and 0.3% polyphosphate, T2: 4% sugar, 5% sorbitol and 0.3% polyphosphate, and T3: 2% salt, 4% sugar, 5% sorbitol and 0.3% polyphosphate). The moisture content was significantly lower in the control and T3 samples. The crude protein content was increased with storage times. The crude protein was higher in the control. The water-holding capacity, myofibrillar protein and shear force were significantly higher in T3 than other surimi samples. All gel characteristics were significantly higher in the control and T3 than other surimi samples. pH 11.0 adjusted chicken breast surimi had greater lightness than the control, and T3 samples had the highest lightness and whiteness. Sensory evaluations were significantly higher in the control and T3 than the other samples. The gel, and physical characteristics and sensory evaluation of T3 were similar to the control. T3 samples had superior color and pH than the control Alaska pollack surimi.

Studies on the Surface Treatment of Kaolin Filler(Part 2) -Morphological Studies by SEM- (Kaolin 충전제(充塡劑) 표면처리(表面處理)에 관(關)한 연구(硏究)(제(弟) 2 보(報)) -주사전자현미경(走査電子顯微鏡)에 의(依)한 morphology-)

  • Kwon, Dong-Yong;Hong, Sung-Il;Kim, Sun-Ho;Lee, Yong-Moo;Huh, Dong-Sub
    • Elastomers and Composites
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    • v.18 no.4
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    • pp.135-139
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    • 1983
  • Scanning electron microscopy studies were conducted to examine the surface treatment effects of treating agents the proposed in the previous studies on various vulcanizates. Fracture surfaces of the vulcanizates compounded with kaolin treated with sodium polyphosphate of poly(maleic anhydride) presented favorable results as expected from the results of the previous studies. In other words, treating agents such as sodium polyphosphate and poly(maleic anhydride) show considerable reinforcing effects on the vulcanizates.

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Quality Changes of Cold Cuts Prepared from Pork and Chicken during Storage (계육과 돈육으로 제조한 Gold Cut의 저장에 따른 품질변화)

  • Lee, Hye-Jeong;Park, Hui-Ok;Kim, Yu-Gyeong
    • The Korean Journal of Food And Nutrition
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    • v.7 no.3
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    • pp.219-222
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    • 1994
  • Cold cuts were prepared from the pork and chicken with polyphosphate salt and spices. Microorganism was more proliferated and acid value was more decreased In pork cold cut rather than chicken cold cut. Otherwise TBA value of chicken cold cut was more increased than that of pork cold cut. Textures of springeness and cohesiveness were not significantly different in both cold cuts. From sensory evaluation, color, appearance and odor were significantly different, but texture, flavor and total acceptability were not significantly different. From these results, if we could study some antioxidants furthermore. we think it possible to manufacture cold cut from chicken.

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A Study on the Allergenicity of Milk Protein (우유 단백질의 Allergenicity에 관한 연구)

  • 정은자
    • The Korean Journal of Food And Nutrition
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    • v.8 no.2
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    • pp.79-87
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    • 1995
  • It is generally known that the protein of talk has allergenicity and the allerenicity Induces allergic diseases. Finding methods to reduce the allergenicity of the food and develop methods to make low allergic food is the purpose of this study. For this study, 1 tried various experimental methods : heat treatment, irradation with ultraviolet and microwaves treatment with polyphosphate, enzyme hydrolysis and PCA inhibition test using guinea pigs and degrees of hydrolysis. The results obtained are as follows. Heat treatment reduced allergenicity of milk protein. The higher the heat, the better the effect. Irradiating with ultraviolet and microwave increased both the degree of protein hydrolysis and PCA inhibition reduced the allergenicity. Ultraviolet was more effective than microwaves on milk protein. Enzyme treatment increased the degree of hydrolysis and PCA inhibition, and reduced allergenicity considerably. Neutrase was more effective than alcalase on milk protein. Adding Polyphosphate did not induced protein hydrolysis, but increased PCA inhibition and reduced allergenicity.

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Studies on the Surface Treatment of Kaolin Filler(Part I) -Fundamental Properties of Kaolin Filler and Treatment Effect on Physical Properties of Rubbers- (Kaolin 충전제(充塡劑) 표면처리(表面處理)에 관(關)한 연구(硏究)(제1보(第1報)) -Kaolin의 기초성상(基礎性狀) 및 고무물성(物性)에 대(對)한 처리효과(處理效果)-)

  • Kwon, Dong-Yong;Hong, Sung-Il;Lee, Yong-Moo
    • Elastomers and Composites
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    • v.18 no.3
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    • pp.87-98
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    • 1983
  • Fundamental properties and surface treatment effects of domestic kaolin calcined at higher temperature were studied to develop reinforcing fillers for rubbers. The results obtained are as follows: (i) X-ray diffraction and scanning electron microscopy studies revealed kaolinite as a major constituent of the raw kaolin used in this study. (ii) Physical properties of natural rubber vulcanizates compounded with the calcined kaolin fillers treated with poly(maleic anhydride) and sodium polyphosphate are favorably improved. Particularly, the kaolin filler treated with sodium polyphosphate(designated as PT series) shows excellent physical properties compared with hydrated silica.

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