• 제목/요약/키워드: Polymer Material

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리튬 이온 폴리머 전지용 Tin oxide-flyash Composite 전극의 전기화학적 특성 (Electrochemical Properties of Tin oxide-flyash Composite for Lithium Ion Polymer Battery)

  • 김종욱;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 센서 박막재료 반도체 세라믹
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    • pp.88-90
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    • 2003
  • The purpose of this study is to research and develop tin oxide-flash composite for lithium Ion polymer battery. Tin oxide is one of the promising material as a electrode active material for lithium Ion polymer battery (LIPB). Tin-based oxides have theoretical volumetric and gravimetric capacities that are four and two times that of carbon, respectively. We investigated cyclic voltammetry and charge/discharge cycling of SnO-flyash/SPE/Li cells. The first discharge capacity of SnO-flyash composite anode was 720 mAh/g. The discharge capacity of SnO-flyash composite anode 412 and 314 mAh/g at cycle 2 and 10 at room temperature, respectively. The SnO-flyash composite anode with PVDF-PMMA-PC-EC-$LiClO_4$ electrolyte showed good capacity with cycling.

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입체면 복합 폴리머 소재의 전도성 패턴 제작 기술 (Conductivity Pattern Manufacture Technology of Solid Surface Compound Polymer Material)

  • 윤신용
    • 전기학회논문지P
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    • 제65권3호
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    • pp.224-234
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    • 2016
  • This study developed the conductivity pattern of solid surface using laser direct pattern and compound polymer material technology. For development direct patterning system of solid surface, we used the laser power stabilizer, the dynamic focusing, 3D scanner S/W and the auto aligning techniques. Also For conductivity pattern, we are developed compound polymer material with additive by electro-less plating. These technologies are already used commercially. However operation and control integrated system for direct patterning of solid surface are not yet developed. The objective of this paper is to introduce the laser direct structuring for simple process improvement instead complex PCB process, and develop the operating stability and integration system. Also we implemented new application of laser direct structuring through sample manufacture.

Influence Study of Aluminum Dross on Polypropylene Matrix-Polymer Composite Material Properties

  • Kongchatree, Khanob;Yaemphuan, Paiboon;Kaewwichit, Jesada;Roybang, Waraporn;Kimapong, Kittipong
    • International Journal of Advanced Culture Technology
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    • 제3권1호
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    • pp.138-144
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    • 2015
  • This paper is aimed to study the influence of aluminium dross from Thai aluminum casting factory on polypropylene matrix-polymer composite material properties. The summarized experimental results are as follows. An increase in the amount of aluminum dross polymer composite material affected to increase hardness, modulus of elasticity and abrasion resistance. However, the increase of the aluminum dross had no effects to change the yield strength and the melting temperature of the polymer composite material. The aluminum dross also affected to form the crystallinity at $117-122^{\circ}C$ and directly increased the rigid property of the composite materials. The microstructure examination revealed that the aluminum dross was located in a polymer matrix and affected to increase the dark colour of the polymer composite material.

Yttrium-doped and Conductive Polymer-Coated High Nickel Layered Cathode Material with Enhanced Structural Stability

  • Shin, Ji-Woong;Lee, Seon-Jin;Nam, Yun-Chae;Son, Jong-Tae
    • Journal of Electrochemical Science and Technology
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    • 제12권2호
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    • pp.272-278
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    • 2021
  • In this study, high nickel layered LiNi0.8Co0.1Mn0.1O2 cathode materials for lithium-ion batteries were modified by yttrium doping and poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) coating. The effects of yttrium doping and PEDOT:PSS coating on the structural and electrochemical properties of the LiNi0.8Co0.1Mn0.1O2 cathode material were investigated and compared. The substitution of nickel with an electrochemically inert yttrium was confirmed to be successful in stabilizing the layered structure framework. Moreover, coating the surfaces of the LiNi0.8Co0.1Mn0.1O2 particles with a conductive polymer, PEDOT:PSS, improved the capacity retention, thermal stability, and impedance of the cathode material by increasing its ionic and electric conductivities.

Fabrication of Micro Conductor Pattern on Polymer Material by Laser Induced Surface Activation Technology

  • Lee, Sung-Hyung;Yashiro, Hitoshi;Kure-Chu, Song-Zhu
    • 한국재료학회지
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    • 제30권7호
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    • pp.327-332
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    • 2020
  • Laser induced surface activation (LISA) technology requires refined selection of process variables to fabricate conductive microcircuits on a general polymer material. Among the process variables, laser mode is one of the crucial factors to make a reliable conductor pattern. Here we compare the continuous wave (CW) laser mode with the pulse wave (PW) laser mode through determination of the surface roughness and circuit accuracy. In the CW laser mode, the surface roughness is pronounced during the implementation of the conductive circuit, which results in uneven plating. In the PW laser mode, the surface is relatively smooth and uniform, and the formed conductive circuit layer has few defects with excellent adhesion to the polymer material. As a result of a change of laser mode from CW to PW, the value of Ra of the polymer material decreases from 0.6 ㎛ to 0.2 ㎛; the value of Ra after the plating process decreases from 0.8 ㎛ to 0.4 ㎛, and a tight bonding force between the polymer source material and the conductive copper plating layer is achieved. In conclusion, this study shows that the PW laser process yields an excellent conductive circuit on a polymeric material.

