• Title/Summary/Keyword: Polymer Binder

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Study on Binders for Preparing Antistatic Films of PEDOT/PSS (대전방지 PEDOT/PSS 필름 제조를 위한 바인더에 관한 연구)

  • Kim, Seok Jun;Park, Wan-Su;Hwang, Jung Seok;Pak, Na Young;Choi, Young Ju;Chung, Dae-won
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.458-462
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    • 2015
  • It is essential to employ a binder to prepare transparent films from conductive polymer such as poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT/PSS). In this paper, poly(vinyl alcohol) (PVA), poly(vinyl pyrrolidone) (PVP), and PSS were selected as a binder, and their effects were investigated. The formation of the film was found to be primarily dependent on the surface tension of coating solution including PEDOT/PSS and a binder. When PSS was used as a binder, the film was not formed. In case of using PVP, it was easily peeled off from the substrate. However, when using the PVA or the mixtures of PVA and PSS or PVA and PVP as a binder, films with good transparency and uniform surface resistances were produced. Based on adhesion and long-term stability tests, we concluded that the mixture of PVA and PSS is the best binder for preparing antistatic films of PEDOT/PSS.

Optimization of Self-crosslinking Comonomer Composition of Polymer Binder for DTP Pigment Ink (DTP 안료 잉크용 고분자 바인더의 Self-crosslinking 공단량체 조성 최적화 연구)

  • Han, Minwoo;Kwon, Woong;Park, Seongmin;Jeong, Euigyung
    • Textile Coloration and Finishing
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    • v.32 no.1
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    • pp.19-26
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    • 2020
  • The previous study reported that the quaternary copolymer of MMA, BA, MAA, and NEA was expected to be a good monomer composition for a binder polymer with good rubbing fastness for digital textile printing(DTP) pigment ink. However, the rubbing fastness of the dyed fabric with the quaternary copolymer binder containing pigment ink is not enough to be commercially used. Therefore, this study aims to optimize MMA:BA:MAA:NEA composition for improved rubbing fastness. And the binder polymer with various MMA:BA:MAA:NEA compositions were synthesized using miniemulsion polymerization. The particle size, viscosity, molecular weight, and Tg of the synthesized binder were evaluated. And the color strength and rubbing fastness of the black pigment ink dyed cotton fabrics with the prepared binders were also evaluated. Then, the stiffness of undyed and dyed cotton fabrics were evaluated to investigate the changes in touch as the binder structure changes.

Adhesion Properties of Polymer Composite Materials for Concrete Repair (콘크리트 보수용 폴리머 복합재료의 접착강도 특성)

  • 지경용;연규석;이윤수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10a
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    • pp.330-335
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    • 1998
  • This research was conducted to evaluate the adhesion in tension of the polymer mortars for cement concrete repair. Various polymer types, binder ratios, and wet/dry conditions of the surface were considered in this study. Styrene-butadiene rubber (SBR) and ethylen vinyl acetate (EVA) used for polymer cement mortars. Epoxy resin (EP), and unsaturated polyester resin (UP) were used for polymer mertars. Adhesion in tension for the dry condition of the substrate surface was higher than that for the wet condition of the substrate surface under the same binder ratio. Therefore, in repairing concrete, the dry surface condition was effective on adhesion.

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A Study on the Freezing and Thawing Resistance of Permeable Polymer Concrete (투수성 폴리머 콘크리트의 동결융해 저항성에 관한 연구)

  • 박응모;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.331-336
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    • 1999
  • Permeable polymer concrete in this study is one of the environment conscious concrete that can be applied at road, side walks and river embankment, etc. The purpose of this study is to evaluate the effects of mix proportions such as resing content, filler-binder ratio and aggregate ratio on the freezing and thawing resistance of permeable polymer concrete. The permeable polymer concrete are prepared with the resin ratio of 5%, 6% and 7%, filler-binder ratio of 0, 0.5 and 1.0, and 2.5~5mm sized aggregate ratio to standard sand of 10:10, 10:20, 20:10 and 20:20. It is tested for freezing and thawing test according to ASTM C 666092, and then, weight change, length change, relative dynamic modulus, durability factor, and compressive and flexural strengths after test are measured. From the test results, the resistance to freezing and thawing of permeable polymer concrete increased with increase the resing content, filler-binder ratio and fine aggregate ratio.

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A Fundamental Study on the Properties of Permeable Polymer Concrete (투수성 폴리머 콘크리트의 성질에 관한 기초적 연구)

  • 박응모;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.363-368
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    • 1997
  • In this study, permeable polymer concretes using unsaturated polyester (UP) resin with binder contents of 6, 7 and 8%, filler-binder ratios of 0, 0.5, 1.0%, and various sand and aggregate contents are prepared, and tested for compressive and flexural strengths, length change and water permeability. The effects of the mix proportioning factors on the strength properties, length change and coefficient of permeability of the permeable polymer concrete are discussed. From the test results, increase in the compressive strength and decrease in the coefficient of permeability of permeable polymer concrete are clearly observed with increasing filler-binder ratio. The permeable polymer concretes having a compressive strength of 9.4~28.3MPa and a coefficient of permeability of 0.12~1.93 cm/s can be produced in the consideration of the mix proportioning factors.

