• Title/Summary/Keyword: Polymeric effect

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알루미나-지르코니아 복합체의 제조공정 및 미세구조에 미치는 폴리머 첨가의 영향 (Effect of Polymer Content on Synthesis Process and Microstructure of Alumina-Zirconia Composite)

  • 이상진;권명도;이충효;조경식
    • 한국분말재료학회지
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    • 제10권5호
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    • pp.310-317
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    • 2003
  • Two-component ceramic (alumina-zirconia) composites were fabricated by a soft-solution process in which polyethylene glycol (PEG) was used as a polymeric carrier. Metal salts and PEG were dissolved in ethyl alcohol without any precipitation in 1:1 volume ratio of alumina and zirconia. In the non-aqueous system, the flammable solvent made explosive, exothermic reaction during drying process. The reaction resulted in formation of volume expanded, porous precursor powders by a vigorous decomposition of organic components in the precursor sol. The PEG content affected the grain size of sintered composites as well as the morphology of precursor powders. The difference of microstructure in sintered composite was attribute to the solubility and homogeneity of metal cations in precursor sol. At the optimum amount of the PEG polymer, the metal ions were dispersed effectively in solution and a homogeneous polymeric network was formed. It made less agglomerated particles in the precursor sol and affected on uniform grain size in sintered composite.

Low Temperature Debinding Process Using Oxygen Plasma for Flexible Printed Electronics

  • Lee, Young-In
    • 한국분말재료학회지
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    • 제19권5호
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    • pp.343-347
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    • 2012
  • In this study, an oxygen plasma treatment was used as a low temperature debinding method to form a conductive copper feature on a flexible substrate using a direct printing process. To demonstrate this concept, conductive copper patterns were formed on polyimide films using a copper nanoparticle-based paste with polymeric binders and dispersing agents and a screen printing method. Thermal and oxygen plasma treatments were utilized to remove the polymeric vehicle before a sintering of copper nanoparticles. The effect of the debinding methods on the phase, microstructure and electrical conductivity of the screen-printed patterns was systematically investigated by FE-SEM, TGA, XRD and four-point probe analysis. The patterns formed using oxygen plasma debinding showed the well-developed microstructure and the superior electrical conductivity compared with those of using thermal debinding.

유기 절연층에 따른 유기 TFT 특성 연구 (Study on the Characteristics of Organic TFT Using Organic Insulating Layer Efficiency)

  • 표상우;이민우;손병천;김영관
    • 한국응용과학기술학회지
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    • 제19권4호
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    • pp.335-338
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    • 2002
  • A new process for polymeric gate insulator in field-effect transistors was proposed. Fourier transform infrared absorption spectra were measured in order to identify ODPA-ODA polyimide. Its breakdown field and electrical conductivity were measured. All-organic thin-film transistors with a stacked-inverted top-contact structure were fabricated to demonstrate that thermally evaporated polyimide films could be used as a gate insulator. As a result, the transistor performances with evaporated polyimide was similar with spin-coated polyimide. It seems that the mass-productive in-situ solution-free processes for all-organic thin-film transistors are possible by using the proposed method without vacuum breaking.

저전계영역에서 M$_{1}$-P-M$_{2}$형 고분자재료의 전기전도 1

  • 이덕출;임광현
    • 전기의세계
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    • 제29권11호
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    • pp.727-732
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    • 1980
  • The main purpose of this paper is to study on the effect of contact state between metal-polymer interface in electrical conduction of polymeric materials under low field region. The electric conduction of polythylene (PE) sandwitched in between two gold (Au) electrodes was lower than that of PE Sandwitched in between two Aluminium (Al) electrodes under low external field. The discharge current of PE which have been treated by the high field application is also obtained some results under no external field. The obtained results can suggest that the material of electrode come to influence on the electrical conduction of polymeric materials and are important as a basis for analysing the data on TSC. It is also suggestive that results of observation must be considered in cases of insulation design of electrical machinery.

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고성능 폴리머 광도파로 소자 (High Performance Polymeric Optical Waveguide Devices)

  • 오민철;노영욱;이형종
    • 한국광학회:학술대회논문집
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    • 한국광학회 2005년도 제16회 정기총회 및 동계학술발표회
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    • pp.292-295
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    • 2005
  • Variable optical attenuators (VOA) made of low-loss fluorinated polymers are demonstrated which shows a low operating power less than 30 mW due to the superior thermo-optic effect of polymer material and a low insertion loss less than 1.0 dB by incorporating highly fluorinated polymers to reduce the absorption loss at 1550 nm. An attenuator-integrated low-crosstalk polymeric digital optical switch (DOS) is also demonstrated. The switch and attenuator shares a single connected electrode which is controlled by a single current source. Due to the simple structure of the integrated attenuator, the device length is reduced to 1 cm so as to provide low insertion loss of 0.8 and 1.1 dB for 1300 and 1550 nm, respectively. The attenuator radiates remained optical signal on the switch-off branch in order to decrease the switching crosstalk to be less than -70 dB with an applied electrical power of 200 mW.

