• Title/Summary/Keyword: Polymer Material

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Preparation and Physicochemical Properties of Soluble Dietary Fiber Extracts from Soymilk Residue at High Temperature (두유박 수용성 식이섬유의 고온 추출물 제조와 이화학적 특성구명)

  • Park, Chun-Ho;Kim, Hyun-Jung;Moon, Tae-Wha
    • Korean Journal of Food Science and Technology
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    • v.29 no.4
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    • pp.648-656
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    • 1997
  • Thermal treatment of soymilk residue was carried out at 140, 150, and $160^{\circ}C$ for possible use as a raw material for dietary fiber, and some physicochemical properties of the extracts were investigated. Soluble dietary fiber(SDF) content of the extracts prepared under optimal conditions was more than 30% suggesting the conversion of insoluble dietary fiber to SDF. The main sugar components of the extracts were glucose, galactose, and arabinose. Analysis of the moelcular weight distribution by high performance size exclusion chromatography revealed that the proportion of high molecular weight fraction decreased and that of middle-sized polymer increased as the extraction temperature increased. The viscosity of aqueous solution of the extracts decreased with an increase in extraction temperature, but showed no trend as pH changed. The solubility increased with extraction temperature showing the highest at $160^{\circ}C$. The extract at $140^{\circ}C$ had the biggest calcium-binding capacity, which correlated with the changes in viscosity.

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Flexibility Study of Silicon Thin Film Transferred on Flexible Substrate (폴리머 기판 위에 전사된 실리콘 박막의 기계적 유연성 연구)

  • Lee, Mi-Kyoung;Lee, Eun-Kyung;Yang, Min;Chon, Min-Woo;Lee, Hyouk;Lim, Jae Sung;Choa, Sung-Hoon
    • Journal of the Microelectronics and Packaging Society
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    • v.20 no.3
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    • pp.23-29
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    • 2013
  • Development of flexible electronic devices has primarily focused on printing technology using organic materials. However, organic-based flexible electronics have several disadvantages, including low electrical performance and long-term reliability. Therefore, we fabricated nano- and micro-thick silicon film attached to the polymer substrate using transfer printing technology to investigate the feasibility of silicon-based flexible electronic devices with high performance and high flexibility. Flexibility of the fabricated samples was investigated using bending and stretching tests. The failure bending radius of the 200 nm-thick silicon film attached on a PI substrate was 4.5 mm, and the failure stretching strain was 1.8%. The failure bending radius of the micro-thick silicon film attached on a FPCB was 2 mm, and the failure strain was 3.5%, which showed superior flexibility compared with conventional silicon material. Improved flexibility was attributed to a buffering effect of the adhesive between the silicon film and the substrate. The superior flexibility of the thin silicon film demonstrates the possibility for flexible electronic devices with high performance.

Creep Behavior of Pultruded Ribbed GFRP Rebar and GFRP Reinforced Concrete Member (인발성형된 이형 GFRP 보강근과 GFRP 보강 콘크리트 부재의 크리프 거동)

  • You, Young-Jun;Park, Young-Hwan;Kim, Hyung-Yeol;Choi, Jin-Won;Kim, Jang-Ho Jay
    • Journal of the Korea Concrete Institute
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    • v.25 no.2
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    • pp.187-194
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    • 2013
  • Fiber reinforced polymer (FRP) has been gathering interest from designers and engineers for its possible usage as a replacement reinforcement of a steel reinforcing bar due to its advantageous characteristics such as high tensile strength, non-corrosive material, etc. Since it is manufactured with various contents ratios, fiber types, and shapes without any general specification, test results for concrete members reinforced with these FRP reinforcing bars could not be systematically used. Moreover, since investigations for FRP reinforced members have mainly focused on short-term behavior, the purpose of this study is to evaluate long-term behaviors of glass FRP (GFRP) reinforcing bar and concrete beams reinforced with GFRP. In this paper, test results of tensile and bond performance of GFRP reinforcing bar and creep behavior are presented. In the creep tests, results showed that 100 years of service time can be secured when sustained load level is below 55% of tensile strength of GFRP reinforcing bar. A modification factor of 0.73 used to calculate long-term deflection of GFRP reinforced beams was acquired from the creep tests for GFRP reinforced concrete beams. It is expected that these test results would give more useful information for design of FRP reinforced members.