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Performance Characteristics of No-Fines Polymer Concrete using Recycled Coarse Aggregate with Binder Contents (결합재의 함량에 따른 순환굵은골재 사용 무세골재 폴리머 콘크리트의 성능 발현 특성)

  • Kim, Do-Heon;Jung, Hyuk-Sang;Kim, Dong-Hyun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.433-442
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    • 2021
  • In this study, the properties of no-fines polymer concrete with different polymer binder contents were evaluated. The polymer concrete was formulated using a polymeric binder (unsaturated polyester resin), fly ash, and recycled coarse aggregate (60%) and crushed coarse aggregate (40%). The polymeric binder content (4.0-6.0wt.%) was used as an experimental variable because it dramatically affects both the cost-effectiveness and material properties. The results showed that the density, compressive strength, flexural strength both before and after exposure to freezing and thawing increased as the polymer binder content increased, while the absorption, void ratio, permeable voids, coefficient of permeability, and acid resistance (mass loss by acid attack) decreased as the polymeric binder content increased. In particular, even though the void ratio was 18.4% and the water permeability coefficient was 7.3mm/sec, the compressive strength and flexural strength were as high as 38.0MPa and 10.0MPa, respectively, much more significant than those of previous studies. Other properties such as absorption and acid resistance were also found to be excellent. The results appear to be rooted in the increased adhesion of the binder by adding a cross-linking agent and the surface hydrophobicity of the polymer.

Effect of the Binder Content on the Recycling of Scrap Waste Tires (폐타이어 재활용에 있어서 Binder양이 미치는 영향)

  • Kim, Jin-Kuk;Cho, Ha-Na;Lee, Soo-Koo
    • Elastomers and Composites
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    • v.29 no.5
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    • pp.431-435
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    • 1994
  • For recycling of the waste tires, polyurethane binder mixed with the scrapped rubber powders which obtained from tread part of waste tire. This study covered the effect of the binder contents on the mechanical properties of the blend. We also studied the change of the properties after aging on properties compared with those of before aging. The curing reaction of the binder was also investigated in this study. We obtained conclusions the suitable binder content was 15phr in this system.

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Study on the Optimization of Cationic Ring Opening Polymerization of Silicone-Based Epoxy Monomers for Holographic Photopolymers

  • Kim, Dae-Heum;Chung, Dae-Won
    • Macromolecular Research
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    • v.17 no.9
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    • pp.651-657
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    • 2009
  • This study examined the optimum compositions of binder, photo-acid generator (PAG) and sensitizer for the cationic ring opening polymerization of 1,3-bis[2-(3-{7-oxabicyclo-[4.1.0]heptyl})]-tetramethyldisiloxane in the presence of polydimethylsiloxane with four epoxide moieties as a co-monomer. When diffractive efficiency (DE) values were compared quantitatively to analyze the effect of the binder on holographic photopolymerization, DE was affected by the viscosity of the binders and miscibility with the monomer mixture. Extremely low DE values were observed when the immiscible dimethyl silicone was used as a binder. Therefore, methylphenyl silicone, which is miscible with the monomer mixture, was used as the binder for further studies. The optimal conditions were a binder viscosity between 250 to 390 cP, and contents of the binder, PAG, and sensitizer were 75-125 wt%, > 6 wt% and 0.05 wt% to the total monomer mixture, respectively.

Strength and Durability of Polymer-Modified Mortars Using Ground Granulated Blast-Furnace Slag (고로슬래그 미분말을 혼입한 폴리머 시멘트 모르타르의 강도 및 내구성)

  • 주명기;김남길;연규석
    • Journal of the Korea Concrete Institute
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    • v.14 no.2
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    • pp.164-170
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    • 2002
  • Effect of the polymer-binder ratio and slag content on the properties of combined wet/dry-cured polymer-modified mortars using granulated blast-furnace slag are examined. Results shows that the flexural and compressive strengths of polymer-modified mortar using the slag tend to increase with increasing slag content, and reaches a maximum at a slag content of 40 %, and is inclined to increase with increasing polymer-binder ratio. Water absorption, carbonation depth and chloride ion penetration depth tend to decrease with increasing polymer-binder ratio and slag content. Accordingly, the incorporation of slag into polymer-modified mortars at a slag content of 40% is recommended for a combined wet/dry curing regardless of the types of polymer.

Evaluation of Properties of Polymer-Modified Mortar with CSA (CSA를 혼입한 폴리머 시멘트 모르타르의 성능평가)

  • Joo, Myung-Ki;Lho, Byeong-Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.1
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    • pp.35-44
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    • 2015
  • Two main parameters were examined such as CSA content and polymer-binder ratio to find effects on the strength, water absorption, chloride ion penetration depth, carbonation depth, length change and chemical resistance of polymer-modified mortar with CSA and EVA polymer powder (EVAPP). As results, compressive, flexural, tensile, adhesive strengths, and length change of the polymer-modified mortar with CSA and EVAPP increases with increasing CSA content and polymer-binder ratio, although the water absorption, chloride ion penetration depth, and carbonation depth decrease with increasing polymer-binder ratio and CSA content, and also the chemical resistance decreases. Such strength and durability development is attributed to the high tensile strength of EVA polymer and the improved bond between cement hydrates and aggregates because of the addition of EVAPP and CSA.