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균열 진전에 대한 미세 입자의 영향 (The effects of microparticles on the crack propagation)

  • 정보영;박성도;윤영기;윤희석
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2003년도 춘계학술대회 논문집
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    • pp.1495-1498
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    • 2003
  • Recently, self-healing methods of a cracked matrix, especially polymeric composite materials, became the center of engineering researchers. In this paper, we summarized the self-healing concept for polymeric composite materials and investigated the effect of microparticle on the crack growth behavior in colorless and transparent matrix by experimental observation to describe the crack propagation around the microparticle inside epoxy matrix composite. Compression splitting test for the specimen involving microparticle was conducted. In addition, FE analysis was pursued to present the stress contour around microparticle in the matrix. Through the experiments and FE analysis, we found that the size. relative position, bonding condition and relative stiffness of microparticle are important parameters to decide the direction of crack propagation, which is related to the rupture of microparticle for self-healing

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Influence of Surface Free Energy of Carbon Black/Thermoplastic Resin Composites on PTC Characteristics

  • Park, Soo-Jin;Kim, Hyun-Chel;Lee, Jae-Rock
    • Carbon letters
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    • 제1권1호
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    • pp.1-5
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    • 2000
  • The effect of surface free energy on the positive temperature coefficient (PTC) of carbon black/thermoplastic resin composites was investigated. The thermoplastic resins such as EVA, LDPE, LLDPE and HDPE were used with the addition of 30 wt.% of the carbon black. The surface free energy of the composites was studied in the context of two-liquid contact angle measurements, i.e., deionized water and diiodomethane. It was observed that the resistivity on PTC composites Was greatly increased near the crystalline melting temperature, due to the thermal expansion of polymeric matrix. From the experimental results, it was proposed that the decrease of surface free energy induced by interactions between carbon black surfaces and polymer chains is an important factor to the fabrication of a PTC composite made of carbon black and polymeric matrix.

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$1{\times}2$ 열광학 폴리머 광스위치의 해석에 관한 연구 (A Study on the Analysis of $1{\times}2$ Polymer Waveguide Thermo-optic switch)

  • 곽혁용;김종헌
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.247-251
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    • 1998
  • This work presents the analysis of $1\times2$ polymer waveguide thermo-optic switch using asymmetric Y-splitter at the wavelength of 1300nm. Because of the high thermo-optic coefficient of polymeric materials the design of efficient switches were feasible. For the numerical simulation of these switches the finite difference beam propagation method has been employed. Design rules for a $1\times2$ polymeric switch have been defined by using the numerical techniques.

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Effect of Cathodic Biofilm on the Performance of Air-Cathode Single Chamber Microbial Fuel Cells

  • Ahmed, Jalal;Kim, Sung-Hyun
    • Bulletin of the Korean Chemical Society
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    • 제32권10호
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    • pp.3726-3729
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    • 2011
  • Biofilm formation is inevitable in a bioelectrochemical system in which microorganisms act as a sole biocatalyst. Cathodic biofilm (CBF) works as a double-edged sword in the performance of the air-cathode microbial fuel cells (MFCs). Proton and oxygen crossover through the CBF are limited by the robust structure of extracellular polymeric substances, composition of available constituents and environmental condition from which the biofilm is formed. The MFC performance in terms of power, current and coulombic efficiency is influenced by the nature and origin of CBF. Development of CBF from different ecological environment while keeping the same anode inoculums, contributes additional charge transfer resistance to the total internal resistance, with increase in coulombic efficiency at the expense of power reduction. This study demonstrates that MFC operation conditions need to be optimized on the choice of initial inoculum medium that leads to the biofilm formation on the air cathode.

유한요소해석을 이용한 직조 탄소섬유 발포 고분자 샌드위치 구조의 압축특성 (FE Analyses of the Compressive Characteristics of Carbon Fabric/Polymeric Foam for Sandwich Structure)

  • 장승환;전성식
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2004년도 춘계학술발표대회 논문집
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    • pp.194-197
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    • 2004
  • In this paper, compressive characteristics of carbon fabric skin with polymeric foam core sandwich structure were investigated by FE analyses and compressive tests of polyurethane foam were also conducted with respect to temperature changes, which were determined by curing processes of epoxy or polyester resin to obtain mechanical behaviour of polyurethane foam. FE analyses indicated variation of parameters with respect to manufacturing pressure, which have comparatively massive effect upon mechanical properties of sandwich structures, i.e. wavelength as well as crimp angle of carbon fabric

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