Case History of Sea Dyke Filter Construction Using Geotextile Tube Mattress (튜브형 매트리스를 활용한 방조제 필터공 축조사례연구)

  • Oh, Young-In;Yoo, Jeon-Yong;Kim, Hyun-Tae
    • Journal of the Korean Geosynthetics Society
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    • v.6 no.1
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    • pp.9-16
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    • 2007
  • Geotextile is one of the most useful and effective polymer material in civil construction works and the main function of geotextile is separation, reinforcement, filtering and drainage. Recently, because of the shortage of natural rock, traditional forms of river and coastal structures have become very expensive to build and maintain. Therefore, the materials used in hydraulic and coastal structures are changing from the traditional rubble and concrete systems to the cheaper materials and systems. One of these alternatives employs geotextile tube technology in the construction of coastal and shore protection structures, such as embankment, see dyke, groins, jetties, detached breakwaters and so on. Geotextile tube technology has changed from being an alternative construction technique and, in fact, has advanced to become the most effective solution of choice. This paper presents case history of sea dyke filter construction using geotextile tube mattress and also, various issues related to the tube mattress design and construction technology.

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Pervaporation of Butanol from their Aqueous Solution using a PDMS-Zeolite Composite Membrane (PDMS-Zeolite 복합막을 이용한 부탄올 투과증발)

  • Kong, Chang-In;Cho, Moon-Hee;Lee, Yong-Taek
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.816-822
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    • 2011
  • Pervaporation is known to be a low energy consumption process since it needs only an electric power to maintain the permeate side in vacuum. Also, the pervaporation is an environmentally clean technology because it does not use the third material such as an entrainer for either an azeotropic distillation or an extractive distillation. In this study, Silicalite-1 particles are hydrothermally synthesized and polydimethylsiloxane(PDMS)-zeolite composite membranes are prepared with a mixture of synthesized Silicalite-1 particles and PDMS-polymer. They are used to separate n-butanol from its aqueous solution. Pervaporation characteristics such as a permeation flux and a separation factor are investigated as a function of the feed concentration and the weight % of Silicalite-1 particles in the membrane. A 1,000 $cm^3$ aqueous solution containing butanol of low mole fraction such as order of 0.001 was used as a feed to the membrane cell while the pressure of the permeation side was kept about 0.2~0.3 torr. When the butanol concentration in the feed solution was 0.015 mole fraction, the flux of n-butanol significantly increased from 14.5 g/ $m^2$/hr to 186.3 g/$m^2$/hr as the Silicalite-1 content increased from 0 wt% to 10 wt%, indicating that the Silicalite-1 molecular sieve improved the membrane permselectivity from 4.8 to 11.8 due to its unique crystalline microporous structure and its strong hydrophobicity. Consequently, the concentration of n-butanol in the permeate substantially increased from 0.07 to 0.15 mole fraction. This composite membrane could be potentially appliable for separation of n-butanol from insitu fermentation broth where n-butanol is produced at a fairly low concentration of 0.015 mole fraction.