배전용 폴리머애자의 현장열화 특성평가 (Characterization of Field-Aged Polymer Insulators for Distribution Power Systems)

  • 이병성;김찬영;한재홍
    • 한국전기전자재료학회논문지
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    • 제13권10호
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    • pp.847-858
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    • 2000
  • The aging characteristics of 2 kinds of 3 years field-aged distribution polymer insulators which were dismounted from 5 regions have been investigated by electrical test and material characterization. Although the tan $\delta$of specimens prepared from weathershed was increased with surface aging, the tan $\delta$and leakage current of real products had no difference between virgin and dismounted ones. Due to the aging, all dismounted polymer insulators had micro-cracks on the surface of weathershed and only the products of manufacturer B showed the reduction of OIT(oxidation induction time). But, there were no differences between virgin and dismounted products in contact angle and chemical structure. Therefore, it can be considered that the aging is only limited on the surface of dismounted polymer insulators and that NMR technique are very useful to evaluate the aging of polymer materials.

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경년변화에 따른 송전용 폴리머 현수애자의 트래킹 성능평가 (Tracking Property of Polymer Suspension Insulator for Transmission line with secular variation)

  • 조한구;이운용;이유정;임기조;최인혁
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.558-559
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    • 2005
  • Recently, polymer insulators that are used for high voltage applications have some advantages such as light weight, small size, vandalism resistance, hydrophobicity and easy making process. During outdoor service of polymer insulators, the surface of the insulating material is frequently subjected to moisture and contamination that lead to dry band arcing. Their tracking resistance, erosion resistance, end sealing and shed design are very important because dry band arcing causes degradation of polymer surface. In this paper, the tracking property of polymer suspension insulator for power transmission is investigated with CEA tracking wheel test. The diagnosis of insulator sample in tracking test has been analyzed by leakage current, STRI Guide, SEM, FTIR and thermal image.

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극화된 고분자에서 비선형 광학특성의 완화 (The Relaxation of Nonlinear Optical Properties in a Poled Polymer)

  • 정치섭
    • 한국전기전자재료학회논문지
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    • 제23권6호
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    • pp.491-496
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    • 2010
  • The relaxation behavior of aligned electric dipoles in a mixed polymer of P2ANS with P(VDF-TrFE) is studied with optical second harmonic generation (SHG). In this work, a macroscopic noncentrosymmetry of the spin coated film was achieved by an electrical poling. The relaxation of induced polar order of nonlinear optic(NLO) chromophores after poling leads to an insufficient long-term stability of NLO properties. In this work, we develop a new technique to suppress such kind of dipole relaxation in a poled polymer. We found that the poled dipoles in a NLO polymer were effectively immobilized by the internal electric field created by a thermally annealed ferroelectric polymer. The long-term stability in a mixed system of NLO polymer/ferroelectric polymer was successively accomplished by a series of thermal treatments applied to the mixed polymer system at a temperature of $140^{\circ}C$ for at least 1hour after poling.

다중벽 탄소나노튜브/리오셀 복합섬유의 제조 및 특성조사 (Preparation and Characterization of Multiwalled Carbon Nanotubes/Lyocell Composite Fibers)

  • Lu, Jiang;Zhang, Huihui;Shao, Huili;Hu, Xuechao
    • 폴리머
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    • 제31권5호
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    • pp.436-441
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    • 2007
  • In this work, the multiwalled carbon nanotubes(MWNTs) were functionalized with sodium dodecylbenzene sulfonate(SDBS) and then MWNTs/Lyocell composite fibers were prepared. The properties of MWNTs, the functionlization on the surface of MWNTs and their dispersion in the cellulose matrix were characterized by TEM, SEM, WAXD and FT-IR. The results showed that SDBS has been coated successfully onto the surface of the MWNTs by functionlization. This can improve effectively the dispersion uniformity of MWNTs in NMMO aqueous solution and is helpful to prepare a spinnable spinning dope. Moreover, the resultant MWNTs/Lyocell composite fibers still have cellulose II crystal structure, and their tensile strength and initial modulus increased with the increasing draw ratio and reached the optimal value with adding 1 wt% MWNTs. The thermal stability of the composite fiber was also improved by the addition of the MWNTs.

전기 절연성능 향상을 위한 폴리머 애자의 표면 특성 연구 (A Study on the Surface Properties of Polymer Insulators for Improving Electrical Insulation Performance)

  • 박용섭;배재성;홍병유;이재형
    • 한국전기전자재료학회논문지
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    • 제34권1호
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    • pp.63-67
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    • 2021
  • In this paper, we investigated the surface properties of polymer insulators to improve electrical insulation performance. First, after washing the polymer insulator in various ways, its contact angle was increased, thereby improving the hydrophobic properties and electrical insulation properties. In addition, TiO2 thin films, which have been used as a photocatalytic material and have been applied to the polymer insulator surface of to enhance the surface and electrical insulating properties. For the sputtering method, the contact angle after coating the TiO2 thin film increased with increasing RF power, but it was lower compared to that before coating, indicating that the hydrophobic properties of the surface were slightly deteriorated. Consequently, the electrical properties of the polymer-insulating material were maintained or improved after the TiO2 thin-film coating.