• Title/Summary/Keyword: Polymer behavior model

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Stress-Strain Properties of recycled-PET Polymer Concrete (PET 재활용 폴리머 콘크리트의 응력-변형률 특성)

  • Jo, Byung-Wan;Park, Jong-Hwa;Park, Seung-Kook
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.316-319
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    • 2004
  • Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. The purposed of this paper is to propose the model for the stress-strain relation of recycled-PET polymer concrete at monotonic uniaxial compression and is to investigate for the stress-strain behavior characteristics of recycled-PET polymer concrete with different variables(strength, resin contents, curing conditions, addition of silane and ages). The maximum stress and strain of recycled-PET polymer concrete was found to increase with an increase in resin content, however, it decreased beyond a particular level of resin content. A ascending and descending branch of stress-strain curve represented more sharply at high temperature curing more than normal temperature curing. In addition, results show that the proposed model accurately predicts the stress-strain relation of recycled-PET polymer concrete.

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Development of a Multi-Physics Model of Polymer Electrolyte Membrane Fuel Cell Using Aspen Custom Modeler (Aspen Custom Modeler를 이용한 고분자전해질 연료전지 다중 물리 모델 개발)

  • SON, HYEYOUNG;HAN, JAESU;YU, SANGSEOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.489-496
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    • 2021
  • The performandce of polymer electrolyte membrane fuel cell depends on the effective management of heat and product water by the electrochemical reaction. This study is designed to investigate the parametric change of heat management along the channel of polymer electrolyte membrane. The model was developed by an aspen custom modeler that it can solve differential equation with distretization model. The model can simulate water transport through the membrane electrolyte that is coupled with heat generation. In order to verify the model, it is compared with the experimental data. The water transport behavior is then evaluated with the simulation model.

Hysteretic behavior in polymer stabilized ferroelectric liquid crystal

  • Lee, Ji-Hoon;Lim, Tong-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.334-337
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    • 2005
  • We have found that the hysteretic behavior of a polymer stabilized ferroelectric liquid crystal system coincides with Blinov et. al's model qualitatively. The hysteresis inversion frequency could be promoted up to 7000 Hz by connecting external capacitor and resistor in serial. In addition, the influence of temperature and the amplitude of the applied field on hysteresis-free switching of the cell could be minimized.

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Experimental and numerical study on viscoelastic behavior of polymer during hot embossing process (핫엠보싱 공정의 폴리머 점탄성 거동에 대한 연구)

  • Song, N.H.;Son, J.W.;Rhim, S.H.;Oh, S.I.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.05a
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    • pp.191-194
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    • 2007
  • In hot embossing lithography which has shown to be a good method to fabricate polymeric patterns for IT and bio components, it is very important to determine the proper process conditions of pressure, temperature, and time. It is also a key factor for predicting the optical properties of final product to calculate residual stress distribution after the embossing process. Therefore, to design the optimum process with right conditions, the ability to predict viscoelastic behavior of polymer during and after the hot embossing process is required. The objective of the present investigation is to establish simulation technique based on constitutive modeling of polymer with experiments. To analyze deformation behavior of viscoelastic polymer, the large strain material properties were obtained from quasi-static compression tests at different strain rates and temperatures and also stress relaxation tests were executed. With this viscoelastic material model, finite element simulation of hot embossing was executed and stress distribution is obtained. Proper process pressure is very important to predict the defect and incomplete filling.

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Axial impact behavior of confined concrete filled square steel tubes using fiber reinforced polymer

  • Zhang, Yitian;Shan, Bo;Kang, Thomas H.K.;Xiao, Yan
    • Steel and Composite Structures
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    • v.38 no.2
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    • pp.165-176
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    • 2021
  • Existing research on confined concrete filled steel tubular (CCFT) columns has been mainly focused on static or cyclic loading. In this paper, square section CCFT and CFT columns were tested under both static and impact loading, using a 10,000 kN capacity compression test machine and a drop weight testing equipment. Research parameters included bonded and unbonded fiber reinforced polymer (FRP) wraps, with carbon, basalt and glass FRPs (or CFRP, BFRP, and GFRP), respectively. Time history curves for impact force and steel strain observed are discussed in detail. Experimental results show that the failure modes of specimens under impact testing were characterized by local buckling of the steel tube and cracking at the corners, for both CCFT and CFT columns, similar to those under static loading. For both static and impact loading, the FRP wraps could improve the behavior and increase the loading capacity. To analyze the dynamic behavior of the composite columns, a finite element, FE, model was established in LS-DYNA. A simplified method that is compared favorably with test results is also proposed to predict the impact load capacity of square CCFT columns.