Effects of Silicone Polymer Blends on Physical Properties of Dental Polyvinylsiloxane Impression Materials (실리콘폴리머의 혼합사용이 폴리비닐실록산 치과용 인상재의 물성에 미치는 영향)

  • Lim, Chang-Ha;Kim, Min-Kang;Kim, Young-Chul;Park, Nam-Cook;Song, Ho-Jun;Park, Yeong-Joon
    • Elastomers and Composites
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    • v.44 no.1
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    • pp.76-83
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    • 2009
  • The purpose of this study was to investigate the effects of combined use of several types of silicone polymers on the physical properties of the dental polyvinylsiloxane impression materials (PVS). Four types of silicone prepolymers having different molecular weight and vinyl group position, and two types of cross-linkers having differently located silyl hydride functional groups were used in various combinations for the formulation. The samples containing bimodal or trimodal prepolymers showed higher tensile strength, elongation at break, and elastic deformation than those containing only one type of prepolymer. The samples using CR210 cross-linker which has side- and terminal-silyl hydride groups showed higher elastic deformation and elongation at break than those using CR101 cross-liker which has side-only silyl hydride group. High vinyl content prepolymer having side vinyl group delayed setting even though it enhanced tensile strength. Further studies are needed to clarify the specific role of this component on setting time and to find appropriate controlling methods for making improved PVS with optimum workability.

Polyether Ester by Rubber Content and Rubber According to the Type of Dynamic Vulcanized Properties (TPEE) (폴리에스터계 동적가교물의 고무함량 및 고무종류에 따른 물성)

  • Yun, Ju-Ho;Yun, Jung-Hwan;Ha, Seong-Mun;Kim, Il;Sim, Sang-Eun
    • Elastomers and Composites
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    • v.48 no.1
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    • pp.67-75
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    • 2013
  • E-TPE (Engineering Thermoplastic Polyether Ester) was Ester Elastomer with functional groups as recycling and fast processability. In addition, if the car's lightweight enough to highlight eco-friendly materials that help to improve fuel economy has become. Have all the attributes of the rubber and engineering plastics E-TPE the available temperature area is spacious, heat resistance and oil resistance is excellent but getting attention as a new material in the field of auto parts in the field of electrical and electronic domestic depends entirely on imports by the lack of core technology and has been research and development is urgently needed. In this study, the hard segments, polyester (TPEE) as the base soft elastomers of the segments Ethylen-prophylene-Copolymer and CSM (Choloro sulphonated polyethylene Rubber), VAMAC (Ethylene Acrylic Rubber), NBR (Acrylonitrin Butadiene Rubber), 1, 3-Phenylene-bisoxazoline is dealing with Dynamic Vulcanized by content and added rubber properties, thermal variation observed. As a result, the properties of the dynamic vulcanization with NBR compared to other rubber heat resistance and oil resistance is on the increase.

COLOR STABILITY OF CEROMERS IN THREE FOOD COLORANTS (식용색소에 의한 CEROMER 수복물의 색안정성)

  • Jeong Yu-Jin;Lim Ju-Hwan;Cho In-Ho;Lim Heon-Song
    • The Journal of Korean Academy of Prosthodontics
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    • v.41 no.2
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    • pp.136-147
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    • 2003
  • Statement of problem : Ceramic and composite resin have been used to fulfill the demand for esthetic prosthesis. However, ceramic is easy to break and wears off the opposite natural teeth. Conventional composite resin also has low abrasive resistance and color stability. Ceramic Optimized Polymer (ceromer) was developed in mid-1990s to overcome the shortfalls of ceramic and composite resin. Ceromer has similar abrasiveness with the natural tooth and has relatively high strength. Color stability affects esthetics and long-term prognosis of the prosthesis. Purpose The purpose of this study was to compare color stability of ceromers(2 types : $Artglass^{(R)}$. $Targis^{(R)}$) with ceramics ($Vintage^{(R)}$-polishing, $Vintage^{(R)}$-glazing). Material and Method : The color difference(${\Delta}E^*$) was measured by spectrophotometer with different immersion time. Twenty disks, 3mm in thickness and 10mm in diameter, were fabricated for each specimen in shade A2(Vita Lumin shade guide), Specimens (5 samples in each group) were immersed in the food colorants (Red no.3. Yellow no.4, Blue no.1, Distilled water) for 24 hours, 48 hours and 72 hours respectively. $L^*,\;a^*$ and $b^*$ value were measured with spectrophotometer (CM 503i : Minolta Co., Japan) and mean ${\Delta}E^*$ value was calculated for statistical analysis Results : The results of this study were obtained as follows. 1. The ${\Delta}E^*$ values of all test samples increased with the time of immersion. 2. The ${\Delta}E^*$ values of all materials increased in order of Distilled Water, Yellow no.4, Blue no.1 and fed no.3. There was significant difference between Red no.3 and the other food colorants(p<0.05). 3. The ${\Delta}E^*$ values increased in order of $Vintage^{(R)}$-glazing, $Vintage^{(R)}$-polishing. $Artglass^{(R)}$ and $Targis^{(R)}$. There was significant difference between $Vintage^{(R)}$-glazing and the other materials (p<0.05). Conclusion : By means of the above results, immersion time was found to be a critical factor for color stability of ceromer. For the long-term color stability of prosthesis it is recommended patients having ceromer prosthesis ($Artglass^{(R)},\;Targis^{(R)}$) to reduce the habitual intake of Red no.3 colorants con taming foods.

