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http://dx.doi.org/10.11001/jksww.2019.33.4.291

Recovery of phosphorus from waste activated sludge by microwave heating and MAP crystallization  

Ahn, Johwan (Hankyung E&C Co., Ltd.)
Publication Information
Journal of Korean Society of Water and Wastewater / v.33, no.4, 2019 , pp. 291-297 More about this Journal
Abstract
Phosphorus is a vital resource for sustaining agriculture and nutrition, but a limited non-renewable resource. Thus, the recovery of phosphorus from waste activated sludge(WAS) was attempted by microwave heating and magnesium ammonium phosphorus(MAP) crystallization. Polyphosphate-accumulating organisms(PAOs) in WAS release phosphate from the cell when they are exposed to high temperature environments. Microwave heating caused phosphorus and ammonia to release from WAS. The amount was increased with increasing temperature, showing that 88.5% of polyphosphate present in the cells were released in the form of phosphate at $80^{\circ}C$. A similar result was also observed in the release of ammonia. On the other hand, both phosphorus and ammonia were crystallized with magnesium, and then was harvested as MAP. Phosphorus recovery rate reached almost 97.8%, but the ammonia was about 13.4%. These results cleary indicate that phosphorus could be recovered from WAS using a physiological trait of PAOs. Heavy metal analyses also show that the MAP crystal is useful and safe as a phosphorus fertilizer.
Keywords
Magnesium ammonium phosphate(MAP); Microwave heating; Phosphorus recovery; Polyphosphate-accumulating organisms(PAOs); Waste activated sludge(WAS);
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