Design, modelling and analysis of a new type of IPMC motor

  • Kolota, Jakub
    • Smart Structures and Systems
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    • v.24 no.2
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    • pp.223-231
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    • 2019
  • The properties of Electroactive Polymer (EAP) materials are attracting the attention of engineers and scientists from many different disciplines. From the point-of-view of robotics, Ionic Polymer Metal Composites (IPMC) belong to the most developed group of the EAP class. To allow effective design of IPMC-actuated mechanisms with large induced strains, it is necessary to have adequate analytical tools for predicting the behavior of IPMC actuators as well as simulating their response as part of prototyping methodologies. This paper presents a novel IPMC motor construction. To simulate the bending behavior that is the dominant phenomenon of motor movement process, a nonlinear model is used. To accomplish the motor design, the IPMC model was identified via a series of experiments. In the proposed model, the curvature output and current transient fields accurately track the measured responses, which is verified by measurements. In this research, a three-dimensional Finite Element Method (FEM) model of the IPMC motor, composed of IPMC actuators, simultaneously determines the mechanical and electrical characteristics of the device and achieves reliable analysis results. The principle of the proposed drive and the output signals are illustrated in this paper. The proposed modelling approach can be used to design a variety of controllers and motors for effective micro-robotic applications, where soft and complex motion are required.

Characterization of the mechanical behavior of PEKK polymer and C/PEKK composite materials for aeronautical applications below and above the glass transition temperature

  • Pedoto, Giuseppe;Smerdova, Olga;Grandidier, Jean-Claude;Gigliotti, Marco;Vinet, Alain
    • Advances in aircraft and spacecraft science
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    • v.7 no.6
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    • pp.475-493
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    • 2020
  • This paper is focused on the characterization of the thermomechanical properties of semicrystalline poly-ether-ether-ketone (PEKK) and of carbon fiberreinforced thermoplastic based laminated composites (C/PEKK) below and above the glass transition temperature (Tg). Differential Scanning Calorimetry (DSC), Dynamic Mechanical Analysis (DMA) and tensile tests are carried out on both pure PEKK polymer and [(±45)2, +45]s C/PEKK composite samples, showing a significant similarity in behavior. The employment of a simple micromechanical model confirms that the mechanical and physical behavior of the polymer and that of the matrix in the composite are similar.

Synthesis, Photochemical and Photophysical Behavior of Vinyl Monomers with Donor/Acceptor Architectures and Their Polymers

  • Li, Zi-Chen;Du, Fu-Sheng;Li, Fu-Mian
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.106-107
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    • 2006
  • A series of vinyl monomers and their saturated model compounds containing different chromophores were synthesized. These monomers display strong intra-molecular fluorescence quenching, their fluorescence quantum yields and lifetimes are generally lower than those of their model compounds. It was found that the C=C bonds in these monomers played a key role in the intra-molecular quenching, which was confirmed by intermolecular fluorescence quenching and time-resolved fluorescence studies. On the basis of the intra-molecular quenching, a new fluorescence approach can be developed to monitor the process of the polymerization and curing of bismaleimides, which can directly reflect the C=C bond consumption during polymerization and curing.

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Thermocontrol of Solute Permeation across Polymer Memberane Composed of Poly(N, N-dimethylaminoethyl methacrylate) and Its Copolymers

  • Yuk, Soon-Hon;Cho, Sun-Hang
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.4
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    • pp.274-278
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    • 2001
  • Polymer membranes composed of N, N-dimethylaminoethyl methaccrylate(DMAEMA) and acrylamide(AAm)(or ethyl acrylamide(EAAm) were prepared to demonstrated the thermo-control of solute permeation. Poly DMEMA has a lower critical solution temperature(LCST) at around 50$\^{C}$ in water, With the copolymerization of DMAEMA with AAm (or EAAm) a shift in the LCST to a lowere temperature was observed, probably due to the formation of hydrogen bonds between the amide and N-N-dimethylamino groups. However, the temperature-induced phase transition of poly(DMAEMA-co-EAAm) did not show a similar trend to that of poly(DMAEMA- co-AAm) in the gel state. The hydrogen bonds in poly(DMAEMA-co-EAAm) were significantly disrupted with the formation a gel network, which led to a difference in the swilling behavior of polymer gels in response to temperature. To apply these polymers to temperature-sensitive sol-ute permeation, polymer membranes were prepared. The permeation pattern of hydrocortisone, used as the model solute, was explained based on the temperature-sensitive swelling behavior of the polymer membranes.

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A comparative analysis of sheeting die geometries using numerical simulations

  • Igali, Dastan;Wei, Dongming;Zhang, Dichuan;Perveen, Asma
    • Advances in Computational Design
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    • v.5 no.2
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    • pp.111-125
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    • 2020
  • The flow behavior of polymer melts within a slit die is an important consideration when designing a die geometry. The quality of the extruded polymer product can be determined through an evaluation of the flow homogeneity, wall shear rate and pressure drop across the central height of the die. However, mathematical formulations cannot fully determine the behavior of the flow due to the complex nature of fluid dynamics and the nonlinear physical properties of the polymer melts. This paper examines two slit die geometries in terms of outlet velocity uniformity, shear rate uniformity at the walls and pressure drop by using the licensed computational fluid dynamics package, Ansys POLYFLOW, based on the finite element method. The Carreau-Yasuda viscosity model was used for the rheological properties of the polypropylene. Comparative analysis of the simulation results will conclude that the modified die design performs better in all three aspects providing uniform exit velocity, uniform wall shear rates, and lower pressure drop.