Weatherability of Organic-Inorganic Hybrid Coating Agents with N-Triethoxy silyl propyl quinine urethane (N-Triethoxy silyl propyl quinine urethane을 도입한 유-무기 복합 코팅제의 내후성)

  • Lee, Man Sung;Jo, Nam-Ju
    • Journal of Adhesion and Interface
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    • v.2 no.2
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    • pp.20-27
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    • 2001
  • Recently polycarbonate material has been utilized as windows in aircraft, buildings, and optical lens. However, while polycarbonate has excellent optical transparency, impact strength and many beneficial mechanical properties, it possesses poor abrasion resistance and weatherability. Then, there is a need for developing optically clear, anti-abrasive and weather resistant hard coating agents for polycarbonate. In this study, N-triethoxy silyl propyl quinine urethane(TESPQU) was synthesized with quinine and 3-isocyanato propyl triethoxy silane(3-IPTES). In order to introduce optically active silane in the main siloxane network, TESPQU was co-hydrolysed and co-condensed with methyl triethoxy silane(MTES) under acidic conditions. Polycarbonate sheets were coated with silica coating agents by the sol-gel method, and their abrasion resistance, ability of UV absorption and weatherability were evaluated. Coating agents containing hydroxybenzophenone as a UV absorber were also prepared to compare weatherability with TESPQU containing coating agent. TESPQU containing coating agent had good weatherability in accelerated QUV test.

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The Thermal and Mechanical Properties of Epoxy Composites Including Boron Carbide Surface Treated with Iron Oxide and Tungsten (철산화물과 텅스텐으로 표면 처리된 보론카바이드를 포함하는 에폭시 조성물의 열적·기계적 물성)

  • Kim, Taehee;Lee, Wonjoo;Seo, Bongkuk;Lim, Choong-Sun
    • Journal of Adhesion and Interface
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    • v.19 no.3
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    • pp.113-117
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    • 2018
  • Boron carbide is lower in hardness than diamond or boron nitride but has a hardness of more than 30 GPa and is used for manufacturing tank armors and ammo shells due to its high hardness. It is also used as a neutron absorber due to its ability to absorb neutrons, which is increasing its use in nuclear power projects. Neutrons have no interaction with electrons and are known to pass through the material without interactions. Along with boron carbide, the atoms with high interaction with neutrons are hydrogen, and high hydrogen concentration polyesters and epoxy polymers including boron are used as materials for manufacturing products for nuclear power generation waste. In this paper, the surface of boron carbide is treated with iron oxide and tungsten to improve interaction between modified boron carbide and epoxy polymer. XRD and XPS were used to confirm that iron oxide and tungsten are well attached on the surface of boron carbide, respectively. The mechanical strength of the surface treated boron carbide was measured by a universal testing machine (UTM) and the dynamic characteristics of the cured product were observed by using a dynamic analyzer (DMA).